Feasibility of biochar manufactured from organic wastes on the stabilization of heavy metals in a metal smelter contaminated soil.
Identifieur interne : 000342 ( PubMed/Checkpoint ); précédent : 000341; suivant : 000343Feasibility of biochar manufactured from organic wastes on the stabilization of heavy metals in a metal smelter contaminated soil.
Auteurs : Ahmed A. Abdelhafez [Égypte] ; Jianhua Li [République populaire de Chine] ; Mohamed H H. Abbas [Égypte]Source :
- Chemosphere [ 1879-1298 ] ; 2014.
Descripteurs français
- Wicri :
- geographic : République populaire de Chine.
English descriptors
- KwdEn :
- MESH :
- chemical , analysis : Arsenic, Industrial Waste.
- chemical , chemistry : Cellulose, Charcoal, Lead, Soil, Soil Pollutants.
- geographic : China.
- chemistry : Citrus sinensis, Saccharum.
Abstract
The main objectives of the current study were to evaluate the potential effects of biochar derived from sugar cane bagasse (SC-BC) and orange peel (OP-BC) on improving the physicochemical properties of a metal smelter contaminated soil, and determining its potentiality for stabilizing Pb and As in soil. To achieve these goals, biochar was produced in a small-scale biochar producing plant, and an incubation experiment was conducted using a silt loam metal-contaminated soil treated with different application rates of biochar (0-10% w/w). The obtained results showed that, the addition of SC-BC and OP-BC increased significantly the soil aggregate stability, water-holding capacity, cation exchange capacity, organic matter and N-status in soil. SC-BC considerably decreased the solubility of Pb to values lower than the toxic regulatory level of the toxicity characteristics leaching procedure extraction (5 mg L(-1)). The rise in soil pH caused by biochar application, and the increase of soil organic matter transformed the labile Pb into less available fractions i.e. "Fe-Mn oxides" and "organic" bound fractions. On the other hand, As was desorbed from Fe-Mn oxides, which resulted in greater mobility of As in the treated soil. We concluded that SC-BC and OP-BC could be used successfully for remediating soils highly contaminated with Pb. However, considerable attention should be paid when using it in soil contaminated with As.
DOI: 10.1016/j.chemosphere.2014.05.086
PubMed: 24972072
Affiliations:
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pubmed:24972072Le document en format XML
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<front><div type="abstract" xml:lang="en">The main objectives of the current study were to evaluate the potential effects of biochar derived from sugar cane bagasse (SC-BC) and orange peel (OP-BC) on improving the physicochemical properties of a metal smelter contaminated soil, and determining its potentiality for stabilizing Pb and As in soil. To achieve these goals, biochar was produced in a small-scale biochar producing plant, and an incubation experiment was conducted using a silt loam metal-contaminated soil treated with different application rates of biochar (0-10% w/w). The obtained results showed that, the addition of SC-BC and OP-BC increased significantly the soil aggregate stability, water-holding capacity, cation exchange capacity, organic matter and N-status in soil. SC-BC considerably decreased the solubility of Pb to values lower than the toxic regulatory level of the toxicity characteristics leaching procedure extraction (5 mg L(-1)). The rise in soil pH caused by biochar application, and the increase of soil organic matter transformed the labile Pb into less available fractions i.e. "Fe-Mn oxides" and "organic" bound fractions. On the other hand, As was desorbed from Fe-Mn oxides, which resulted in greater mobility of As in the treated soil. We concluded that SC-BC and OP-BC could be used successfully for remediating soils highly contaminated with Pb. However, considerable attention should be paid when using it in soil contaminated with As.</div>
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