(2) H/(1) H measurements of amphiboles and nominally anhydrous minerals (clinopyroxene, garnet and diamond) using high-temperature continuous flow elemental analyser/pyrolysis/isotope ratio mass spectrometry.
Identifieur interne : 000171 ( PubMed/Curation ); précédent : 000170; suivant : 000172(2) H/(1) H measurements of amphiboles and nominally anhydrous minerals (clinopyroxene, garnet and diamond) using high-temperature continuous flow elemental analyser/pyrolysis/isotope ratio mass spectrometry.
Auteurs : François Fourel [France] ; Christophe Lécuyer [France] ; Attila Demeny [Hongrie] ; Philippe Boulvais [France] ; Lutz Lange [Allemagne] ; Dorrit E. Jacob [Australie] ; Istvan Kovacs [Hongrie]Source :
- Rapid communications in mass spectrometry : RCM [ 1097-0231 ] ; 2017.
Abstract
We have used a high-precision, high-efficiency method for the measurement of the (2) H/(1) H ratios of hydrous silicates (amphiboles) and nominally anhydrous minerals (NAM) such as clinopyroxene, garnet and diamond, which are usually extremely resistant to pyrolysis. This opens up new fields of investigation to better understand the conditions of formation for deep-Earth minerals.
DOI: 10.1002/rcm.7996
PubMed: 28940398
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Jacob</name><affiliation wicri:level="1"><nlm:affiliation>Australian Research Council Centre of Excellence for Core to Crust Fluid Systems and Department of Earth and Planetary Science, Macquarie University, North Ryde, Sydney, NSW2109, Australia.</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>Australian Research Council Centre of Excellence for Core to Crust Fluid Systems and Department of Earth and Planetary Science, Macquarie University, North Ryde, Sydney, NSW2109</wicri:regionArea></affiliation></author><author><name sortKey="Kovacs, Istvan" sort="Kovacs, Istvan" uniqKey="Kovacs I" first="Istvan" last="Kovacs">Istvan Kovacs</name><affiliation wicri:level="1"><nlm:affiliation>Geological and Geophysical Institute of Hungary, Stefánia Street 14, Budapest, H-1143, Hungary.</nlm:affiliation><country xml:lang="fr">Hongrie</country><wicri:regionArea>Geological and Geophysical Institute of Hungary, Stefánia Street 14, Budapest, H-1143</wicri:regionArea></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2017">2017</date><idno type="RBID">pubmed:28940398</idno><idno type="pmid">28940398</idno><idno type="doi">10.1002/rcm.7996</idno><idno type="wicri:Area/PubMed/Corpus">000171</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000171</idno><idno type="wicri:Area/PubMed/Curation">000171</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">000171</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">(2) H/(1) H measurements of amphiboles and nominally anhydrous minerals (clinopyroxene, garnet and diamond) using high-temperature continuous flow elemental analyser/pyrolysis/isotope ratio mass spectrometry.</title><author><name sortKey="Fourel, Francois" sort="Fourel, Francois" uniqKey="Fourel F" first="François" last="Fourel">François Fourel</name><affiliation wicri:level="1"><nlm:affiliation>Laboratoire d'Ecologie des Hydrosystèmes Naturels et Anthropisés LEHNA UMR CNRS 5023, Université Claude Bernard Lyon 1, 3 rue Raphaël Dubois - Bât. Forel, F-69622, Villeurbanne Cedex, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire d'Ecologie des Hydrosystèmes Naturels et Anthropisés LEHNA UMR CNRS 5023, Université Claude Bernard Lyon 1, 3 rue Raphaël Dubois - Bât. Forel, F-69622, Villeurbanne Cedex</wicri:regionArea></affiliation></author><author><name sortKey="Lecuyer, Christophe" sort="Lecuyer, Christophe" uniqKey="Lecuyer C" first="Christophe" last="Lécuyer">Christophe Lécuyer</name><affiliation wicri:level="1"><nlm:affiliation>Laboratoire de Géologie de Lyon "Terre, Planètes Environnement", CNRS UMR 5276, Université Claude Bernard Lyon 1, Ecole Normale Supérieure de Lyon, Campus de la Doua, F-69622, Villeurbanne, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire de Géologie de Lyon "Terre, Planètes Environnement", CNRS UMR 5276, Université Claude Bernard Lyon 1, Ecole Normale Supérieure de Lyon, Campus de la Doua, F-69622, Villeurbanne</wicri:regionArea></affiliation></author><author><name sortKey="Demeny, Attila" sort="Demeny, Attila" uniqKey="Demeny A" first="Attila" last="Demeny">Attila Demeny</name><affiliation wicri:level="1"><nlm:affiliation>Geological and Geophysical Institute of Hungary, Stefánia Street 14, Budapest, H-1143, Hungary.