Validation of a multiclass multiresidue method and monitoring results for 210 pesticides in fruits and vegetables by gas chromatography-triple quadrupole mass spectrometry.
Identifieur interne : 000261 ( PubMed/Checkpoint ); précédent : 000260; suivant : 000262Validation of a multiclass multiresidue method and monitoring results for 210 pesticides in fruits and vegetables by gas chromatography-triple quadrupole mass spectrometry.
Auteurs : Samanta Uclés [Espagne] ; Noelia Belmonte ; Milagros Mezcua ; Ana B. Martínez ; M Jesus Martinez-Bueno ; Miguel Gam N ; Amadeo R. Fernández-AlbaSource :
- Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes [ 1532-4109 ] ; 2014.
English descriptors
- KwdEn :
- MESH :
- chemical , analysis : Pesticide Residues.
- chemistry : Citrus sinensis, Fruit, Lycopersicon esculentum, Onions, Solanum tuberosum, Vegetables.
- methods : Food Technology.
- Gas Chromatography-Mass Spectrometry.
Abstract
A rapid, sensitive, accurate and reliable multiresidue method for the identification and quantification of 210 relevant pesticides in four representative fruit and vegetable commodities (tomato, potato, spring onion and orange) has been developed and validated by gas chromatography in tandem with triple quadrupole mass spectrometry. The method has been fully validated and applied to 292 samples from different countries. Prior to instrumental analysis, an extraction procedure based on a sample extraction of multiclass analytes, using the ethyl acetate method was employed. Mass spectrometric conditions were individually optimized for each compound in the selected reaction monitoring (SRM) mode to achieve maximum sensitivity. The pesticides were separated in less than 25 min. This was followed by an exhaustive control of the retention times. The Retention Time Locking Method was applied, working at a constant pressure throughout the analysis. System maintenance was reduced by using a purged capillary flow device that provided backflush capabilities by reversing column flow immediately after elution of the last compound of interest. Istotopically labelled internal standards were employed to improve the quality of the analytical results.
DOI: 10.1080/03601234.2014.911566
PubMed: 24901959
Affiliations:
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Martínez</name></author><author><name sortKey="Martinez Bueno, M Jesus" sort="Martinez Bueno, M Jesus" uniqKey="Martinez Bueno M" first="M Jesus" last="Martinez-Bueno">M Jesus Martinez-Bueno</name></author><author><name sortKey="Gam N, Miguel" sort="Gam N, Miguel" uniqKey="Gam N M" first="Miguel" last="Gam N">Miguel Gam N</name></author><author><name sortKey="Fernandez Alba, Amadeo R" sort="Fernandez Alba, Amadeo R" uniqKey="Fernandez Alba A" first="Amadeo R" last="Fernández-Alba">Amadeo R. 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Martínez</name></author><author><name sortKey="Martinez Bueno, M Jesus" sort="Martinez Bueno, M Jesus" uniqKey="Martinez Bueno M" first="M Jesus" last="Martinez-Bueno">M Jesus Martinez-Bueno</name></author><author><name sortKey="Gam N, Miguel" sort="Gam N, Miguel" uniqKey="Gam N M" first="Miguel" last="Gam N">Miguel Gam N</name></author><author><name sortKey="Fernandez Alba, Amadeo R" sort="Fernandez Alba, Amadeo R" uniqKey="Fernandez Alba A" first="Amadeo R" last="Fernández-Alba">Amadeo R. Fernández-Alba</name></author></analytic><series><title level="j">Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes</title><idno type="eISSN">1532-4109</idno><imprint><date when="2014" type="published">2014</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Citrus sinensis (chemistry)</term><term>Food Technology (methods)</term><term>Fruit (chemistry)</term><term>Gas Chromatography-Mass Spectrometry</term><term>Lycopersicon esculentum (chemistry)</term><term>Onions (chemistry)</term><term>Pesticide Residues (analysis)</term><term>Solanum tuberosum (chemistry)</term><term>Vegetables (chemistry)</term></keywords><keywords scheme="MESH" type="chemical" qualifier="analysis" xml:lang="en"><term>Pesticide Residues</term></keywords><keywords scheme="MESH" qualifier="chemistry" xml:lang="en"><term>Citrus sinensis</term><term>Fruit</term><term>Lycopersicon