The Dynamic Surface Tension of Water.
Identifieur interne : 000E51 ( PubMed/Curation ); précédent : 000E50; suivant : 000E52The Dynamic Surface Tension of Water.
Auteurs : Ines M. Hauner [Pays-Bas] ; Antoine Deblais [France] ; James K. Beattie [Australie] ; Hamid Kellay [France] ; Daniel Bonn [Pays-Bas]Source :
- The journal of physical chemistry letters [ 1948-7185 ] ; 2017.
Abstract
The surface tension of water is an important parameter for many biological or industrial processes, and roughly a factor of 3 higher than that of nonpolar liquids such as oils, which is usually attributed to hydrogen bonding and dipolar interactions. Here we show by studying the formation of water drops that the surface tension of a freshly created water surface is even higher (∼90 mN m(-1)) than under equilibrium conditions (∼72 mN m(-1)) with a relaxation process occurring on a long time scale (∼1 ms). Dynamic adsorption effects of protons or hydroxides may be at the origin of this dynamic surface tension. However, changing the pH does not significantly change the dynamic surface tension. It also seems unlikely that hydrogen bonding or dipole orientation effects play any role at the relatively long time scale probed in the experiments.
DOI: 10.1021/acs.jpclett.7b00267
PubMed: 28301160
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Beattie</name><affiliation wicri:level="1"><nlm:affiliation>School of Chemistry, University of Sydney , Sydney, New South Wales 2006, Australia.</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>School of Chemistry, University of Sydney , Sydney, New South Wales 2006</wicri:regionArea></affiliation></author><author><name sortKey="Kellay, Hamid" sort="Kellay, Hamid" uniqKey="Kellay H" first="Hamid" last="Kellay">Hamid Kellay</name><affiliation wicri:level="1"><nlm:affiliation>Laboratoire Ondes et Matière d'Aquitaine (UMR 5798 CNRS), University of Bordeaux , 351 cours de la Libération, 33405 Talence, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire Ondes et Matière d'Aquitaine (UMR 5798 CNRS), University of Bordeaux , 351 cours de la Libération, 33405 Talence</wicri:regionArea></affiliation></author><author><name sortKey="Bonn, Daniel" sort="Bonn, Daniel" uniqKey="Bonn D" first="Daniel" last="Bonn">Daniel Bonn</name><affiliation wicri:level="1"><nlm:affiliation>van der Waals-Zeeman Institute, University of Amsterdam , 1098XH Amsterdam, The Netherlands.</nlm:affiliation><country xml:lang="fr">Pays-Bas</country><wicri:regionArea>van der Waals-Zeeman Institute, University of Amsterdam , 1098XH Amsterdam</wicri:regionArea></affiliation></author></analytic><series><title level="j">The journal of physical chemistry letters</title><idno type="eISSN">1948-7185</idno><imprint><date when="2017" type="published">2017</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The surface tension of water is an important parameter for many biological or industrial processes, and roughly a factor of 3 higher than that of nonpolar liquids such as oils, which is usually attributed to hydrogen bonding and dipolar interactions. Here we show by studying the formation of water drops that the surface tension of a freshly created water surface is even higher (∼90 mN m(-1)) than under equilibrium conditions (∼72 mN m(-1)) with a relaxation process occurring on a long time scale (∼1 ms). Dynamic adsorption effects of protons or hydroxides may be at the origin of this dynamic surface tension. However, changing the pH does not significantly change the dynamic surface tension. It also seems unlikely that hydrogen bonding or dipole orientation effects play any role at the relatively long time scale probed in the experiments.</div></front></TEI><pubmed><MedlineCitation Status="In-Data-Review" Owner="NLM"><PMID Version="1">28301160</PMID><DateCreated><Year>2017</Year><Month>03</Month><Day>16</Day></DateCreated><DateRevised><Year>2017</Year><Month>04</Month><Day>16</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1948-7185</ISSN><JournalIssue CitedMedium="Internet"><Volume>8</Volume><Issue>7</Issue><PubDate><Year>2017</Year><Month>Apr</Month><Day>06</Day></PubDate></JournalIssue><Title>The journal of physical chemistry letters</Title><ISOAbbreviation>J Phys Chem Lett</ISOAbbreviation></Journal><ArticleTitle>The Dynamic Surface Tension of Water.