Aggregation-Induced Electrochemiluminescence of Platinum(II) Complexes.
Identifieur interne : 000404 ( PubMed/Corpus ); précédent : 000403; suivant : 000405Aggregation-Induced Electrochemiluminescence of Platinum(II) Complexes.
Auteurs : Serena Carrara ; Alessandro Aliprandi ; Conor F. Hogan ; Luisa De ColaSource :
- Journal of the American Chemical Society [ 1520-5126 ] ; 2017.
Abstract
We report the electrochemiluminescence properties of square-planar Pt(II) complexes that result from the formation of supramolecular nanostructures. We define this new phenomenon as aggregation-induced electrochemiluminescence (AIECL). In this system, self-assembly changes the HOMO and LUMO energies, making their population accessible via ECL pathways and leading to the generation of the luminescent excited state. Significantly, the emission from the self-assembled system is the first example of electrochemiluminescence (ECL) of Pt(II) complexes in aqueous solution having higher efficiency than the standard, Ru(bpy)3(2+).The finding can lead to a new generation of bright emitters that can be used as ECL labels.
DOI: 10.1021/jacs.7b07710
PubMed: 28914532
Links to Exploration step
pubmed:28914532Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Aggregation-Induced Electrochemiluminescence of Platinum(II) Complexes.</title>
<author><name sortKey="Carrara, Serena" sort="Carrara, Serena" uniqKey="Carrara S" first="Serena" last="Carrara">Serena Carrara</name>
<affiliation><nlm:affiliation>ISIS & icFRC, Universitè de Strasbourg & CNRS , 8 Allée Gaspard Monge, 67000, Strasbourg, France.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Aliprandi, Alessandro" sort="Aliprandi, Alessandro" uniqKey="Aliprandi A" first="Alessandro" last="Aliprandi">Alessandro Aliprandi</name>
<affiliation><nlm:affiliation>ISIS & icFRC, Universitè de Strasbourg & CNRS , 8 Allée Gaspard Monge, 67000, Strasbourg, France.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Hogan, Conor F" sort="Hogan, Conor F" uniqKey="Hogan C" first="Conor F" last="Hogan">Conor F. Hogan</name>
<affiliation><nlm:affiliation>Departiment of Chemistry and Physics, La Trobe Institute for Molecular Science, La Trobe University , Melbourne, Victoria 3086, Australia.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="De Cola, Luisa" sort="De Cola, Luisa" uniqKey="De Cola L" first="Luisa" last="De Cola">Luisa De Cola</name>
<affiliation><nlm:affiliation>ISIS & icFRC, Universitè de Strasbourg & CNRS , 8 Allée Gaspard Monge, 67000, Strasbourg, France.</nlm:affiliation>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PubMed</idno>
<date when="2017">2017</date>
<idno type="RBID">pubmed:28914532</idno>
<idno type="pmid">28914532</idno>
<idno type="doi">10.1021/jacs.7b07710</idno>
<idno type="wicri:Area/PubMed/Corpus">000404</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000404</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en">Aggregation-Induced Electrochemiluminescence of Platinum(II) Complexes.</title>
<author><name sortKey="Carrara, Serena" sort="Carrara, Serena" uniqKey="Carrara S" first="Serena" last="Carrara">Serena Carrara</name>
<affiliation><nlm:affiliation>ISIS & icFRC, Universitè de Strasbourg & CNRS , 8 Allée Gaspard Monge, 67000, Strasbourg, France.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Aliprandi, Alessandro" sort="Aliprandi, Alessandro" uniqKey="Aliprandi A" first="Alessandro" last="Aliprandi">Alessandro Aliprandi</name>
<affiliation><nlm:affiliation>ISIS & icFRC, Universitè de Strasbourg & CNRS , 8 Allée Gaspard Monge, 67000, Strasbourg, France.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Hogan, Conor F" sort="Hogan, Conor F" uniqKey="Hogan C" first="Conor F" last="Hogan">Conor F. Hogan</name>
<affiliation><nlm:affiliation>Departiment of Chemistry and Physics, La Trobe Institute for Molecular Science, La Trobe University , Melbourne, Victoria 3086, Australia.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="De Cola, Luisa" sort="De Cola, Luisa" uniqKey="De Cola L" first="Luisa" last="De Cola">Luisa De Cola</name>
<affiliation><nlm:affiliation>ISIS & icFRC, Universitè de Strasbourg & CNRS , 8 Allée Gaspard Monge, 67000, Strasbourg, France.</nlm:affiliation>
</affiliation>
</author>
</analytic>
<series><title level="j">Journal of the American Chemical Society</title>
<idno type="eISSN">1520-5126</idno>
<imprint><date when="2017" type="published">2017</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">We report the electrochemiluminescence properties of square-planar Pt(II) complexes that result from the formation of supramolecular nanostructures. We define this new phenomenon as aggregation-induced electrochemiluminescence (AIECL). In this system, self-assembly changes the HOMO and LUMO energies, making their population accessible via ECL pathways and leading to the generation of the luminescent excited state. Significantly, the emission from the self-assembled system is the first example of electrochemiluminescence (ECL) of Pt(II) complexes in aqueous solution having higher efficiency than the standard, Ru(bpy)3(2+).The finding can lead to a new generation of bright emitters that can be used as ECL labels.</div>