esculentum</term><term>Onions</term><term>Solanum tuberosum</term><term>Vegetables</term></keywords><keywords scheme="MESH" qualifier="methods" xml:lang="en"><term>Food Technology</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Gas Chromatography-Mass Spectrometry</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">A rapid, sensitive, accurate and reliable multiresidue method for the identification and quantification of 210 relevant pesticides in four representative fruit and vegetable commodities (tomato, potato, spring onion and orange) has been developed and validated by gas chromatography in tandem with triple quadrupole mass spectrometry. The method has been fully validated and applied to 292 samples from different countries. Prior to instrumental analysis, an extraction procedure based on a sample extraction of multiclass analytes, using the ethyl acetate method was employed. Mass spectrometric conditions were individually optimized for each compound in the selected reaction monitoring (SRM) mode to achieve maximum sensitivity. The pesticides were separated in less than 25 min. This was followed by an exhaustive control of the retention times. The Retention Time Locking Method was applied, working at a constant pressure throughout the analysis. System maintenance was reduced by using a purged capillary flow device that provided backflush capabilities by reversing column flow immediately after elution of the last compound of interest. Istotopically labelled internal standards were employed to improve the quality of the analytical results.</div></front></TEI><pubmed><MedlineCitation Status="MEDLINE" Owner="NLM"><PMID Version="1">24901959</PMID><DateCreated><Year>2014</Year><Month>6</Month><Day>6</Day></DateCreated><DateCompleted><Year>2015</Year><Month>01</Month><Day>16</Day></DateCompleted><DateRevised><Year>2014</Year><Month>6</Month><Day>6</Day></DateRevised><Article PubModel="Print"><Journal><ISSN IssnType="Electronic">1532-4109</ISSN><JournalIssue CitedMedium="Internet"><Volume>49</Volume><Issue>8</Issue><PubDate><Year>2014</Year></PubDate></JournalIssue><Title>Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes</Title><ISOAbbreviation>J Environ Sci Health B</ISOAbbreviation></Journal><ArticleTitle>Validation of a multiclass multiresidue method and monitoring results for 210 pesticides in fruits and vegetables by gas chromatography-triple quadrupole mass spectrometry.</ArticleTitle><Pagination><MedlinePgn>557-68</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1080/03601234.2014.911566</ELocationID><Abstract><AbstractText>A rapid, sensitive, accurate and reliable multiresidue method for the identification and quantification of 210 relevant pesticides in four representative fruit and vegetable commodities (tomato, potato, spring onion and orange) has been developed and validated by gas chromatography in tandem with triple quadrupole mass spectrometry. The method has been fully validated and applied to 292 samples from different countries. Prior to instrumental analysis, an extraction procedure based on a sample extraction of multiclass analytes, using the ethyl acetate method was employed. Mass spectrometric conditions were individually optimized for each compound in the selected reaction monitoring (SRM) mode to achieve maximum sensitivity. The pesticides were separated in less than 25 min. This was followed by an exhaustive control of the retention times. The Retention Time Locking Method was applied, working at a constant pressure throughout the analysis. System maintenance was reduced by using a purged capillary flow device that provided backflush capabilities by reversing column flow immediately after elution of the last compound of interest. Istotopically labelled internal standards were employed to improve the quality of the analytical results.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Uclés</LastName><ForeName>Samanta</ForeName><Initials>S</Initials><AffiliationInfo><Affiliation>a Agrifood Campus of International Excellence (ceiA3), European Union Reference Laboratory for Pesticide Residues in Fruit & Vegetables , University of Almeria , Almería , Spain.