Double-Sided Electrochromic Device Based on Metal-Organic Frameworks.
Identifieur interne : 000052 ( PubMed/Corpus ); précédent : 000051; suivant : 000053Double-Sided Electrochromic Device Based on Metal-Organic Frameworks.
Auteurs : Issam Mjejri ; Cara M. Doherty ; Marta Rubio-Martinez ; Glenna L. Drisko ; Aline RougierSource :
- ACS applied materials & interfaces [ 1944-8252 ] ; 2017.
Abstract
Devices displaying controllably tunable optical properties through an applied voltage are attractive for smart glass, mirrors, and displays. Electrochromic material development aims to decrease power consumption while increasing the variety of attainable colors, their brilliance, and their longevity. We report the first electrochromic device constructed from metal organic frameworks (MOFs). Two MOF films, HKUST-1 and ZnMOF-74, are assembled so that the oxidation of one corresponds to the reduction of the other, allowing the two sides of the device to simultaneously change color. These MOF films exhibit cycling stability unrivaled by other MOFs and a significant optical contrast in a lithium-based electrolyte. HKUST-1 reversibly changed from bright blue to light blue and ZnMOF-74 from yellow to brown. The electrochromic device associates the two MOF films via a PMMA-lithium based electrolyte membrane. The color-switching of these MOFs does not arise from an organic-linker redox reaction, signaling unexplored possibilities for electrochromic MOF-based materials.
DOI: 10.1021/acsami.7b13647
PubMed: 29043775
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Doherty</name><affiliation><nlm:affiliation>CSIRO Manufacturing and Minerals , Research Way, Clayton, Victoria 3168, Australia.</nlm:affiliation></affiliation></author><author><name sortKey="Rubio Martinez, Marta" sort="Rubio Martinez, Marta" uniqKey="Rubio Martinez M" first="Marta" last="Rubio-Martinez">Marta Rubio-Martinez</name><affiliation><nlm:affiliation>CSIRO Manufacturing and Minerals , Research Way, Clayton, Victoria 3168, Australia.</nlm:affiliation></affiliation></author><author><name sortKey="Drisko, Glenna L" sort="Drisko, Glenna L" uniqKey="Drisko G" first="Glenna L" last="Drisko">Glenna L. Drisko</name><affiliation><nlm:affiliation>ICMCB, UPR 9048, CNRS , F-33600 Pessac, France.</nlm:affiliation></affiliation></author><author><name sortKey="Rougier, Aline" sort="Rougier, Aline" uniqKey="Rougier A" first="Aline" last="Rougier">Aline Rougier</name><affiliation><nlm:affiliation>ICMCB, UPR 9048, CNRS , F-33600 Pessac, France.</nlm:affiliation></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2017">2017</date><idno type="RBID">pubmed:29043775</idno><idno type="pmid">29043775</idno><idno type="doi">10.1021/acsami.7b13647</idno><idno type="wicri:Area/PubMed/Corpus">000052</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000052</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Double-Sided Electrochromic Device Based on Metal-Organic Frameworks.</title><author><name sortKey="Mjejri, Issam" sort="Mjejri, Issam" uniqKey="Mjejri I" first="Issam" last="Mjejri">Issam Mjejri</name><affiliation><nlm:affiliation>ICMCB, UPR 9048, CNRS , F-33600 Pessac, France.</nlm:affiliation></affiliation></author><author><name sortKey="Doherty, Cara M" sort="Doherty, Cara M" uniqKey="Doherty C" first="Cara M" last="Doherty">Cara M. Doherty</name><affiliation><nlm:affiliation>CSIRO Manufacturing and Minerals , Research Way, Clayton, Victoria 3168, Australia.</nlm:affiliation></affiliation></author><author><name sortKey="Rubio Martinez, Marta" sort="Rubio Martinez, Marta" uniqKey="Rubio Martinez M" first="Marta" last="Rubio-Martinez">Marta Rubio-Martinez</name><affiliation><nlm:affiliation>CSIRO Manufacturing and Minerals , Research Way, Clayton, Victoria 3168, Australia.</nlm:affiliation></affiliation></author><author><name sortKey="Drisko, Glenna L" sort="Drisko, Glenna L" uniqKey="Drisko G" first="Glenna L" last="Drisko">Glenna L. Drisko</name><affiliation><nlm:affiliation>ICMCB, UPR 9048, CNRS , F-33600 Pessac, France.</nlm:affiliation></affiliation></author><author><name sortKey="Rougier, Aline" sort="Rougier, Aline" uniqKey="Rougier A" first="Aline" last="Rougier">Aline Rougier</name><affiliation><nlm:affiliation>ICMCB, UPR 9048, CNRS , F-33600 Pessac, France.</nlm:affiliation></affiliation></author></analytic><series><title level="j">ACS applied materials & interfaces</title><idno type="eISSN">1944-8252</idno><imprint><date when="2017" type="published">2017</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Devices displaying controllably tunable optical properties through an applied voltage are attractive for smart glass, mirrors, and displays. Electrochromic material development aims to decrease power consumption while increasing the variety of attainable colors, their brilliance, and their longevity. We report the first electrochromic device constructed from metal organic frameworks (MOFs). Two MOF films, HKUST-1 and ZnMOF-74, are assembled so that the oxidation of one corresponds to the reduction of the other, allowing the two sides of the device to simultaneously change color. These MOF films exhibit cycling stability unrivaled by other MOFs and a significant optical contrast in a lithium-based electrolyte. HKUST-1 reversibly changed from bright blue to light blue and ZnMOF-74 from yellow to brown. The electrochromic device associates the two MOF films via a PMMA-lithium based electrolyte membrane. The color-switching of these MOFs does not arise from an organic-linker redox reaction, signaling unexplored possibilities for electrochromic MOF-based materials.