A highly selective dual mode detection of Fe3+ ion sensing based on 1,5-dihydroxyanthraquinone in the presence of β-cyclodextrin.
Identifieur interne : 000250 ( PubMed/Checkpoint ); précédent : 000249; suivant : 000251A highly selective dual mode detection of Fe3+ ion sensing based on 1,5-dihydroxyanthraquinone in the presence of β-cyclodextrin.
Auteurs : Sonaimuthu Mohandoss [Inde] ; Munisamy Maniyazagan [Inde] ; Thambusamy Stalin [Inde]Source :
- Materials science & engineering. C, Materials for biological applications [ 1873-0191 ] ; 2015.
English descriptors
- KwdEn :
- Anthraquinones (chemistry), Citrus sinensis (chemistry), Food Analysis (methods), Fresh Water (analysis), Hydrogen-Ion Concentration, Iron (analysis), Limit of Detection, Sensitivity and Specificity, Spectrometry, Fluorescence (methods), Spectrophotometry, Ultraviolet (methods), Spinacia oleracea (chemistry), beta-Cyclodextrins (chemistry).
- MESH :
- chemical , analysis : Iron.
- chemical , chemistry : Anthraquinones, beta-Cyclodextrins.
- analysis : Fresh Water.
- chemistry : Citrus sinensis, Spinacia oleracea.
- methods : Food Analysis, Spectrometry, Fluorescence, Spectrophotometry, Ultraviolet.
- Hydrogen-Ion Concentration, Limit of Detection, Sensitivity and Specificity.
Abstract
1,5-Dihydroxyanthraquinone (1,5-DHAQ) and in the presence of β-cyclodextrin (β-CD) has been used to find Fe(3+) ion in aqueous solution by UV-visible and fluorescence spectroscopy. The chromo-fluorogenic probe undergoes absorption and emission intensity enhancement upon binding to Fe(3+) ion in pH~7 aqueous solutions. The enhancement of the chemosensor probe is attributed to a 1:1 inclusion complex formation between β-CD and 1,5-DHAQ, which has been utilized as the basis for selective detection of Fe(3+) ion. The chemosensors can be applied to the selectivity and sensitivity analysis which showed that the remarkable sensing limit of detection (LOD) was 7.3∗10(-7)M (β-CD/1,5-DHAQ:Fe(3+)). The proposed chemosensors based on 1,5-DHAQ and in the presence of β-CD has a good selectivity, sensitivity and potential application to the determination of Fe(3+) ion in environmental and biological systems.
DOI: 10.1016/j.msec.2014.11.060
PubMed: 25579901
Affiliations:
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Electronic address: tstalinphd@rediffmail.com.</nlm:affiliation><country xml:lang="fr">Inde</country><wicri:regionArea>Department of Industrial Chemistry, School of Chemical Sciences, Alagappa University, Karaikudi 630 003, Tamilnadu</wicri:regionArea><wicri:noRegion>Tamilnadu</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2015">2015</date><idno type="RBID">pubmed:25579901</idno><idno type="pmid">25579901</idno><idno type="doi">10.1016/j.msec.2014.11.060</idno><idno type="wicri:Area/PubMed/Corpus">000216</idno><idno type="wicri:Area/PubMed/Curation">000216</idno><idno type="wicri:Area/PubMed/Checkpoint">000216</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">A highly selective dual mode detection of Fe3+ ion sensing based on 1,5-dihydroxyanthraquinone in the presence of β-cyclodextrin.</title><author><name sortKey="Mohandoss, Sonaimuthu" sort="Mohandoss, Sonaimuthu" uniqKey="Mohandoss S" first="Sonaimuthu" last="Mohandoss">Sonaimuthu Mohandoss</name><affiliation wicri:level="1"><nlm:affiliation>Department of Industrial Chemistry, School of Chemical Sciences, Alagappa University, Karaikudi 630 003, Tamilnadu, India.</nlm:affiliation><country xml:lang="fr">Inde</country><wicri:regionArea>Department of Industrial Chemistry, School of Chemical Sciences, Alagappa University, Karaikudi 630 003, Tamilnadu</wicri:regionArea><wicri:noRegion>Tamilnadu</wicri:noRegion></affiliation></author><author><name sortKey="Maniyazagan, Munisamy" sort="Maniyazagan, Munisamy" uniqKey="Maniyazagan M" first="Munisamy" last="Maniyazagan">Munisamy Maniyazagan</name><affiliation wicri:level="1"><nlm:affiliation>Department of Industrial Chemistry, School of Chemical Sciences, Alagappa University, Karaikudi 630 003, Tamilnadu, India.</nlm:affiliation><country xml:lang="fr">Inde</country><wicri:regionArea>Department of Industrial Chemistry, School of Chemical Sciences, Alagappa University, Karaikudi 630 003, Tamilnadu</wicri:regionArea><wicri:noRegion>Tamilnadu</wicri:noRegion></affiliation></author><author><name sortKey="Stalin, Thambusamy" sort="Stalin, Thambusamy" uniqKey="Stalin T" first="Thambusamy" last="Stalin">Thambusamy Stalin</name><affiliation wicri:level="1"><nlm:affiliation>Department of Industrial Chemistry, School of Chemical Sciences, Alagappa University, Karaikudi 630 003, Tamilnadu, India. Electronic address: tstalinphd@rediffmail.com.