Quasi one-dimensional band dispersion and surface metallization in long-range ordered polymeric wires.
Identifieur interne : 002341 ( PubMed/Curation ); précédent : 002340; suivant : 002342Quasi one-dimensional band dispersion and surface metallization in long-range ordered polymeric wires.
Auteurs : Guillaume Vasseur [France] ; Yannick Fagot-Revurat [France] ; Muriel Sicot [France] ; Bertrand Kierren [France] ; Luc Moreau [France] ; Daniel Malterre [France] ; Luis Cardenas [Canada] ; Gianluca Galeotti [Canada] ; Josh Lipton-Duffin [Canada] ; Federico Rosei [Canada] ; Marco Di Giovannantonio [Italie] ; Giorgio Contini [Italie] ; Patrick Le Fèvre [France] ; François Bertran [France] ; Liangbo Liang [États-Unis] ; Vincent Meunier [États-Unis] ; Dmitrii F. Perepichka [Canada]Source :
- Nature communications [ 2041-1723 ] ; 2016.
Abstract
On-surface covalent self-assembly of organic molecules is a very promising bottom-up approach for producing atomically controlled nanostructures. Due to their highly tuneable properties, these structures may be used as building blocks in electronic carbon-based molecular devices. Following this idea, here we report on the electronic structure of an ordered array of poly(para-phenylene) nanowires produced by surface-catalysed dehalogenative reaction. By scanning tunnelling spectroscopy we follow the quantization of unoccupied molecular states as a function of oligomer length, with Fermi level crossing observed for long chains. Angle-resolved photoelectron spectroscopy reveals a quasi-1D valence band as well as a direct gap of 1.15 eV, as the conduction band is partially filled through adsorption on the surface. Tight-binding modelling and ab initio density functional theory calculations lead to a full description of the band structure, including the gap size and charge transfer mechanisms, highlighting a strong substrate-molecule interaction that drives the system into a metallic behaviour.
DOI: 10.1038/ncomms10235
PubMed: 26725974
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F-54506 Vandoeuvre-les-Nancy, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Institut Jean Lamour, UMR 7198, Université de Lorraine/CNRS, BP 70239, F-54506 Vandoeuvre-les-Nancy</wicri:regionArea></affiliation></author><author><name sortKey="Cardenas, Luis" sort="Cardenas, Luis" uniqKey="Cardenas L" first="Luis" last="Cardenas">Luis Cardenas</name><affiliation wicri:level="1"><nlm:affiliation>Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Quebec, Canada J3X 1S2.</nlm:affiliation><country>Canada</country><wicri:regionArea>Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Quebec</wicri:regionArea></affiliation></author><author><name sortKey="Galeotti, Gianluca" sort="Galeotti, Gianluca" uniqKey="Galeotti G" first="Gianluca" last="Galeotti">Gianluca Galeotti</name><affiliation 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Quebec</wicri:regionArea></affiliation></author><author><name sortKey="Rosei, Federico" sort="Rosei, Federico" uniqKey="Rosei F" first="Federico" last="Rosei">Federico Rosei</name><affiliation wicri:level="1"><nlm:affiliation>Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Quebec, Canada J3X 1S2.</nlm:affiliation><country>Canada</country><wicri:regionArea>Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Quebec</wicri:regionArea></affiliation></author><author><name sortKey="Di Giovannantonio, Marco" sort="Di Giovannantonio, Marco" uniqKey="Di Giovannantonio M" first="Marco" last="Di Giovannantonio">Marco Di Giovannantonio</name><affiliation wicri:level="1"><nlm:affiliation>Instituto di Struttura della Materia, CNR, Via Fosso del Cavaliere 100, 00133 Roma, Italy.</nlm:affiliation><country 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xml:lang="fr">France</country><wicri:regionArea>Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin, BP 48, F-91192 Gif sur Yvette</wicri:regionArea></affiliation></author><author><name sortKey="Bertran, Francois" sort="Bertran, Francois" uniqKey="Bertran F" first="François" last="Bertran">François Bertran</name><affiliation wicri:level="1"><nlm:affiliation>Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin, BP 48, F-91192 Gif sur Yvette, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin, BP 48, F-91192 Gif sur Yvette</wicri:regionArea></affiliation></author><author><name sortKey="Liang, Liangbo" sort="Liang, Liangbo" uniqKey="Liang L" first="Liangbo" last="Liang">Liangbo Liang</name><affiliation wicri:level="1"><nlm:affiliation>Department of Physics, Applied Physics, and Astronomy, Rensselaer Polytechnic Institute, Troy, NY 12180, USA.