</nlm:affiliation><country xml:lang="fr">Hongrie</country><wicri:regionArea>Geological and Geophysical Institute of Hungary, Stefánia Street 14, Budapest, H-1143</wicri:regionArea></affiliation></author><author><name sortKey="Boulvais, Philippe" sort="Boulvais, Philippe" uniqKey="Boulvais P" first="Philippe" last="Boulvais">Philippe Boulvais</name><affiliation wicri:level="1"><nlm:affiliation>Géosciences Rennes, CNRS UMR 6118, OSUR, Campus de Beaulieu, Université de Rennes 1, 35042, Rennes, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Géosciences Rennes, CNRS UMR 6118, OSUR, Campus de Beaulieu, Université de Rennes 1, 35042, Rennes</wicri:regionArea></affiliation></author><author><name sortKey="Lange, Lutz" sort="Lange, Lutz" uniqKey="Lange L" first="Lutz" last="Lange">Lutz Lange</name><affiliation wicri:level="1"><nlm:affiliation>Elementar Analysensysteme GmbH, Elementar-Straße 1, 63505, Langenselbold, Germany.</nlm:affiliation><country xml:lang="fr">Allemagne</country><wicri:regionArea>Elementar Analysensysteme GmbH, Elementar-Straße 1, 63505, Langenselbold</wicri:regionArea></affiliation></author><author><name sortKey="Jacob, Dorrit E" sort="Jacob, Dorrit E" uniqKey="Jacob D" first="Dorrit E" last="Jacob">Dorrit E. Jacob</name><affiliation wicri:level="1"><nlm:affiliation>Australian Research Council Centre of Excellence for Core to Crust Fluid Systems and Department of Earth and Planetary Science, Macquarie University, North Ryde, Sydney, NSW2109, Australia.</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>Australian Research Council Centre of Excellence for Core to Crust Fluid Systems and Department of Earth and Planetary Science, Macquarie University, North Ryde, Sydney, NSW2109</wicri:regionArea></affiliation></author><author><name sortKey="Kovacs, Istvan" sort="Kovacs, Istvan" uniqKey="Kovacs I" first="Istvan" last="Kovacs">Istvan Kovacs</name><affiliation wicri:level="1"><nlm:affiliation>Geological and Geophysical Institute of Hungary, Stefánia Street 14, Budapest, H-1143, Hungary.</nlm:affiliation><country xml:lang="fr">Hongrie</country><wicri:regionArea>Geological and Geophysical Institute of Hungary, Stefánia Street 14, Budapest, H-1143</wicri:regionArea></affiliation></author></analytic><series><title level="j">Rapid communications in mass spectrometry : RCM</title><idno type="eISSN">1097-0231</idno><imprint><date when="2017" type="published">2017</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">We have used a high-precision, high-efficiency method for the measurement of the (2) H/(1) H ratios of hydrous silicates (amphiboles) and nominally anhydrous minerals (NAM) such as clinopyroxene, garnet and diamond, which are usually extremely resistant to pyrolysis. This opens up new fields of investigation to better understand the conditions of formation for deep-Earth minerals.</div></front></TEI><pubmed><MedlineCitation Status="In-Data-Review" Owner="NLM"><PMID Version="1">28940398</PMID><DateCreated><Year>2017</Year><Month>09</Month><Day>23</Day></DateCreated><DateRevised><Year>2017</Year><Month>11</Month><Day>16</Day></DateRevised><Article PubModel="Print"><Journal><ISSN IssnType="Electronic">1097-0231</ISSN><JournalIssue CitedMedium="Internet"><Volume>31</Volume><Issue>24</Issue><PubDate><Year>2017</Year><Month>Dec</Month><Day>30</Day></PubDate></JournalIssue><Title>Rapid communications in mass spectrometry : RCM</Title><ISOAbbreviation>Rapid Commun. Mass Spectrom.</ISOAbbreviation></Journal><ArticleTitle>(2) H/(1) H measurements of amphiboles and nominally anhydrous minerals (clinopyroxene, garnet and diamond) using high-temperature continuous flow elemental analyser/pyrolysis/isotope ratio mass spectrometry.</ArticleTitle><Pagination><MedlinePgn>2066-2072</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1002/rcm.7996</ELocationID><Abstract><AbstractText Label="RATIONALE" NlmCategory="BACKGROUND">We have used a high-precision, high-efficiency method for the measurement of the (2) H/(1) H ratios of hydrous silicates (amphiboles) and nominally anhydrous minerals (NAM) such as clinopyroxene, garnet and diamond, which are usually extremely resistant to pyrolysis. This opens up new fields of investigation to better understand the conditions of formation for deep-Earth minerals.