Chemical ionization by [NO]+ and subsequent collision‐induced dissociation for the selective on‐line detection of monoterpenes and linalool
Identifieur interne : 000795 ( Istex/Corpus ); précédent : 000794; suivant : 000796Chemical ionization by [NO]+ and subsequent collision‐induced dissociation for the selective on‐line detection of monoterpenes and linalool
Auteurs : Juliette Rimetz-Planchon ; Frederik Dhooghe ; Niels Schoon ; Frank Vanhaecke ; Crist AmelynckSource :
- Rapid Communications in Mass Spectrometry [ 0951-4198 ] ; 2011-03-15.
Abstract
Existing on‐line Chemical Ionization Mass Spectrometry (CIMS) techniques for quantification of atmospheric trace gases, such as Biogenic Volatile Organic Compounds (BVOCs), suffer from difficulty in discriminating between isomeric (and more generally isobaric) compounds. Selective detection of these compounds, however, is important because they can affect atmospheric chemistry in different ways, depending on their chemical structure. In this work, Flowing Afterglow Tandem Mass Spectrometry (FATMS) was used to investigate the feasibility of the selective detection of a series of monoterpenes, an oxygenated monoterpene (linalool) and a sesquiterpene (β‐caryophyllene). Ions at m/z 137 from [H3O]+ chemical ionization of α‐pinene, linalool and β‐caryophyllene have been subjected to Collision‐Induced Dissociation (CID) with Ar in the collision cell of a tandem mass spectrometer at center‐of‐mass energies ranging between 0 and 8 eV. Similar fragmentation patterns were obtained, demonstrating that this method is not suited for the selective detection of these compounds. However, CID of the ions at m/z 136 produced via [NO]+ chemical ionization of a series of monoterpenes has revealed promising results. Some tracer‐product ions for individual compounds or groups of compounds were found, which can be considered as a step forward towards selective on‐line monitoring of BVOCs with CIMS techniques. Copyright © 2011 John Wiley & Sons, Ltd.
Url:
DOI: 10.1002/rcm.4901
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ISTEX:03EBA43B8BE6ABBCC6B6A9FBC7F9BF90B779B162Le document en format XML
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Mass Spectrom.</title><idno type="ISSN">0951-4198</idno><idno type="eISSN">1097-0231</idno><imprint><publisher>John Wiley & Sons, Ltd.</publisher><pubPlace>Chichester, UK</pubPlace><date type="published" when="2011-03-15">2011-03-15</date><biblScope unit="volume">25</biblScope><biblScope unit="issue">5</biblScope><biblScope unit="page" from="647">647</biblScope><biblScope unit="page" to="654">654</biblScope></imprint><idno type="ISSN">0951-4198</idno></series><idno type="istex">03EBA43B8BE6ABBCC6B6A9FBC7F9BF90B779B162</idno><idno type="DOI">10.1002/rcm.4901</idno><idno type="ArticleID">RCM4901</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0951-4198</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Existing on‐line Chemical Ionization Mass Spectrometry (CIMS) techniques for quantification of atmospheric trace gases, such as Biogenic Volatile Organic Compounds (BVOCs), suffer from difficulty in discriminating between isomeric (and more generally isobaric) compounds. Selective detection of these compounds, however, is important because they can affect atmospheric chemistry in different ways, depending on their chemical structure. In this work, Flowing Afterglow Tandem Mass Spectrometry (FATMS) was used to investigate the feasibility of the selective detection of a series of monoterpenes, an oxygenated monoterpene (linalool) and a sesquiterpene (β‐caryophyllene). Ions at m/z 137 from [H3O]+ chemical ionization of α‐pinene, linalool and β‐caryophyllene have been subjected to Collision‐Induced Dissociation (CID) with Ar in the collision cell of a tandem mass spectrometer at center‐of‐mass energies ranging between 0 and 8 eV. Similar fragmentation patterns were obtained, demonstrating that this method is not suited for the selective detection of these compounds. However, CID of the ions at m/z 136 produced via [NO]+ chemical ionization of a series of monoterpenes has revealed promising results. Some tracer‐product ions for individual compounds or groups of compounds were found, which can be considered as a step forward towards selective on‐line monitoring of BVOCs with CIMS techniques. Copyright © 2011 John Wiley & Sons, Ltd.