</div></front></TEI><pubmed><MedlineCitation Status="Publisher" Owner="NLM"><PMID Version="1">29043775</PMID><DateCreated><Year>2017</Year><Month>10</Month><Day>18</Day></DateCreated><DateRevised><Year>2017</Year><Month>11</Month><Day>08</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1944-8252</ISSN><JournalIssue CitedMedium="Internet"><PubDate><Year>2017</Year><Month>Nov</Month><Day>08</Day></PubDate></JournalIssue><Title>ACS applied materials & interfaces</Title><ISOAbbreviation>ACS Appl Mater Interfaces</ISOAbbreviation></Journal><ArticleTitle>Double-Sided Electrochromic Device Based on Metal-Organic Frameworks.</ArticleTitle><ELocationID EIdType="doi" ValidYN="Y">10.1021/acsami.7b13647</ELocationID><Abstract><AbstractText>Devices displaying controllably tunable optical properties through an applied voltage are attractive for smart glass, mirrors, and displays. Electrochromic material development aims to decrease power consumption while increasing the variety of attainable colors, their brilliance, and their longevity. We report the first electrochromic device constructed from metal organic frameworks (MOFs). Two MOF films, HKUST-1 and ZnMOF-74, are assembled so that the oxidation of one corresponds to the reduction of the other, allowing the two sides of the device to simultaneously change color. These MOF films exhibit cycling stability unrivaled by other MOFs and a significant optical contrast in a lithium-based electrolyte. HKUST-1 reversibly changed from bright blue to light blue and ZnMOF-74 from yellow to brown. The electrochromic device associates the two MOF films via a PMMA-lithium based electrolyte membrane. The color-switching of these MOFs does not arise from an organic-linker redox reaction, signaling unexplored possibilities for electrochromic MOF-based materials.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Mjejri</LastName><ForeName>Issam</ForeName><Initials>I</Initials><AffiliationInfo><Affiliation>ICMCB, UPR 9048, CNRS , F-33600 Pessac, France.</Affiliation></AffiliationInfo><AffiliationInfo><Affiliation>ICMCB, UPR 9048, Université de Bordeaux , F-33600 Pessac, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Doherty</LastName><ForeName>Cara M</ForeName><Initials>CM</Initials><AffiliationInfo><Affiliation>CSIRO Manufacturing and Minerals , Research Way, Clayton, Victoria 3168, Australia.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Rubio-Martinez</LastName><ForeName>Marta</ForeName><Initials>M</Initials><AffiliationInfo><Affiliation>CSIRO Manufacturing and Minerals , Research Way, Clayton, Victoria 3168, Australia.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Drisko</LastName><ForeName>Glenna L</ForeName><Initials>GL</Initials><AffiliationInfo><Affiliation>ICMCB, UPR 9048, CNRS , F-33600 Pessac, France.</Affiliation></AffiliationInfo><AffiliationInfo><Affiliation>ICMCB, UPR 9048, Université de Bordeaux , F-33600 Pessac, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Rougier</LastName><ForeName>Aline</ForeName><Initials>A</Initials><Identifier Source="ORCID">http://orcid.org/0000-0002-1340-734X</Identifier><AffiliationInfo><Affiliation>ICMCB, UPR 9048, CNRS , F-33600 Pessac, France.</Affiliation></AffiliationInfo><AffiliationInfo><Affiliation>ICMCB, UPR 9048, Université de Bordeaux , F-33600 Pessac, France.</Affiliation></AffiliationInfo></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2017</Year><Month>11</Month><Day>08</Day></ArticleDate></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>ACS Appl Mater Interfaces</MedlineTA><NlmUniqueID>101504991</NlmUniqueID><ISSNLinking>1944-8244</ISSNLinking></MedlineJournalInfo><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">HKUST-1</Keyword><Keyword MajorTopicYN="N">color switching</Keyword><Keyword MajorTopicYN="N">device</Keyword><Keyword MajorTopicYN="N">electrochromism</Keyword><Keyword MajorTopicYN="N">metal−organic frameworks</Keyword><Keyword MajorTopicYN="N">thin films</Keyword></KeywordList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="pubmed"><Year>2017</Year><Month>10</Month><Day>19</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2017</Year><Month>10</Month><Day>19</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2017</Year><Month>10</Month><Day>19</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>aheadofprint</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">29043775</ArticleId><ArticleId IdType="doi">10.1021/acsami.7b13647</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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