</AbstractText><AbstractText Label="METHODS" NlmCategory="METHODS">The technique described here involves Isotope Ratio Mass Spectrometry (IRMS) on-line in continuous flow mode with an Elemental Analyser (EA) using "purge and trap" technology rather than separation by conventional packed column gas chromatography (GC). The system is equipped with a special high-temperature furnace reaching 1500°C, with a longer hot zone and improved temperature stability. Emphasis is put on the efficiency of the system to reliably pyrolyse refractory minerals difficult to analyse with other conventional systems.</AbstractText><AbstractText Label="RESULTS" NlmCategory="RESULTS">While conventional systems usually fail to generate hydrogen suitable for isotopic analyses, with the technique presented here we were able to measure (2) H/(1) H ratios from four diamond samples (δ(2) H = -60, -77, -84 and -79‰ V-SMOW; average SD = 4.5‰; n = 2), three garnet samples (δ(2) H from -70 to -63‰), and nine clinopyroxenes (δ(2) H from -92 to -58‰) associated with seven amphiboles (δ(2) H from -76 to -27‰) from single mantle rock.</AbstractText><AbstractText Label="CONCLUSIONS" NlmCategory="CONCLUSIONS">The possibility of using such a system to reliably measure (2) H/(1) H ratios from refractory minerals, which are usually extremely difficult to analyse, offers a new tool of investigation for providing us with unrivaled clues to study the deep interiors of Earth.</AbstractText><CopyrightInformation>Copyright © 2017 John Wiley & Sons, Ltd.</CopyrightInformation></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Fourel</LastName><ForeName>François</ForeName><Initials>F</Initials><Identifier Source="ORCID">http://orcid.org/0000-0003-3094-7003</Identifier><AffiliationInfo><Affiliation>Laboratoire d'Ecologie des Hydrosystèmes Naturels et Anthropisés LEHNA UMR CNRS 5023, Université Claude Bernard Lyon 1, 3 rue Raphaël Dubois - Bât. Forel, F-69622, Villeurbanne Cedex, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Lécuyer</LastName><ForeName>Christophe</ForeName><Initials>C</Initials><AffiliationInfo><Affiliation>Laboratoire de Géologie de Lyon "Terre, Planètes Environnement", CNRS UMR 5276, Université Claude Bernard Lyon 1, Ecole Normale Supérieure de Lyon, Campus de la Doua, F-69622, Villeurbanne, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Demeny</LastName><ForeName>Attila</ForeName><Initials>A</Initials><AffiliationInfo><Affiliation>Geological and Geophysical Institute of Hungary, Stefánia Street 14, Budapest, H-1143, Hungary.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Boulvais</LastName><ForeName>Philippe</ForeName><Initials>P</Initials><AffiliationInfo><Affiliation>Géosciences Rennes, CNRS UMR 6118, OSUR, Campus de Beaulieu, Université de Rennes 1, 35042, Rennes, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Lange</LastName><ForeName>Lutz</ForeName><Initials>L</Initials><AffiliationInfo><Affiliation>Elementar Analysensysteme GmbH, Elementar-Straße 1, 63505, Langenselbold, Germany.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Jacob</LastName><ForeName>Dorrit E</ForeName><Initials>DE</Initials><AffiliationInfo><Affiliation>Australian Research Council Centre of Excellence for Core to Crust Fluid Systems and Department of Earth and Planetary Science, Macquarie University, North Ryde, Sydney, NSW2109, Australia.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Kovacs</LastName><ForeName>Istvan</ForeName><Initials>I</Initials><AffiliationInfo><Affiliation>Geological and Geophysical Institute of Hungary, Stefánia Street 14, Budapest, H-1143, Hungary.</Affiliation></AffiliationInfo></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList></Article><MedlineJournalInfo><Country>England</Country><MedlineTA>Rapid Commun Mass Spectrom</MedlineTA><NlmUniqueID>8802365</NlmUniqueID><ISSNLinking>0951-4198</ISSNLinking></MedlineJournalInfo></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2017</Year><Month>05</Month><Day>16</Day></PubMedPubDate><PubMedPubDate PubStatus="revised"><Year>2017</Year><Month>08</Month><Day>19</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2017</Year><Month>08</Month><Day>24</Day></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2017</Year><Month>9</Month><Day>25</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2017</Year><Month>9</Month><Day>25</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2017</Year><Month>9</Month><Day>24</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">28940398</ArticleId><ArticleId IdType="doi">10.1002/rcm.7996</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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