Different Complexation Behavior of P-Functionalized Ferrocene Derivatives Towards SnCl2 , SnCl4 and SnPh2 Cl2 : Auto-ionization and Redox-Type Reactions.
Identifieur interne : 002D15 ( PubMed/Checkpoint ); précédent : 002D14; suivant : 002D16Different Complexation Behavior of P-Functionalized Ferrocene Derivatives Towards SnCl2 , SnCl4 and SnPh2 Cl2 : Auto-ionization and Redox-Type Reactions.
Auteurs : Matthias Gawron ; Christina Dietz ; Michael Lutter ; Andrew Duthie ; Viatcheslav Jouikov ; Klaus Jurkschat [Allemagne]Source :
- Chemistry (Weinheim an der Bergstrasse, Germany) [ 1521-3765 ] ; 2015.
Abstract
The novel phosphonyl-substituted ferrocene derivatives [Fe(η(5) -Cp)(η(5) -C5 H3 {P(O)(O-iPr)2 }2 -1,2)] (Fc(1,2) ) and [Fe{η(5) -C5 H4 P(O)(O-iPr)2 }2 ] (Fc(1,1') ) react with SnCl2 , SnCl4 , and SnPh2 Cl2 , giving the corresponding complexes [(Fc(1,2) )2 SnCl][SnCl3 ] (1), [{(Fc(1,1') )SnCl2 }n ] (2), [(Fc(1,1') )SnCl4 ] (3), [{(Fc(1,1') )SnPh2 Cl2 }n ] (4), and [(Fc(1,2) )SnCl4 ] (5), respectively. The compounds are characterized by elemental analyses, (1) H, (13) C, (31) P, (119) Sn NMR and IR spectroscopy, (31) P and (119) Sn CP-MAS NMR spectroscopy, cyclovoltammetry, electrospray ionization mass spectrometry, and single-crystal as well as powder X-ray diffraction analyses. The experimental work is accompanied by DFT calculations, which help to shed light on the origin for the different reaction behavior of Fc(1,1') and Fc(1,2) towards tin(II) chloride.
DOI: 10.1002/chem.201501999
PubMed: 26480839
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code="subField">44221 Dortmund (Germany)</wicri:noCountry></affiliation></author><author><name sortKey="Lutter, Michael" sort="Lutter, Michael" uniqKey="Lutter M" first="Michael" last="Lutter">Michael Lutter</name><affiliation><nlm:affiliation>Lehrstuhl für Anorganische Chemie II, Fakultät Chemie und Chemische Biologie der Technischen Universität Dortmund, 44221 Dortmund (Germany).</nlm:affiliation><wicri:noCountry code="subField">44221 Dortmund (Germany)</wicri:noCountry></affiliation></author><author><name sortKey="Duthie, Andrew" sort="Duthie, Andrew" uniqKey="Duthie A" first="Andrew" last="Duthie">Andrew Duthie</name><affiliation><nlm:affiliation>School of Life and Environmental Science, Deakin University, Geelong, Victoria 3216 (Australia).</nlm:affiliation><wicri:noCountry code="subField">Victoria 3216 (Australia)</wicri:noCountry></affiliation></author><author><name sortKey="Jouikov, Viatcheslav" sort="Jouikov, Viatcheslav" uniqKey="Jouikov V" first="Viatcheslav" 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(Germany)</wicri:noCountry></affiliation></author><author><name sortKey="Dietz, Christina" sort="Dietz, Christina" uniqKey="Dietz C" first="Christina" last="Dietz">Christina Dietz</name><affiliation><nlm:affiliation>Lehrstuhl für Anorganische Chemie II, Fakultät Chemie und Chemische Biologie der Technischen Universität Dortmund, 44221 Dortmund (Germany).</nlm:affiliation><wicri:noCountry code="subField">44221 Dortmund (Germany)</wicri:noCountry></affiliation></author><author><name sortKey="Lutter, Michael" sort="Lutter, Michael" uniqKey="Lutter M" first="Michael" last="Lutter">Michael Lutter</name><affiliation><nlm:affiliation>Lehrstuhl für Anorganische Chemie II, Fakultät Chemie und Chemische Biologie der Technischen Universität Dortmund, 44221 Dortmund (Germany).</nlm:affiliation><wicri:noCountry code="subField">44221 Dortmund (Germany)</wicri:noCountry></affiliation></author><author><name sortKey="Duthie, Andrew" sort="Duthie, Andrew" uniqKey="Duthie A" first="Andrew" last="Duthie">Andrew Duthie</name><affiliation><nlm:affiliation>School of Life and Environmental Science, Deakin University, Geelong, Victoria 3216 (Australia).</nlm:affiliation><wicri:noCountry code="subField">Victoria 3216 (Australia)</wicri:noCountry></affiliation></author><author><name sortKey="Jouikov, Viatcheslav" sort="Jouikov, Viatcheslav" uniqKey="Jouikov V" first="Viatcheslav" last="Jouikov">Viatcheslav Jouikov</name><affiliation><nlm:affiliation>Molecular Chemistry and Photonics, UMR 6226 ISCR, University of Rennes I, 35042 Rennes (France).</nlm:affiliation><wicri:noCountry code="subField">35042 Rennes (France)</wicri:noCountry></affiliation></author><author><name sortKey="Jurkschat, Klaus" sort="Jurkschat, Klaus" uniqKey="Jurkschat K" first="Klaus" last="Jurkschat">Klaus Jurkschat</name><affiliation wicri:level="1"><nlm:affiliation>Lehrstuhl für Anorganische Chemie II, Fakultät Chemie und Chemische Biologie der Technischen Universität Dortmund, 44221 Dortmund (Germany). klaus.jurkschat@tu-dortmund.de.