</div></front></TEI><istex><corpusName>wiley</corpusName><author><json:item><name>Juliette Rimetz‐Planchon</name><affiliations><json:string>Belgian Institute for Space Aeronomy, Ringlaan 3, B‐1180 Brussels, Belgium</json:string></affiliations></json:item><json:item><name>Frederik Dhooghe</name><affiliations><json:string>Belgian Institute for Space Aeronomy, Ringlaan 3, B‐1180 Brussels, Belgium</json:string><json:string>Department of Analytical Chemistry, Ghent University, Krijgslaan 281 ‐ S12, B‐9000 Ghent, Belgium</json:string></affiliations></json:item><json:item><name>Niels Schoon</name><affiliations><json:string>Belgian Institute for Space Aeronomy, Ringlaan 3, B‐1180 Brussels, Belgium</json:string></affiliations></json:item><json:item><name>Frank Vanhaecke</name><affiliations><json:string>Department of Analytical Chemistry, Ghent University, Krijgslaan 281 ‐ S12, B‐9000 Ghent, Belgium</json:string></affiliations></json:item><json:item><name>Crist Amelynck</name><affiliations><json:string>Belgian Institute for Space Aeronomy, Ringlaan 3, B‐1180 Brussels, Belgium</json:string><json:string>Belgian Institute for Space Aeronomy, Ringlaan 3, B‐1180 Brussels, Belgium.</json:string></affiliations></json:item></author><articleId><json:string>RCM4901</json:string></articleId><language><json:string>eng</json:string></language><originalGenre><json:string>article</json:string></originalGenre><abstract>Existing on‐line Chemical Ionization Mass Spectrometry (CIMS) techniques for quantification of atmospheric trace gases, such as Biogenic Volatile Organic Compounds (BVOCs), suffer from difficulty in discriminating between isomeric (and more generally isobaric) compounds. Selective detection of these compounds, however, is important because they can affect atmospheric chemistry in different ways, depending on their chemical structure. In this work, Flowing Afterglow Tandem Mass Spectrometry (FATMS) was used to investigate the feasibility of the selective detection of a series of monoterpenes, an oxygenated monoterpene (linalool) and a sesquiterpene (β‐caryophyllene). Ions at m/z 137 from [H3O]+ chemical ionization of α‐pinene, linalool and β‐caryophyllene have been subjected to Collision‐Induced Dissociation (CID) with Ar in the collision cell of a tandem mass spectrometer at center‐of‐mass energies ranging between 0 and 8 eV. Similar fragmentation patterns were obtained, demonstrating that this method is not suited for the selective detection of these compounds. However, CID of the ions at m/z 136 produced via [NO]+ chemical ionization of a series of monoterpenes has revealed promising results. Some tracer‐product ions for individual compounds or groups of compounds were found, which can be considered as a step forward towards selective on‐line monitoring of BVOCs with CIMS techniques. Copyright © 2011 John Wiley & Sons, Ltd.</abstract><qualityIndicators><score>7.448</score><pdfVersion>1.3</pdfVersion><pdfPageSize>595 x 791 pts</pdfPageSize><refBibsNative>true</refBibsNative><abstractCharCount>1449</abstractCharCount><pdfWordCount>5895</pdfWordCount><pdfCharCount>37441</pdfCharCount><pdfPageCount>8</pdfPageCount><abstractWordCount>204</abstractWordCount></qualityIndicators><title>Chemical ionization by [NO]+ and subsequent collision‐induced dissociation for the selective on‐line detection of monoterpenes and linalool</title><refBibs><json:item><author><json:item><name>A. Arneth</name></json:item><json:item><name>R. K. Monson</name></json:item><json:item><name>G. Schurgers</name></json:item><json:item><name>U. Niinemets</name></json:item><json:item><name>P. I. 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Mass Spectrom.</title></host><title>Near‐threshold photoionization spectroscopy of the mono‐terpenes limonene and carvone</title></json:item></refBibs><genre><json:string>article</json:string></genre><host><volume>25</volume><publisherId><json:string>RCM</json:string></publisherId><pages><total>8</total><last>654</last><first>647</first></pages><issn><json:string>0951-4198</json:string></issn><issue>5</issue><subject><json:item><value>Research Article</value></json:item></subject><genre><json:string>journal</json:string></genre><language><json:string>unknown</json:string></language><eissn><json:string>1097-0231</json:string></eissn><title>Rapid Communications in Mass