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Physics, Applied Physics, and Astronomy, Rensselaer Polytechnic Institute, Troy, NY 12180</wicri:regionArea></affiliation></author><author><name sortKey="Meunier, Vincent" sort="Meunier, Vincent" uniqKey="Meunier V" first="Vincent" last="Meunier">Vincent Meunier</name><affiliation wicri:level="1"><nlm:affiliation>Department of Physics, Applied Physics, and Astronomy, Rensselaer Polytechnic Institute, Troy, NY 12180, USA.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Physics, Applied Physics, and Astronomy, Rensselaer Polytechnic Institute, Troy, NY 12180</wicri:regionArea></affiliation></author><author><name sortKey="Perepichka, Dmitrii F" sort="Perepichka, Dmitrii F" uniqKey="Perepichka D" first="Dmitrii F" last="Perepichka">Dmitrii F. Perepichka</name><affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, Quebec, Canada H3A 0B8.</nlm:affiliation><country>Canada</country><wicri:regionArea>Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, Quebec</wicri:regionArea></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2016">2016</date><idno type="RBID">pubmed:26725974</idno><idno type="pmid">26725974</idno><idno type="doi">10.1038/ncomms10235</idno><idno type="wicri:Area/PubMed/Corpus">002373</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">002373</idno><idno type="wicri:Area/PubMed/Curation">002341</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">002341</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Quasi one-dimensional band dispersion and surface metallization in long-range ordered polymeric wires.</title><author><name sortKey="Vasseur, Guillaume" sort="Vasseur, Guillaume" uniqKey="Vasseur G" first="Guillaume" last="Vasseur">Guillaume Vasseur</name><affiliation wicri:level="1"><nlm:affiliation>Institut Jean Lamour, UMR 7198, Université de Lorraine/CNRS, BP 70239, F-54506 Vandoeuvre-les-Nancy, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Institut Jean Lamour, UMR 7198, Université de Lorraine/CNRS, BP 70239, F-54506 Vandoeuvre-les-Nancy</wicri:regionArea></affiliation></author><author><name sortKey="Fagot Revurat, Yannick" sort="Fagot Revurat, Yannick" uniqKey="Fagot Revurat Y" first="Yannick" last="Fagot-Revurat">Yannick Fagot-Revurat</name><affiliation wicri:level="1"><nlm:affiliation>Institut Jean Lamour, UMR 7198, Université de Lorraine/CNRS, BP 70239, F-54506 Vandoeuvre-les-Nancy, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Institut Jean Lamour, UMR 7198, Université de Lorraine/CNRS, BP 70239, F-54506 Vandoeuvre-les-Nancy</wicri:regionArea></affiliation></author><author><name sortKey="Sicot, Muriel" sort="Sicot, Muriel" uniqKey="Sicot M" first="Muriel" last="Sicot">Muriel Sicot</name><affiliation wicri:level="1"><nlm:affiliation>Institut Jean Lamour, UMR 7198, Université de Lorraine/CNRS, BP 70239, F-54506 Vandoeuvre-les-Nancy, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Institut Jean Lamour, UMR 7198, Université de Lorraine/CNRS, BP 70239, F-54506 Vandoeuvre-les-Nancy</wicri:regionArea></affiliation></author><author><name sortKey="Kierren, Bertrand" sort="Kierren, Bertrand" uniqKey="Kierren B" first="Bertrand" last="Kierren">Bertrand Kierren</name><affiliation wicri:level="1"><nlm:affiliation>Institut Jean Lamour, UMR 7198, Université de Lorraine/CNRS, BP 70239, F-54506 Vandoeuvre-les-Nancy, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Institut Jean Lamour, UMR 7198, Université de Lorraine/CNRS, BP 70239, F-54506 Vandoeuvre-les-Nancy</wicri:regionArea></affiliation></author><author><name sortKey="Moreau, Luc" sort="Moreau, Luc" uniqKey="Moreau L" first="Luc" last="Moreau">Luc Moreau</name><affiliation wicri:level="1"><nlm:affiliation>Institut Jean Lamour, UMR 7198, Université de Lorraine/CNRS, BP 70239, F-54506 Vandoeuvre-les-Nancy, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Institut Jean Lamour, UMR 7198, Université de Lorraine/CNRS, BP 70239, F-54506 Vandoeuvre-les-Nancy</wicri:regionArea></affiliation></author><author><name sortKey="Malterre, Daniel" sort="Malterre, Daniel" uniqKey="Malterre D" first="Daniel" last="Malterre">Daniel Malterre</name><affiliation wicri:level="1"><nlm:affiliation>Institut Jean Lamour, UMR 7198, Université de Lorraine/CNRS, BP 70239, F-54506 Vandoeuvre-les-Nancy, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Institut Jean Lamour, UMR 7198, Université de Lorraine/CNRS, BP 70239, F-54506 Vandoeuvre-les-Nancy</wicri:regionArea></affiliation></author><author><name sortKey="Cardenas, Luis" sort="Cardenas, Luis" uniqKey="Cardenas L" first="Luis" last="Cardenas">Luis Cardenas</name><affiliation wicri:level="1"><nlm:affiliation>Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Quebec, Canada J3X 1S2.