</nlm:affiliation><country xml:lang="fr">Inde</country><wicri:regionArea>Department of Industrial Chemistry, School of Chemical Sciences, Alagappa University, Karaikudi 630 003, Tamilnadu</wicri:regionArea><wicri:noRegion>Tamilnadu</wicri:noRegion></affiliation></author></analytic><series><title level="j">Materials science & engineering. C, Materials for biological applications</title><idno type="eISSN">1873-0191</idno><imprint><date when="2015" type="published">2015</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Anthraquinones (chemistry)</term><term>Citrus sinensis (chemistry)</term><term>Food Analysis (methods)</term><term>Fresh Water (analysis)</term><term>Hydrogen-Ion Concentration</term><term>Iron (analysis)</term><term>Limit of Detection</term><term>Sensitivity and Specificity</term><term>Spectrometry, Fluorescence (methods)</term><term>Spectrophotometry, Ultraviolet (methods)</term><term>Spinacia oleracea (chemistry)</term><term>beta-Cyclodextrins (chemistry)</term></keywords><keywords scheme="MESH" type="chemical" qualifier="analysis" xml:lang="en"><term>Iron</term></keywords><keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Anthraquinones</term><term>beta-Cyclodextrins</term></keywords><keywords scheme="MESH" qualifier="analysis" xml:lang="en"><term>Fresh Water</term></keywords><keywords scheme="MESH" qualifier="chemistry" xml:lang="en"><term>Citrus sinensis</term><term>Spinacia oleracea</term></keywords><keywords scheme="MESH" qualifier="methods" xml:lang="en"><term>Food Analysis</term><term>Spectrometry, Fluorescence</term><term>Spectrophotometry, Ultraviolet</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Hydrogen-Ion Concentration</term><term>Limit of Detection</term><term>Sensitivity and Specificity</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">1,5-Dihydroxyanthraquinone (1,5-DHAQ) and in the presence of β-cyclodextrin (β-CD) has been used to find Fe(3+) ion in aqueous solution by UV-visible and fluorescence spectroscopy. The chromo-fluorogenic probe undergoes absorption and emission intensity enhancement upon binding to Fe(3+) ion in pH~7 aqueous solutions. The enhancement of the chemosensor probe is attributed to a 1:1 inclusion complex formation between β-CD and 1,5-DHAQ, which has been utilized as the basis for selective detection of Fe(3+) ion. The chemosensors can be applied to the selectivity and sensitivity analysis which showed that the remarkable sensing limit of detection (LOD) was 7.3∗10(-7)M (β-CD/1,5-DHAQ:Fe(3+)). The proposed chemosensors based on 1,5-DHAQ and in the presence of β-CD has a good selectivity, sensitivity and potential application to the determination of Fe(3+) ion in environmental and biological systems.</div></front></TEI><pubmed><MedlineCitation Status="MEDLINE" Owner="NLM"><PMID Version="1">25579901</PMID><DateCreated><Year>2015</Year><Month>1</Month><Day>12</Day></DateCreated><DateCompleted><Year>2015</Year><Month>09</Month><Day>21</Day></DateCompleted><DateRevised><Year>2015</Year><Month>1</Month><Day>12</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1873-0191</ISSN><JournalIssue CitedMedium="Internet"><Volume>48</Volume><PubDate><Year>2015</Year><Month>Mar</Month></PubDate></JournalIssue><Title>Materials science & engineering. C, Materials for biological applications</Title><ISOAbbreviation>Mater Sci Eng C Mater Biol Appl</ISOAbbreviation></Journal><ArticleTitle>A highly selective dual mode detection of Fe3+ ion sensing based on 1,5-dihydroxyanthraquinone in the presence of β-cyclodextrin.</ArticleTitle><Pagination><MedlinePgn>94-102</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1016/j.msec.2014.11.060</ELocationID><ELocationID EIdType="pii" ValidYN="Y">S0928-4931(14)00784-X</ELocationID><Abstract><AbstractText>1,5-Dihydroxyanthraquinone (1,5-DHAQ) and in the presence of β-cyclodextrin (β-CD) has been used to find Fe(3+) ion in aqueous solution by UV-visible and fluorescence spectroscopy. The chromo-fluorogenic probe undergoes absorption and emission intensity enhancement upon binding to Fe(3+) ion in pH~7 aqueous solutions. The enhancement of the chemosensor probe is attributed to a 1:1 inclusion complex formation between β-CD and 1,5-DHAQ, which has been utilized as the basis for selective detection of Fe(3+) ion. The chemosensors can be applied to the selectivity and sensitivity analysis which showed that the remarkable sensing limit of detection (LOD) was 7.3∗10(-7)M (β-CD/1,5-DHAQ:Fe(3+)). The proposed chemosensors based on 1,5-DHAQ and in the presence of β-CD has a good selectivity, sensitivity and potential application to the determination of Fe(3+) ion in environmental and biological systems.</AbstractText><CopyrightInformation>Copyright © 2014 Elsevier B.V. All rights reserved.</CopyrightInformation></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Mohandoss</LastName><ForeName>Sonaimuthu</ForeName><Initials>S</Initials><AffiliationInfo><Affiliation>Department of Industrial Chemistry, School of Chemical Sciences, Alagappa University, Karaikudi 630 003, Tamilnadu, India.