Spectrometry</title><doi><json:string>10.1002/(ISSN)1097-0231</json:string></doi></host><categories><wos><json:string>science</json:string><json:string>spectroscopy</json:string><json:string>chemistry, analytical</json:string><json:string>biochemical research methods</json:string></wos><scienceMetrix><json:string>natural sciences</json:string><json:string>chemistry</json:string><json:string>analytical chemistry</json:string></scienceMetrix></categories><publicationDate>2011</publicationDate><copyrightDate>2011</copyrightDate><doi><json:string>10.1002/rcm.4901</json:string></doi><id>03EBA43B8BE6ABBCC6B6A9FBC7F9BF90B779B162</id><score>1</score><fulltext><json:item><extension>pdf</extension><original>true</original><mimetype>application/pdf</mimetype><uri>https://api.istex.fr/document/03EBA43B8BE6ABBCC6B6A9FBC7F9BF90B779B162/fulltext/pdf</uri></json:item><json:item><extension>zip</extension><original>false</original><mimetype>application/zip</mimetype><uri>https://api.istex.fr/document/03EBA43B8BE6ABBCC6B6A9FBC7F9BF90B779B162/fulltext/zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/document/03EBA43B8BE6ABBCC6B6A9FBC7F9BF90B779B162/fulltext/tei"><teiHeader><fileDesc><titleStmt><title level="a" type="main" xml:lang="en">Chemical ionization by [NO]+ and subsequent collision‐induced dissociation for the selective on‐line detection of monoterpenes and linalool</title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher>John Wiley & Sons, Ltd.</publisher><pubPlace>Chichester, UK</pubPlace><availability><p>Copyright © 2011 John Wiley & Sons, Ltd.</p></availability><date>2011</date></publicationStmt><sourceDesc><biblStruct type="inbook"><analytic><title level="a" type="main" xml:lang="en">Chemical ionization by [NO]+ and subsequent collision‐induced dissociation for the selective on‐line detection of monoterpenes and linalool</title><author xml:id="author-1"><persName><forename type="first">Juliette</forename><surname>Rimetz‐Planchon</surname></persName><affiliation>Belgian Institute for Space Aeronomy, Ringlaan 3, B‐1180 Brussels, Belgium</affiliation></author><author xml:id="author-2"><persName><forename type="first">Frederik</forename><surname>Dhooghe</surname></persName><affiliation>Belgian Institute for Space Aeronomy, Ringlaan 3, B‐1180 Brussels, Belgium</affiliation><affiliation>Department of Analytical Chemistry, Ghent University, Krijgslaan 281 ‐ S12, B‐9000 Ghent, Belgium</affiliation></author><author xml:id="author-3"><persName><forename type="first">Niels</forename><surname>Schoon</surname></persName><affiliation>Belgian Institute for Space Aeronomy, Ringlaan 3, B‐1180 Brussels, Belgium</affiliation></author><author xml:id="author-4"><persName><forename type="first">Frank</forename><surname>Vanhaecke</surname></persName><affiliation>Department of Analytical Chemistry, Ghent University, Krijgslaan 281 ‐ S12, B‐9000 Ghent, Belgium</affiliation></author><author xml:id="author-5"><persName><forename type="first">Crist</forename><surname>Amelynck</surname></persName><affiliation>Belgian Institute for Space Aeronomy, Ringlaan 3, B‐1180 Brussels, Belgium</affiliation><affiliation>Belgian Institute for Space Aeronomy, Ringlaan 3, B‐1180 Brussels, Belgium.</affiliation></author></analytic><monogr><title level="j">Rapid Communications in Mass Spectrometry</title><title level="j" type="abbrev">Rapid Commun. Mass Spectrom.</title><idno type="pISSN">0951-4198</idno><idno type="eISSN">1097-0231</idno><idno type="DOI">10.1002/(ISSN)1097-0231</idno><imprint><publisher>John Wiley & Sons, Ltd.</publisher><pubPlace>Chichester, UK</pubPlace><date type="published" when="2011-03-15"></date><biblScope unit="volume">25</biblScope><biblScope unit="issue">5</biblScope><biblScope unit="page" from="647">647</biblScope><biblScope unit="page" to="654">654</biblScope></imprint></monogr><idno type="istex">03EBA43B8BE6ABBCC6B6A9FBC7F9BF90B779B162</idno><idno type="DOI">10.1002/rcm.4901</idno><idno type="ArticleID">RCM4901</idno></biblStruct></sourceDesc></fileDesc><profileDesc><creation><date>2011</date></creation><langUsage><language ident="en">en</language></langUsage><abstract xml:lang="en"><p>Existing on‐line Chemical Ionization Mass Spectrometry (CIMS) techniques for quantification of atmospheric trace gases, such as Biogenic Volatile Organic Compounds (BVOCs), suffer from difficulty in discriminating between isomeric (and more generally