</nlm:affiliation><country>Canada</country><wicri:regionArea>Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Quebec</wicri:regionArea></affiliation></author><author><name sortKey="Galeotti, Gianluca" sort="Galeotti, Gianluca" uniqKey="Galeotti G" first="Gianluca" last="Galeotti">Gianluca Galeotti</name><affiliation wicri:level="1"><nlm:affiliation>Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Quebec, Canada J3X 1S2.</nlm:affiliation><country>Canada</country><wicri:regionArea>Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Quebec</wicri:regionArea></affiliation></author><author><name sortKey="Lipton Duffin, Josh" sort="Lipton Duffin, Josh" uniqKey="Lipton Duffin J" first="Josh" last="Lipton-Duffin">Josh Lipton-Duffin</name><affiliation wicri:level="1"><nlm:affiliation>Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Quebec, Canada J3X 1S2.</nlm:affiliation><country>Canada</country><wicri:regionArea>Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Quebec</wicri:regionArea></affiliation></author><author><name sortKey="Rosei, Federico" sort="Rosei, Federico" uniqKey="Rosei F" first="Federico" last="Rosei">Federico Rosei</name><affiliation wicri:level="1"><nlm:affiliation>Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Quebec, Canada J3X 1S2.</nlm:affiliation><country>Canada</country><wicri:regionArea>Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Quebec</wicri:regionArea></affiliation></author><author><name sortKey="Di Giovannantonio, Marco" sort="Di Giovannantonio, Marco" uniqKey="Di Giovannantonio M" first="Marco" last="Di Giovannantonio">Marco Di Giovannantonio</name><affiliation wicri:level="1"><nlm:affiliation>Instituto di Struttura della Materia, CNR, Via Fosso del Cavaliere 100, 00133 Roma, Italy.</nlm:affiliation><country xml:lang="fr">Italie</country><wicri:regionArea>Instituto di Struttura della Materia, CNR, Via Fosso del Cavaliere 100, 00133 Roma</wicri:regionArea></affiliation></author><author><name sortKey="Contini, Giorgio" sort="Contini, Giorgio" uniqKey="Contini G" first="Giorgio" last="Contini">Giorgio Contini</name><affiliation wicri:level="1"><nlm:affiliation>Instituto di Struttura della Materia, CNR, Via Fosso del Cavaliere 100, 00133 Roma, Italy.</nlm:affiliation><country xml:lang="fr">Italie</country><wicri:regionArea>Instituto di Struttura della Materia, CNR, Via Fosso del Cavaliere 100, 00133 Roma</wicri:regionArea></affiliation></author><author><name sortKey="Le Fevre, Patrick" sort="Le Fevre, Patrick" uniqKey="Le Fevre P" first="Patrick" last="Le Fèvre">Patrick Le Fèvre</name><affiliation wicri:level="1"><nlm:affiliation>Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin, BP 48, F-91192 Gif sur Yvette, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin, BP 48, F-91192 Gif sur Yvette</wicri:regionArea></affiliation></author><author><name sortKey="Bertran, Francois" sort="Bertran, Francois" uniqKey="Bertran F" first="François" last="Bertran">François Bertran</name><affiliation wicri:level="1"><nlm:affiliation>Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin, BP 48, F-91192 Gif sur Yvette, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin, BP 48, F-91192 Gif sur Yvette</wicri:regionArea></affiliation></author><author><name sortKey="Liang, Liangbo" sort="Liang, Liangbo" uniqKey="Liang L" first="Liangbo" last="Liang">Liangbo Liang</name><affiliation wicri:level="1"><nlm:affiliation>Department of Physics, Applied Physics, and Astronomy, Rensselaer Polytechnic Institute, Troy, NY 12180, USA.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Physics, Applied Physics, and Astronomy, Rensselaer Polytechnic Institute, Troy, NY 12180</wicri:regionArea></affiliation></author><author><name sortKey="Meunier, Vincent" sort="Meunier, Vincent" uniqKey="Meunier V" first="Vincent" last="Meunier">Vincent Meunier</name><affiliation wicri:level="1"><nlm:affiliation>Department of Physics, Applied Physics, and Astronomy, Rensselaer Polytechnic Institute, Troy, NY 12180, USA.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Physics, Applied Physics, and Astronomy, Rensselaer Polytechnic Institute, Troy, NY 12180</wicri:regionArea></affiliation></author><author><name sortKey="Perepichka, Dmitrii F" sort="Perepichka, Dmitrii F" uniqKey="Perepichka D" first="Dmitrii F" last="Perepichka">Dmitrii F. Perepichka</name><affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, Quebec, Canada H3A 0B8.