Comparison of laboratory delignification methods, their selectivity, and impacts on physiochemical characteristics of cellulosic biomass.
Identifieur interne : 002733 ( Main/Curation ); précédent : 002732; suivant : 002734Comparison of laboratory delignification methods, their selectivity, and impacts on physiochemical characteristics of cellulosic biomass.
Auteurs : Rajeev Kumar [États-Unis] ; Fan Hu ; Christopher A. Hubbell ; Arthur J. Ragauskas ; Charles E. WymanSource :
- Bioresource technology [ 1873-2976 ] ; 2013.
Descripteurs français
- KwdFr :
- Acide acétique (composition chimique), Acide peracétique (composition chimique), Biomasse (MeSH), Bois (MeSH), Chlorures (composition chimique), Cinétique (MeSH), Lignine (composition chimique), Masse moléculaire (MeSH), Panicum (MeSH), Pinus (MeSH), Polymérisation (MeSH), Populus (MeSH), Zea mays (MeSH).
- MESH :
- composition chimique : Acide acétique, Acide peracétique, Chlorures, Lignine.
- Biomasse, Bois, Cinétique, Masse moléculaire, Panicum, Pinus, Polymérisation, Populus, Zea mays.
English descriptors
- KwdEn :
- MESH :
- chemical , chemistry : Acetic Acid, Chlorides, Lignin, Peracetic Acid.
- Biomass, Kinetics, Molecular Weight, Panicum, Pinus, Polymerization, Populus, Wood, Zea mays.
Abstract
Two established delignification methods employing sodium chlorite-acetic acid (SC/AA) and peracetic acid (PAA) are often used, and are reportedly highly selective. However, these reports are mostly for highly recalcitrant and unpretreated softwoods and hardwoods species, and information for less recalcitrant lignocellulosic feedstocks and pretreated biomass is scarce. Furthermore, the effects on cellulose structure are not documented. Thus, in this study, delignification kinetics and selectivity were evaluated when SC/AA and PAA were applied to untreated switchgrass, poplar, corn stover, and pine sawdust; poplar subjected to AFEX, controlled pH, lime, and SO(2) pretreatments; and the cellulose model compounds. Both methods proved effective in removing >90% lignin, but selectivity for lignin and carbohydrates removal was substrate and pretreatment dependent. For untreated biomass, PAA was more selective in removing lignin than SC/AA; however, both methods were less selective for pretreated solids. Cellulose characterizations revealed that PAA had less pronounced impacts on cellulose structure.
DOI: 10.1016/j.biortech.2012.12.028
PubMed: 23313683
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pubmed:23313683Le document en format XML
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<author><name sortKey="Kumar, Rajeev" sort="Kumar, Rajeev" uniqKey="Kumar R" first="Rajeev" last="Kumar">Rajeev Kumar</name>
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<series><title level="j">Bioresource technology</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Acetic Acid (chemistry)</term>
<term>Biomass (MeSH)</term>
<term>Chlorides (chemistry)</term>
<term>Kinetics (MeSH)</term>
<term>Lignin (chemistry)</term>
<term>Molecular Weight (MeSH)</term>
<term>Panicum (MeSH)</term>
<term>Peracetic Acid (chemistry)</term>
<term>Pinus (MeSH)</term>
<term>Polymerization (MeSH)</term>
<term>Populus (MeSH)</term>
<term>Wood (MeSH)</term>
<term>Zea mays (MeSH)</term>
</keywords>
<keywords scheme="KwdFr" xml:lang="fr"><term>Acide acétique (composition chimique)</term>
<term>Acide peracétique (composition chimique)</term>
<term>Biomasse (MeSH)</term>
<term>Bois (MeSH)</term>
<term>Chlorures (composition chimique)</term>
<term>Cinétique (MeSH)</term>
<term>Lignine (composition chimique)</term>
<term>Masse moléculaire (MeSH)</term>
<term>Panicum (MeSH)</term>
<term>Pinus (MeSH)</term>
<term>Polymérisation (MeSH)</term>
<term>Populus (MeSH)</term>
<term>Zea mays (MeSH)</term>
</keywords>
<keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Acetic Acid</term>
<term>Chlorides</term>
<term>Lignin</term>
<term>Peracetic Acid</term>
</keywords>
<keywords scheme="MESH" qualifier="composition chimique" xml:lang="fr"><term>Acide acétique</term>
<term>Acide peracétique</term>
<term>Chlorures</term>
<term>Lignine</term>
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<keywords scheme="MESH" xml:lang="en"><term>Biomass</term>
<term>Kinetics</term>
<term>Molecular Weight</term>
<term>Panicum</term>
<term>Pinus</term>
<term>Polymerization</term>
<term>Populus</term>
<term>Wood</term>
<term>Zea mays</term>
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<term>Bois</term>
<term>Cinétique</term>
<term>Masse moléculaire</term>
<term>Panicum</term>
<term>Pinus</term>
<term>Polymérisation</term>
<term>Populus</term>
<term>Zea mays</term>
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<front><div type="abstract" xml:lang="en">Two established delignification methods employing sodium chlorite-acetic acid (SC/AA) and peracetic acid (PAA) are often used, and are reportedly highly selective. However, these reports are mostly for highly recalcitrant and unpretreated softwoods and hardwoods species, and information for less recalcitrant lignocellulosic feedstocks and pretreated biomass is scarce. Furthermore, the effects on cellulose structure are not documented. Thus, in this study, delignification kinetics and selectivity were evaluated when SC/AA and PAA were applied to untreated switchgrass, poplar, corn stover, and pine sawdust; poplar subjected to AFEX, controlled pH, lime, and SO(2) pretreatments; and the cellulose model compounds. Both methods proved effective in removing >90% lignin, but selectivity for lignin and carbohydrates removal was substrate and pretreatment dependent. For untreated biomass, PAA was more selective in removing lignin than SC/AA; however, both methods were less selective for pretreated solids. Cellulose characterizations revealed that PAA had less pronounced impacts on cellulose structure.</div>
</front>
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<Abstract><AbstractText>Two established delignification methods employing sodium chlorite-acetic acid (SC/AA) and peracetic acid (PAA) are often used, and are reportedly highly selective. However, these reports are mostly for highly recalcitrant and unpretreated softwoods and hardwoods species, and information for less recalcitrant lignocellulosic feedstocks and pretreated biomass is scarce. Furthermore, the effects on cellulose structure are not documented. Thus, in this study, delignification kinetics and selectivity were evaluated when SC/AA and PAA were applied to untreated switchgrass, poplar, corn stover, and pine sawdust; poplar subjected to AFEX, controlled pH, lime, and SO(2) pretreatments; and the cellulose model compounds. Both methods proved effective in removing >90% lignin, but selectivity for lignin and carbohydrates removal was substrate and pretreatment dependent. For untreated biomass, PAA was more selective in removing lignin than SC/AA; however, both methods were less selective for pretreated solids. Cellulose characterizations revealed that PAA had less pronounced impacts on cellulose structure.</AbstractText>
<CopyrightInformation>Copyright © 2012 Elsevier Ltd. All rights reserved.</CopyrightInformation>
</Abstract>
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