isobaric) compounds. Selective detection of these compounds, however, is important because they can affect atmospheric chemistry in different ways, depending on their chemical structure. In this work, Flowing Afterglow Tandem Mass Spectrometry (FATMS) was used to investigate the feasibility of the selective detection of a series of monoterpenes, an oxygenated monoterpene (linalool) and a sesquiterpene (β‐caryophyllene). Ions at m/z 137 from [H3O]+ chemical ionization of α‐pinene, linalool and β‐caryophyllene have been subjected to Collision‐Induced Dissociation (CID) with Ar in the collision cell of a tandem mass spectrometer at center‐of‐mass energies ranging between 0 and 8 eV. Similar fragmentation patterns were obtained, demonstrating that this method is not suited for the selective detection of these compounds. However, CID of the ions at m/z 136 produced via [NO]+ chemical ionization of a series of monoterpenes has revealed promising results. Some tracer‐product ions for individual compounds or groups of compounds were found, which can be considered as a step forward towards selective on‐line monitoring of BVOCs with CIMS techniques. Copyright © 2011 John Wiley & Sons, Ltd.</p></abstract><textClass><keywords scheme="Journal Subject"><list><head>article-category</head><item><term>Research Article</term></item></list></keywords></textClass></profileDesc><revisionDesc><change when="2010-10-13">Received</change><change when="2010-12-06">Registration</change><change when="2011-03-15">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/document/03EBA43B8BE6ABBCC6B6A9FBC7F9BF90B779B162/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Wiley, elements deleted: body"><istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration><istex:document><component version="2.0" type="serialArticle" xml:lang="en"><header><publicationMeta level="product"><publisherInfo><publisherName>John Wiley & Sons, Ltd.</publisherName><publisherLoc>Chichester, UK</publisherLoc></publisherInfo><doi registered="yes">10.1002/(ISSN)1097-0231</doi><issn type="print">0951-4198</issn><issn type="electronic">1097-0231</issn><idGroup><id type="product" value="RCM"></id></idGroup><titleGroup><title type="main" xml:lang="en" sort="RAPID COMMUNICATIONS IN MASS SPECTROMETRY">Rapid Communications in Mass Spectrometry</title><title type="short">Rapid Commun. Mass Spectrom.</title></titleGroup></publicationMeta><publicationMeta level="part" position="50"><doi origin="wiley" registered="yes">10.1002/rcm.v25.5</doi><numberingGroup><numbering type="journalVolume" number="25">25</numbering><numbering type="journalIssue">5</numbering></numberingGroup><coverDate startDate="2011-03-15">15 March 2011</coverDate></publicationMeta><publicationMeta level="unit" type="article" position="110" status="forIssue"><doi origin="wiley" registered="yes">10.1002/rcm.4901</doi><idGroup><id type="unit" value="RCM4901"></id></idGroup><countGroup><count type="pageTotal" number="8"></count></countGroup><titleGroup><title type="articleCategory">Research Article</title><title type="tocHeading1">Research Articles</title></titleGroup><copyright ownership="publisher">Copyright © 2011 John Wiley & Sons, Ltd.</copyright><eventGroup><event type="manuscriptReceived" date="2010-10-13"></event><event type="manuscriptRevised" date="2010-12-06"></event><event type="manuscriptAccepted" date="2010-12-06"></event><event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:2.4.6 mode:FullText mathml2tex" date="2011-02-21"></event><event type="publishedOnlineFinalForm" date="2011-02-04"></event><event type="firstOnline" date="2011-02-04"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.8.8" date="2014-02-08"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-11-03"></event></eventGroup><numberingGroup><numbering type="pageFirst">647</numbering><numbering type="pageLast">654</numbering></numberingGroup><correspondenceTo>Belgian Institute for Space Aeronomy, Ringlaan 3, B‐1180 Brussels, Belgium.</correspondenceTo><linkGroup><link type="toTypesetVersion" href="file:RCM.RCM4901.