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Two-coordinate terminal zinc hydride complexes: synthesis, structure and preliminary reactivity studies.

Identifieur interne : 001A26 ( PubMed/Corpus ); précédent : 001A25; suivant : 001A27

Two-coordinate terminal zinc hydride complexes: synthesis, structure and preliminary reactivity studies.

Auteurs : Michael J C. Dawkins ; Ewart Middleton ; Christos E. Kefalidis ; Deepak Dange ; Martin M. Juckel ; Laurent Maron ; Cameron Jones

Source :

Chemical communications (Cambridge, England) [ 1364-548X ] ; 2016.

RBID : pubmed:27499232

Abstract

The first examples of essentially two-coordinate, monomeric zinc hydride complexes, LZnH (L = -N(Ar)(SiR3)) (Ar = C6H2{C(H)Ph2}2R'-2,6,4; R = Me, R' = Pr(i) (L'); R = Pr(i), R' = Me (L*); R = Pr(i), R' = Pr(i) (L(†))) have been prepared and shown by crystallographic studies to have near linear N-Zn-H fragments. The results of computational studies imply that any PhZn interactions in the compounds are weak at best. Preliminary reactivity studies reveal the compounds to be effective for the stoichiometric hydrozincation and catalytic hydrosilylation of carbonyl compounds.

DOI: 10.1039/c6cc05445e
PubMed: 27499232

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pubmed:27499232

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<author><name sortKey="Middleton, Ewart" sort="Middleton, Ewart" uniqKey="Middleton E" first="Ewart" last="Middleton">Ewart Middleton</name>
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<author><name sortKey="Kefalidis, Christos E" sort="Kefalidis, Christos E" uniqKey="Kefalidis C" first="Christos E" last="Kefalidis">Christos E. Kefalidis</name>
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<author><name sortKey="Dange, Deepak" sort="Dange, Deepak" uniqKey="Dange D" first="Deepak" last="Dange">Deepak Dange</name>
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<author><name sortKey="Juckel, Martin M" sort="Juckel, Martin M" uniqKey="Juckel M" first="Martin M" last="Juckel">Martin M. Juckel</name>
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<author><name sortKey="Maron, Laurent" sort="Maron, Laurent" uniqKey="Maron L" first="Laurent" last="Maron">Laurent Maron</name>
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<author><name sortKey="Dange, Deepak" sort="Dange, Deepak" uniqKey="Dange D" first="Deepak" last="Dange">Deepak Dange</name>
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<front><div type="abstract" xml:lang="en">The first examples of essentially two-coordinate, monomeric zinc hydride complexes, LZnH (L = -N(Ar)(SiR3)) (Ar = C6H2{C(H)Ph2}2R'-2,6,4; R = Me, R' = Pr(i) (L'); R = Pr(i), R' = Me (L*); R = Pr(i), R' = Pr(i) (L(†))) have been prepared and shown by crystallographic studies to have near linear N-Zn-H fragments. The results of computational studies imply that any PhZn interactions in the compounds are weak at best. Preliminary reactivity studies reveal the compounds to be effective for the stoichiometric hydrozincation and catalytic hydrosilylation of carbonyl compounds.</div>
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<Abstract><AbstractText>The first examples of essentially two-coordinate, monomeric zinc hydride complexes, LZnH (L = -N(Ar)(SiR3)) (Ar = C6H2{C(H)Ph2}2R'-2,6,4; R = Me, R' = Pr(i) (L'); R = Pr(i), R' = Me (L*); R = Pr(i), R' = Pr(i) (L(†))) have been prepared and shown by crystallographic studies to have near linear N-Zn-H fragments. The results of computational studies imply that any PhZn interactions in the compounds are weak at best. Preliminary reactivity studies reveal the compounds to be effective for the stoichiometric hydrozincation and catalytic hydrosilylation of carbonyl compounds.</AbstractText>
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Two-coordinate terminal zinc hydride complexes: synthesis, structure and preliminary reactivity studies.

Two-coordinate terminal zinc hydride complexes: synthesis, structure and preliminary reactivity studies.

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