</nlm:affiliation><country>Canada</country><wicri:regionArea>Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, Quebec</wicri:regionArea></affiliation></author></analytic><series><title level="j">Nature communications</title><idno type="eISSN">2041-1723</idno><imprint><date when="2016" type="published">2016</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">On-surface covalent self-assembly of organic molecules is a very promising bottom-up approach for producing atomically controlled nanostructures. Due to their highly tuneable properties, these structures may be used as building blocks in electronic carbon-based molecular devices. Following this idea, here we report on the electronic structure of an ordered array of poly(para-phenylene) nanowires produced by surface-catalysed dehalogenative reaction. By scanning tunnelling spectroscopy we follow the quantization of unoccupied molecular states as a function of oligomer length, with Fermi level crossing observed for long chains. Angle-resolved photoelectron spectroscopy reveals a quasi-1D valence band as well as a direct gap of 1.15 eV, as the conduction band is partially filled through adsorption on the surface. Tight-binding modelling and ab initio density functional theory calculations lead to a full description of the band structure, including the gap size and charge transfer mechanisms, highlighting a strong substrate-molecule interaction that drives the system into a metallic behaviour.</div></front></TEI><pubmed><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">26725974</PMID><DateCreated><Year>2016</Year><Month>01</Month><Day>04</Day></DateCreated><DateCompleted><Year>2016</Year><Month>04</Month><Day>25</Day></DateCompleted><DateRevised><Year>2017</Year><Month>07</Month><Day>23</Day></DateRevised><Article PubModel="Electronic"><Journal><ISSN IssnType="Electronic">2041-1723</ISSN><JournalIssue CitedMedium="Internet"><Volume>7</Volume><PubDate><Year>2016</Year><Month>Jan</Month><Day>04</Day></PubDate></JournalIssue><Title>Nature communications</Title><ISOAbbreviation>Nat Commun</ISOAbbreviation></Journal><ArticleTitle>Quasi one-dimensional band dispersion and surface metallization in long-range ordered polymeric wires.</ArticleTitle><Pagination><MedlinePgn>10235</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1038/ncomms10235</ELocationID><Abstract><AbstractText>On-surface covalent self-assembly of organic molecules is a very promising bottom-up approach for producing atomically controlled nanostructures. Due to their highly tuneable properties, these structures may be used as building blocks in electronic carbon-based molecular devices. Following this idea, here we report on the electronic structure of an ordered array of poly(para-phenylene) nanowires produced by surface-catalysed dehalogenative reaction. By scanning tunnelling spectroscopy we follow the quantization of unoccupied molecular states as a function of oligomer length, with Fermi level crossing observed for long chains. Angle-resolved photoelectron spectroscopy reveals a quasi-1D valence band as well as a direct gap of 1.15 eV, as the conduction band is partially filled through adsorption on the surface. Tight-binding modelling and ab initio density functional theory calculations lead to a full description of the band structure, including the gap size and charge transfer mechanisms, highlighting a strong substrate-molecule interaction that drives the system into a metallic behaviour.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Vasseur</LastName><ForeName>Guillaume</ForeName><Initials>G</Initials><AffiliationInfo><Affiliation>Institut Jean Lamour, UMR 7198, Université de Lorraine/CNRS, BP 70239, F-54506 Vandoeuvre-les-Nancy, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Fagot-Revurat</LastName><ForeName>Yannick</ForeName><Initials>Y</Initials><AffiliationInfo><Affiliation>Institut Jean Lamour, UMR 7198, Université de Lorraine/CNRS, BP 70239, F-54506 Vandoeuvre-les-Nancy, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Sicot</LastName><ForeName>Muriel</ForeName><Initials>M</Initials><AffiliationInfo><Affiliation>Institut Jean Lamour, UMR 7198, Université de Lorraine/CNRS, BP 70239, F-54506 Vandoeuvre-les-Nancy, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Kierren</LastName><ForeName>Bertrand</ForeName><Initials>B</Initials><AffiliationInfo><Affiliation>Institut Jean Lamour, UMR 7198, Université de Lorraine/CNRS, BP 70239, F-54506 