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="3"></count><count type="tableTotal" number="3"></count><count type="referenceTotal" number="53"></count></countGroup><titleGroup><title type="main" xml:lang="en">Chemical ionization by [NO]<sup>+</sup> and subsequent collision‐induced dissociation for the selective on‐line detection of monoterpenes and linalool</title><title type="short" xml:lang="en">MS/MS studies of monoterpenes and linalool</title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Juliette</givenNames><familyName>Rimetz‐Planchon</familyName></personName></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#af1 #af2"><personName><givenNames>Frederik</givenNames><familyName>Dhooghe</familyName></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Niels</givenNames><familyName>Schoon</familyName></personName></creator><creator xml:id="au4" creatorRole="author" affiliationRef="#af2"><personName><givenNames>Frank</givenNames><familyName>Vanhaecke</familyName></personName></creator><creator xml:id="au5" creatorRole="author" affiliationRef="#af1" corresponding="yes"><personName><givenNames>Crist</givenNames><familyName>Amelynck</familyName></personName><contactDetails><email>Crist.Amelynck@aeronomie.be</email></contactDetails></creator></creators><affiliationGroup><affiliation xml:id="af1" countryCode="BE" type="organization"><unparsedAffiliation>Belgian Institute for Space Aeronomy, Ringlaan 3, B‐1180 Brussels, Belgium</unparsedAffiliation></affiliation><affiliation xml:id="af2" countryCode="BE" type="organization"><unparsedAffiliation>Department of Analytical Chemistry, Ghent University, Krijgslaan 281 ‐ S12, B‐9000 Ghent, Belgium</unparsedAffiliation></affiliation></affiliationGroup><supportingInformation><p> Additional supporting information may be found in the online version of this article. </p><supportingInfoItem><mediaResource alt="supporting information" href="urn-x:wiley:09514198:media:rcm4901:RCM_4901_sm_SuppInfo"></mediaResource><caption>Supplementary Information</caption></supportingInfoItem></supportingInformation><abstractGroup><abstract type="main" xml:lang="en"><title type="main">Abstract</title><p>Existing on‐line Chemical Ionization Mass Spectrometry (CIMS) techniques for quantification of atmospheric trace gases, such as Biogenic Volatile Organic Compounds (BVOCs), suffer from difficulty in discriminating between isomeric (and more generally isobaric) compounds. Selective detection of these compounds, however, is important because they can affect atmospheric chemistry in different ways, depending on their chemical structure. In this work, Flowing Afterglow Tandem Mass Spectrometry (FATMS) was used to investigate the feasibility of the selective detection of a series of monoterpenes, an oxygenated monoterpene (linalool) and a sesquiterpene (β‐caryophyllene). Ions at <i>m/z</i> 137 from [H<sub>3</sub>O]<sup>+</sup> chemical ionization of α‐pinene, linalool and β‐caryophyllene have been subjected to Collision‐Induced Dissociation (CID) with Ar in the collision cell of a tandem mass spectrometer at center‐of‐mass energies ranging between 0 and 8 eV. Similar fragmentation patterns were obtained, demonstrating that this method is not suited for the selective detection of these compounds. However, CID of the ions at <i>m/z</i> 136 produced via [NO]<sup>+</sup> chemical ionization of a series of monoterpenes has revealed promising results. Some tracer‐product ions for individual compounds or groups of compounds were found, which can be considered as a step forward towards selective on‐line monitoring of BVOCs with CIMS techniques. Copyright © 2011 John Wiley & Sons, Ltd.</p></abstract></abstractGroup></contentMeta></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Chemical ionization by [NO]+ and subsequent collision‐induced dissociation for the selective on‐line detection of monoterpenes and linalool</title></titleInfo><titleInfo type="abbreviated" lang="en"><title>MS/MS studies of monoterpenes and linalool</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Chemical ionization by [NO]+ and subsequent collision‐induced dissociation for the selective on‐line detection of monoterpenes and linalool</title></titleInfo><name type="personal"><namePart type="given">Juliette</namePart><namePart type="family">Rimetz‐Planchon</namePart><affiliation>Belgian Institute for Space Aeronomy, Ringlaan 3, B‐1180 Brussels, Belgium</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Frederik</namePart><namePart type="family">Dhooghe</namePart><affiliation>Belgian Institute for Space Aeronomy, Ringlaan 3, B‐1180 Brussels, Belgium</affiliation><affiliation>Department