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Belmonte</LastName><ForeName>Noelia</ForeName><Initials>N</Initials></Author><Author ValidYN="Y"><LastName>Mezcua</LastName><ForeName>Milagros</ForeName><Initials>M</Initials></Author><Author ValidYN="Y"><LastName>Martínez</LastName><ForeName>Ana B</ForeName><Initials>AB</Initials></Author><Author ValidYN="Y"><LastName>Martinez-Bueno</LastName><ForeName>M Jesus</ForeName><Initials>MJ</Initials></Author><Author ValidYN="Y"><LastName>Gamón</LastName><ForeName>Miguel</ForeName><Initials>M</Initials></Author><Author ValidYN="Y"><LastName>Fernández-Alba</LastName><ForeName>Amadeo R</ForeName><Initials>AR</Initials></Author></AuthorList><Language>ENG</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType><PublicationType UI="D013485">Research Support, Non-U.S. Gov't</PublicationType><PublicationType UI="D023361">Validation Studies</PublicationType></PublicationTypeList></Article><MedlineJournalInfo><Country>England</Country><MedlineTA>J Environ Sci Health B</MedlineTA><NlmUniqueID>7607167</NlmUniqueID><ISSNLinking>0360-1234</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D010573">Pesticide Residues</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName UI="D032084" MajorTopicYN="N">Citrus sinensis</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D005524" MajorTopicYN="N">Food Technology</DescriptorName><QualifierName UI="Q000379" MajorTopicYN="Y">methods</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D005638" MajorTopicYN="N">Fruit</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D008401" MajorTopicYN="Y">Gas Chromatography-Mass Spectrometry</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D018551" MajorTopicYN="N">Lycopersicon esculentum</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D019697" MajorTopicYN="N">Onions</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D010573" MajorTopicYN="N">Pesticide Residues</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="Y">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D011198" MajorTopicYN="N">Solanum tuberosum</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D014675" MajorTopicYN="N">Vegetables</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName></MeshHeading></MeshHeadingList><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">GC-QQQ-MS</Keyword><Keyword MajorTopicYN="N">Multiresidue methods</Keyword><Keyword MajorTopicYN="N">fruits and vegetables</Keyword><Keyword MajorTopicYN="N">monitoring</Keyword><Keyword MajorTopicYN="N">pesticides</Keyword></KeywordList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="entrez"><Year>2014</Year><Month>6</Month><Day>6</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2014</Year><Month>6</Month><Day>6</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2015</Year><Month>1</Month><Day>17</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">24901959</ArticleId><ArticleId IdType="doi">10.1080/03601234.2014.911566</ArticleId></ArticleIdList></PubmedData></pubmed><affiliations><list><country><li>Espagne</li></country></list><tree><noCountry><name sortKey="Belmonte, Noelia" sort="Belmonte, Noelia" uniqKey="Belmonte N" first="Noelia" last="Belmonte">Noelia Belmonte</name><name sortKey="Fernandez Alba, Amadeo R" sort="Fernandez Alba, Amadeo R" uniqKey="Fernandez Alba A" first="Amadeo R" last="Fernández-Alba">Amadeo R. Fernández-Alba</name><name sortKey="Gam N, Miguel" sort="Gam N, Miguel" uniqKey="Gam N M" first="Miguel" last="Gam N">Miguel Gam N</name><name sortKey="Martinez Bueno, M Jesus" sort="Martinez Bueno, M Jesus" uniqKey="Martinez Bueno M" first="M Jesus" last="Martinez-Bueno">M Jesus Martinez-Bueno</name><name sortKey="Martinez, Ana B" sort="Martinez, Ana B" uniqKey="Martinez A" first="Ana B" last="Martínez">Ana B. Martínez</name><name sortKey="Mezcua, Milagros" sort="Mezcua, Milagros" uniqKey="Mezcua M" first="Milagros" last="Mezcua">Milagros Mezcua</name></noCountry><country name="Espagne"><noRegion><name sortKey="Ucles, Samanta" sort="Ucles, Samanta" uniqKey="Ucles S" first="Samanta" last="Uclés">Samanta Uclés</name></noRegion></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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