Vandoeuvre-les-Nancy, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Moreau</LastName><ForeName>Luc</ForeName><Initials>L</Initials><AffiliationInfo><Affiliation>Institut Jean Lamour, UMR 7198, Université de Lorraine/CNRS, BP 70239, F-54506 Vandoeuvre-les-Nancy, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Malterre</LastName><ForeName>Daniel</ForeName><Initials>D</Initials><AffiliationInfo><Affiliation>Institut Jean Lamour, UMR 7198, Université de Lorraine/CNRS, BP 70239, F-54506 Vandoeuvre-les-Nancy, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Cardenas</LastName><ForeName>Luis</ForeName><Initials>L</Initials><AffiliationInfo><Affiliation>Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Quebec, Canada J3X 1S2.</Affiliation></AffiliationInfo><AffiliationInfo><Affiliation>IRCELYON, Institut de Recherches sur la Catalyse et l'Environnement de Lyon, Villeurbanne 69626, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Galeotti</LastName><ForeName>Gianluca</ForeName><Initials>G</Initials><AffiliationInfo><Affiliation>Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Quebec, Canada J3X 1S2.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Lipton-Duffin</LastName><ForeName>Josh</ForeName><Initials>J</Initials><AffiliationInfo><Affiliation>Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Quebec, Canada J3X 1S2.</Affiliation></AffiliationInfo><AffiliationInfo><Affiliation>Institute for Future Environments, Queensland University of Technology (QUT), 2 George Street, Brisbane, Queensland 4001, Australia.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Rosei</LastName><ForeName>Federico</ForeName><Initials>F</Initials><AffiliationInfo><Affiliation>Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Quebec, Canada J3X 1S2.</Affiliation></AffiliationInfo><AffiliationInfo><Affiliation>Institute for Fundamental and Frontier Science, University of Electronic Science and Technology of China, Chengdu 610054, China.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Di Giovannantonio</LastName><ForeName>Marco</ForeName><Initials>M</Initials><AffiliationInfo><Affiliation>Instituto di Struttura della Materia, CNR, Via Fosso del Cavaliere 100, 00133 Roma, Italy.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Contini</LastName><ForeName>Giorgio</ForeName><Initials>G</Initials><AffiliationInfo><Affiliation>Instituto di Struttura della Materia, CNR, Via Fosso del Cavaliere 100, 00133 Roma, Italy.</Affiliation></AffiliationInfo><AffiliationInfo><Affiliation>Physics Department, University of Rome 'Tor Vergata', Via della Ricerca Scientifica 1, I-00133 Roma, Italy.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Le Fèvre</LastName><ForeName>Patrick</ForeName><Initials>P</Initials><AffiliationInfo><Affiliation>Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin, BP 48, F-91192 Gif sur Yvette, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Bertran</LastName><ForeName>François</ForeName><Initials>F</Initials><AffiliationInfo><Affiliation>Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin, BP 48, F-91192 Gif sur Yvette, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Liang</LastName><ForeName>Liangbo</ForeName><Initials>L</Initials><Identifier Source="ORCID">http://orcid.org/0000-0003-1199-0049</Identifier><AffiliationInfo><Affiliation>Department of Physics, Applied Physics, and Astronomy, Rensselaer Polytechnic Institute, Troy, NY 12180, USA.</Affiliation></AffiliationInfo><AffiliationInfo><Affiliation>Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Meunier</LastName><ForeName>Vincent</ForeName><Initials>V</Initials><AffiliationInfo><Affiliation>Department of Physics, Applied Physics, and Astronomy, Rensselaer Polytechnic Institute, Troy, NY 12180, USA.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Perepichka</LastName><ForeName>Dmitrii F</ForeName><Initials>DF</Initials><AffiliationInfo><Affiliation>Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, Quebec, Canada H3A 0B8.</Affiliation></AffiliationInfo></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType><PublicationType UI="D013485">Research Support, Non-U.S. Gov't</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2016</Year><Month>01</Month><Day>04</Day></ArticleDate></Article><MedlineJournalInfo><Country>England</Country><MedlineTA>Nat Commun</MedlineTA><NlmUniqueID>101528555</NlmUniqueID><ISSNLinking>2041-1723</ISSNLinking></MedlineJournalInfo><CommentsCorrectionsList><CommentsCorrections RefType="Cites"><RefSource>Nat Chem. 2012 Jan 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