of Analytical Chemistry, Ghent University, Krijgslaan 281 ‐ S12, B‐9000 Ghent, Belgium</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Niels</namePart><namePart type="family">Schoon</namePart><affiliation>Belgian Institute for Space Aeronomy, Ringlaan 3, B‐1180 Brussels, Belgium</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Frank</namePart><namePart type="family">Vanhaecke</namePart><affiliation>Department of Analytical Chemistry, Ghent University, Krijgslaan 281 ‐ S12, B‐9000 Ghent, Belgium</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Crist</namePart><namePart type="family">Amelynck</namePart><affiliation>Belgian Institute for Space Aeronomy, Ringlaan 3, B‐1180 Brussels, Belgium</affiliation><affiliation>Belgian Institute for Space Aeronomy, Ringlaan 3, B‐1180 Brussels, Belgium.</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="article" displayLabel="article"></genre><originInfo><publisher>John Wiley & Sons, Ltd.</publisher><place><placeTerm type="text">Chichester, UK</placeTerm></place><dateIssued encoding="w3cdtf">2011-03-15</dateIssued><dateCaptured encoding="w3cdtf">2010-10-13</dateCaptured><dateValid encoding="w3cdtf">2010-12-06</dateValid><copyrightDate encoding="w3cdtf">2011</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType><extent unit="figures">3</extent><extent unit="tables">3</extent><extent unit="references">53</extent></physicalDescription><abstract lang="en">Existing on‐line Chemical Ionization Mass Spectrometry (CIMS) techniques for quantification of atmospheric trace gases, such as Biogenic Volatile Organic Compounds (BVOCs), suffer from difficulty in discriminating between isomeric (and more generally isobaric) compounds. Selective detection of these compounds, however, is important because they can affect atmospheric chemistry in different ways, depending on their chemical structure. In this work, Flowing Afterglow Tandem Mass Spectrometry (FATMS) was used to investigate the feasibility of the selective detection of a series of monoterpenes, an oxygenated monoterpene (linalool) and a sesquiterpene (β‐caryophyllene). Ions at m/z 137 from [H3O]+ chemical ionization of α‐pinene, linalool and β‐caryophyllene have been subjected to Collision‐Induced Dissociation (CID) with Ar in the collision cell of a tandem mass spectrometer at center‐of‐mass energies ranging between 0 and 8 eV. Similar fragmentation patterns were obtained, demonstrating that this method is not suited for the selective detection of these compounds. However, CID of the ions at m/z 136 produced via [NO]+ chemical ionization of a series of monoterpenes has revealed promising results. Some tracer‐product ions for individual compounds or groups of compounds were found, which can be considered as a step forward towards selective on‐line monitoring of BVOCs with CIMS techniques. Copyright © 2011 John Wiley & Sons, Ltd.</abstract><relatedItem type="host"><titleInfo><title>Rapid Communications in Mass Spectrometry</title></titleInfo><titleInfo type="abbreviated"><title>Rapid Commun. Mass Spectrom.</title></titleInfo><genre type="journal">journal</genre><note type="content"> Additional supporting information may be found in the online version of this article.Supporting Info Item: Supplementary Information - </note><subject><genre>article-category</genre><topic>Research Article</topic></subject><identifier type="ISSN">0951-4198</identifier><identifier type="eISSN">1097-0231</identifier><identifier type="DOI">10.1002/(ISSN)1097-0231</identifier><identifier type="PublisherID">RCM</identifier><part><date>2011</date><detail type="volume"><caption>vol.</caption><number>25</number></detail><detail type="issue"><caption>no.</caption><number>5</number></detail><extent unit="pages"><start>647</start><end>654</end><total>8</total></extent></part></relatedItem><identifier type="istex">03EBA43B8BE6ABBCC6B6A9FBC7F9BF90B779B162</identifier><identifier type="DOI">10.1002/rcm.4901</identifier><identifier type="ArticleID">RCM4901</identifier><accessCondition type="use and reproduction" contentType="copyright">Copyright © 2011 John Wiley & Sons, Ltd.</accessCondition><recordInfo><recordContentSource>WILEY</recordContentSource><recordOrigin>John Wiley & Sons, Ltd.</recordOrigin></recordInfo></mods></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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