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Maniyazagan</LastName><ForeName>Munisamy</ForeName><Initials>M</Initials><AffiliationInfo><Affiliation>Department of Industrial Chemistry, School of Chemical Sciences, Alagappa University, Karaikudi 630 003, Tamilnadu, India.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Stalin</LastName><ForeName>Thambusamy</ForeName><Initials>T</Initials><AffiliationInfo><Affiliation>Department of Industrial Chemistry, School of Chemical Sciences, Alagappa University, Karaikudi 630 003, Tamilnadu, India. Electronic address: tstalinphd@rediffmail.com.</Affiliation></AffiliationInfo></Author></AuthorList><Language>ENG</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType><PublicationType UI="D013485">Research Support, Non-U.S. Gov't</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2014</Year><Month>Nov</Month><Day>29</Day></ArticleDate></Article><MedlineJournalInfo><Country>Netherlands</Country><MedlineTA>Mater Sci Eng C Mater Biol Appl</MedlineTA><NlmUniqueID>101484109</NlmUniqueID><ISSNLinking>0928-4931</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="C000601351">1,5-dihydroxyanthraquinone</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D000880">Anthraquinones</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D047392">beta-Cyclodextrins</NameOfSubstance></Chemical><Chemical><RegistryNumber>E1UOL152H7</RegistryNumber><NameOfSubstance UI="D007501">Iron</NameOfSubstance></Chemical><Chemical><RegistryNumber>JV039JZZ3A</RegistryNumber><NameOfSubstance UI="C031215">betadex</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName UI="D000880" MajorTopicYN="N">Anthraquinones</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D032084" MajorTopicYN="N">Citrus sinensis</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D005504" MajorTopicYN="N">Food Analysis</DescriptorName><QualifierName UI="Q000379" MajorTopicYN="N">methods</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D005618" MajorTopicYN="N">Fresh Water</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="N">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D006863" MajorTopicYN="N">Hydrogen-Ion Concentration</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D007501" MajorTopicYN="N">Iron</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="Y">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D057230" MajorTopicYN="N">Limit of Detection</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D012680" MajorTopicYN="N">Sensitivity and Specificity</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D013050" MajorTopicYN="N">Spectrometry, Fluorescence</DescriptorName><QualifierName UI="Q000379" MajorTopicYN="Y">methods</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D013056" MajorTopicYN="N">Spectrophotometry, Ultraviolet</DescriptorName><QualifierName UI="Q000379" MajorTopicYN="N">methods</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D018724" MajorTopicYN="N">Spinacia oleracea</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D047392" MajorTopicYN="N">beta-Cyclodextrins</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName></MeshHeading></MeshHeadingList><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">1,5-Dihydroxyanthraquinone</Keyword><Keyword MajorTopicYN="N">Chemosensors</Keyword><Keyword MajorTopicYN="N">Job's plot analysis</Keyword><Keyword MajorTopicYN="N">Real sample analysis</Keyword><Keyword MajorTopicYN="N">β-Cyclodextrin</Keyword></KeywordList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2014</Year><Month>1</Month><Day>24</Day></PubMedPubDate><PubMedPubDate PubStatus="revised"><Year>2014</Year><Month>10</Month><Day>9</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2014</Year><Month>11</Month><Day>28</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2015</Year><Month>1</Month><Day>13</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2015</Year><Month>1</Month><Day>13</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2015</Year><Month>9</Month><Day>22</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">25579901</ArticleId><ArticleId IdType="pii">S0928-4931(14)00784-X</ArticleId><ArticleId IdType="doi">10.1016/j.msec.2014.11.060</ArticleId></ArticleIdList></PubmedData></pubmed><affiliations><list><country><li>Inde</li></country></list><tree><country name="Inde"><noRegion><name sortKey="Mohandoss, Sonaimuthu" sort="Mohandoss, Sonaimuthu" uniqKey="Mohandoss S" first="Sonaimuthu" last="Mohandoss">Sonaimuthu Mohandoss</name></noRegion><name sortKey="Maniyazagan, Munisamy" sort="Maniyazagan, Munisamy" uniqKey="Maniyazagan M" first="Munisamy" last="Maniyazagan">Munisamy Maniyazagan</name><name sortKey="Stalin, Thambusamy" sort="Stalin, Thambusamy" uniqKey="Stalin T" first="Thambusamy" last="Stalin">Thambusamy Stalin</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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