</ArticleTitle><Pagination><MedlinePgn>1599-1603</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1021/acs.jpclett.7b00267</ELocationID><Abstract><AbstractText>The surface tension of water is an important parameter for many biological or industrial processes, and roughly a factor of 3 higher than that of nonpolar liquids such as oils, which is usually attributed to hydrogen bonding and dipolar interactions. Here we show by studying the formation of water drops that the surface tension of a freshly created water surface is even higher (∼90 mN m(-1)) than under equilibrium conditions (∼72 mN m(-1)) with a relaxation process occurring on a long time scale (∼1 ms). Dynamic adsorption effects of protons or hydroxides may be at the origin of this dynamic surface tension. However, changing the pH does not significantly change the dynamic surface tension. It also seems unlikely that hydrogen bonding or dipole orientation effects play any role at the relatively long time scale probed in the experiments.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Hauner</LastName><ForeName>Ines M</ForeName><Initials>IM</Initials><Identifier Source="ORCID">http://orcid.org/0000-0002-5694-3556</Identifier><AffiliationInfo><Affiliation>van der Waals-Zeeman Institute, University of Amsterdam , 1098XH Amsterdam, The Netherlands.</Affiliation></AffiliationInfo><AffiliationInfo><Affiliation>Chimie ParisTech, PSL Research University, CNRS, Institut de Recherche de Chimie Paris , 75005 Paris, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Deblais</LastName><ForeName>Antoine</ForeName><Initials>A</Initials><AffiliationInfo><Affiliation>Laboratoire Ondes et Matière d'Aquitaine (UMR 5798 CNRS), University of Bordeaux , 351 cours de la Libération, 33405 Talence, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Beattie</LastName><ForeName>James K</ForeName><Initials>JK</Initials><AffiliationInfo><Affiliation>School of Chemistry, University of Sydney , Sydney, New South Wales 2006, Australia.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Kellay</LastName><ForeName>Hamid</ForeName><Initials>H</Initials><AffiliationInfo><Affiliation>Laboratoire Ondes et Matière d'Aquitaine (UMR 5798 CNRS), University of Bordeaux , 351 cours de la Libération, 33405 Talence, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Bonn</LastName><ForeName>Daniel</ForeName><Initials>D</Initials><AffiliationInfo><Affiliation>van der Waals-Zeeman Institute, University of Amsterdam , 1098XH Amsterdam, The Netherlands.</Affiliation></AffiliationInfo></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2017</Year><Month>03</Month><Day>23</Day></ArticleDate></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>J Phys Chem Lett</MedlineTA><NlmUniqueID>101526034</NlmUniqueID><ISSNLinking>1948-7185</ISSNLinking></MedlineJournalInfo><CommentsCorrectionsList><CommentsCorrections RefType="Cites"><RefSource>J Colloid Interface Sci. 1996 Dec 25;184(2):550-63</RefSource><PMID Version="1">8978559</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>Phys Rev E Stat Nonlin Soft Matter Phys. 2012 Jul;86(1 Pt 2):015301</RefSource><PMID Version="1">23005482</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>Environ Sci Technol. 2007 Nov 15;41(22):7609-20</RefSource><PMID Version="1">18075065</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>J Phys Chem B. 2012 Aug 2;116(30):8981-8</RefSource><PMID Version="1">22582761</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>Phys Rev Lett. 2002 Apr 29;88(17):174501</RefSource><PMID Version="1">12005762</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>Phys Rev Lett. 2002 Sep 9;89(11):115505</RefSource><PMID Version="1">12225151</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>Phys Rev E Stat Nonlin Soft Matter Phys. 2007 Mar;75(3 Pt 2):036311</RefSource><PMID Version="1">17500795</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>Proc Natl Acad Sci U S A. 2007 May 1;104(18):7342-7</RefSource><PMID Version="1">17452650</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>J Chem Phys. 2010 Oct 21;133(15):154107</RefSource><PMID Version="1">20969370</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>Phys Rev Lett. 2006 Jul 21;97(3):038301</RefSource><PMID Version="1">16907548</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>Phys Chem Chem Phys. 2008 Aug 28;10(32):4975-80</RefSource><PMID Version="1">18688542</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>J Chem Phys. 2016 May 28;144(20):204705</RefSource><PMID Version="1">27250323</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>J Phys Chem B. 2008 Nov 13;112(45):14230-42</RefSource><PMID Version="1">18942871</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>Phys Rev Lett. 2005 Oct 14;95(16):164504</RefSource><PMID Version="1">16241806</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>Faraday Discuss. 2009;141:31-9; 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