</front>
</TEI>
<pubmed><MedlineCitation Status="In-Data-Review" Owner="NLM"><PMID Version="1">28914532</PMID>
<DateCreated><Year>2017</Year>
<Month>09</Month>
<Day>15</Day>
</DateCreated>
<DateRevised><Year>2017</Year>
<Month>10</Month>
<Day>18</Day>
</DateRevised>
<Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1520-5126</ISSN>
<JournalIssue CitedMedium="Internet"><Volume>139</Volume>
<Issue>41</Issue>
<PubDate><Year>2017</Year>
<Month>Oct</Month>
<Day>18</Day>
</PubDate>
</JournalIssue>
<Title>Journal of the American Chemical Society</Title>
<ISOAbbreviation>J. Am. Chem. Soc.</ISOAbbreviation>
</Journal>
<ArticleTitle>Aggregation-Induced Electrochemiluminescence of Platinum(II) Complexes.</ArticleTitle>
<Pagination><MedlinePgn>14605-14610</MedlinePgn>
</Pagination>
<ELocationID EIdType="doi" ValidYN="Y">10.1021/jacs.7b07710</ELocationID>
<Abstract><AbstractText>We report the electrochemiluminescence properties of square-planar Pt(II) complexes that result from the formation of supramolecular nanostructures. We define this new phenomenon as aggregation-induced electrochemiluminescence (AIECL). In this system, self-assembly changes the HOMO and LUMO energies, making their population accessible via ECL pathways and leading to the generation of the luminescent excited state. Significantly, the emission from the self-assembled system is the first example of electrochemiluminescence (ECL) of Pt(II) complexes in aqueous solution having higher efficiency than the standard, Ru(bpy)3(2+).The finding can lead to a new generation of bright emitters that can be used as ECL labels.</AbstractText>
</Abstract>
<AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Carrara</LastName>
<ForeName>Serena</ForeName>
<Initials>S</Initials>
<AffiliationInfo><Affiliation>ISIS & icFRC, Universitè de Strasbourg & CNRS , 8 Allée Gaspard Monge, 67000, Strasbourg, France.</Affiliation>
</AffiliationInfo>
</Author>
<Author ValidYN="Y"><LastName>Aliprandi</LastName>
<ForeName>Alessandro</ForeName>
<Initials>A</Initials>
<AffiliationInfo><Affiliation>ISIS & icFRC, Universitè de Strasbourg & CNRS , 8 Allée Gaspard Monge, 67000, Strasbourg, France.</Affiliation>
</AffiliationInfo>
</Author>
<Author ValidYN="Y"><LastName>Hogan</LastName>
<ForeName>Conor F</ForeName>
<Initials>CF</Initials>
<AffiliationInfo><Affiliation>Departiment of Chemistry and Physics, La Trobe Institute for Molecular Science, La Trobe University , Melbourne, Victoria 3086, Australia.</Affiliation>
</AffiliationInfo>
</Author>
<Author ValidYN="Y"><LastName>De Cola</LastName>
<ForeName>Luisa</ForeName>
<Initials>L</Initials>
<Identifier Source="ORCID">http://orcid.org/0000-0002-2152-6517</Identifier>
<AffiliationInfo><Affiliation>ISIS & icFRC, Universitè de Strasbourg & CNRS , 8 Allée Gaspard Monge, 67000, Strasbourg, France.</Affiliation>
</AffiliationInfo>
<AffiliationInfo><Affiliation>Institute of Nanotechnology, Karlsruhe Institute of Technology , KIT Campus North, Hermann-von-Helmholtz-Platz 1, Eggenstein-Leopoldshafen, 76344, Germany.</Affiliation>
</AffiliationInfo>
</Author>
</AuthorList>
<Language>eng</Language>
<PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType>
</PublicationTypeList>
<ArticleDate DateType="Electronic"><Year>2017</Year>
<Month>10</Month>
<Day>03</Day>
</ArticleDate>
</Article>
<MedlineJournalInfo><Country>United States</Country>
<MedlineTA>J Am Chem Soc</MedlineTA>
<NlmUniqueID>7503056</NlmUniqueID>
<ISSNLinking>0002-7863</ISSNLinking>
</MedlineJournalInfo>
</MedlineCitation>
<PubmedData><History><PubMedPubDate PubStatus="pubmed"><Year>2017</Year>
<Month>9</Month>
<Day>16</Day>
<Hour>6</Hour>
<Minute>0</Minute>
</PubMedPubDate>
<PubMedPubDate PubStatus="medline"><Year>2017</Year>
<Month>9</Month>
<Day>16</Day>
<Hour>6</Hour>
<Minute>0</Minute>
</PubMedPubDate>
<PubMedPubDate PubStatus="entrez"><Year>2017</Year>
<Month>9</Month>
<Day>16</Day>
<Hour>6</Hour>
<Minute>0</Minute>
</PubMedPubDate>
</History>
<PublicationStatus>ppublish</PublicationStatus>
<ArticleIdList><ArticleId IdType="pubmed">28914532</ArticleId>
<ArticleId IdType="doi">10.1021/jacs.7b07710</ArticleId>
</ArticleIdList>
</PubmedData>
</pubmed>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Asie/explor/AustralieFrV1/Data/PubMed/Corpus
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000404 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/PubMed/Corpus/biblio.hfd -nk 000404 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Wicri/Asie |area= AustralieFrV1 |flux= PubMed |étape= Corpus |type= RBID |clé= pubmed:28914532 |texte= Aggregation-Induced Electrochemiluminescence of Platinum(II) Complexes. }}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/PubMed/Corpus/RBID.i -Sk "pubmed:28914532" \ | HfdSelect -Kh $EXPLOR_AREA/Data/PubMed/Corpus/biblio.hfd \ | NlmPubMed2Wicri -a AustralieFrV1
This area was generated with Dilib version V0.6.33. |