</nlm:affiliation><country wicri:rule="url">Allemagne</country></affiliation></author></analytic><series><title level="j">Chemistry (Weinheim an der Bergstrasse, Germany)</title><idno type="eISSN">1521-3765</idno><imprint><date when="2015" type="published">2015</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The novel phosphonyl-substituted ferrocene derivatives [Fe(η(5) -Cp)(η(5) -C5 H3 {P(O)(O-iPr)2 }2 -1,2)] (Fc(1,2) ) and [Fe{η(5) -C5 H4 P(O)(O-iPr)2 }2 ] (Fc(1,1') ) react with SnCl2 , SnCl4 , and SnPh2 Cl2 , giving the corresponding complexes [(Fc(1,2) )2 SnCl][SnCl3 ] (1), [{(Fc(1,1') )SnCl2 }n ] (2), [(Fc(1,1') )SnCl4 ] (3), [{(Fc(1,1') )SnPh2 Cl2 }n ] (4), and [(Fc(1,2) )SnCl4 ] (5), respectively. The compounds are characterized by elemental analyses, (1) H, (13) C, (31) P, (119) Sn NMR and IR spectroscopy, (31) P and (119) Sn CP-MAS NMR spectroscopy, cyclovoltammetry, electrospray ionization mass spectrometry, and single-crystal as well as powder X-ray diffraction analyses. The experimental work is accompanied by DFT calculations, which help to shed light on the origin for the different reaction behavior of Fc(1,1') and Fc(1,2) towards tin(II) chloride.</div></front></TEI><pubmed><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">26480839</PMID><DateCreated><Year>2015</Year><Month>10</Month><Day>31</Day></DateCreated><DateCompleted><Year>2016</Year><Month>02</Month><Day>11</Day></DateCompleted><DateRevised><Year>2015</Year><Month>10</Month><Day>31</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1521-3765</ISSN><JournalIssue CitedMedium="Internet"><Volume>21</Volume><Issue>46</Issue><PubDate><Year>2015</Year><Month>Nov</Month><Day>09</Day></PubDate></JournalIssue><Title>Chemistry (Weinheim an der Bergstrasse, Germany)</Title><ISOAbbreviation>Chemistry</ISOAbbreviation></Journal><ArticleTitle>Different Complexation Behavior of P-Functionalized Ferrocene Derivatives Towards SnCl2 , SnCl4 and SnPh2 Cl2 : Auto-ionization and Redox-Type Reactions.</ArticleTitle><Pagination><MedlinePgn>16609-22</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1002/chem.201501999</ELocationID><Abstract><AbstractText>The novel phosphonyl-substituted ferrocene derivatives [Fe(η(5) -Cp)(η(5) -C5 H3 {P(O)(O-iPr)2 }2 -1,2)] (Fc(1,2) ) and [Fe{η(5) -C5 H4 P(O)(O-iPr)2 }2 ] (Fc(1,1') ) react with SnCl2 , SnCl4 , and SnPh2 Cl2 , giving the corresponding complexes [(Fc(1,2) )2 SnCl][SnCl3 ] (1), [{(Fc(1,1') )SnCl2 }n ] (2), [(Fc(1,1') )SnCl4 ] (3), [{(Fc(1,1') )SnPh2 Cl2 }n ] (4), and [(Fc(1,2) )SnCl4 ] (5), respectively. The compounds are characterized by elemental analyses, (1) H, (13) C, (31) P, (119) Sn NMR and IR spectroscopy, (31) P and (119) Sn CP-MAS NMR spectroscopy, cyclovoltammetry, electrospray ionization mass spectrometry, and single-crystal as well as powder X-ray diffraction analyses. The experimental work is accompanied by DFT calculations, which help to shed light on the origin for the different reaction behavior of Fc(1,1') and Fc(1,2) towards tin(II) chloride.</AbstractText><CopyrightInformation>© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</CopyrightInformation></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Gawron</LastName><ForeName>Matthias</ForeName><Initials>M</Initials><AffiliationInfo><Affiliation>Lehrstuhl für Anorganische Chemie II, Fakultät Chemie und Chemische Biologie der Technischen Universität Dortmund, 44221 Dortmund (Germany).</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Dietz</LastName><ForeName>Christina</ForeName><Initials>C</Initials><AffiliationInfo><Affiliation>Lehrstuhl für Anorganische Chemie II, Fakultät Chemie und Chemische Biologie der Technischen Universität Dortmund, 44221 Dortmund (Germany).</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Lutter</LastName><ForeName>Michael</ForeName><Initials>M</Initials><AffiliationInfo><Affiliation>Lehrstuhl für Anorganische Chemie II, Fakultät Chemie und Chemische Biologie der Technischen Universität Dortmund, 44221 Dortmund (Germany).</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Duthie</LastName><ForeName>Andrew</ForeName><Initials>A</Initials><AffiliationInfo><Affiliation>School of Life and Environmental Science, Deakin University, Geelong, Victoria 3216 (Australia).</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Jouikov</LastName><ForeName>Viatcheslav</ForeName><Initials>V</Initials><AffiliationInfo><Affiliation>Molecular Chemistry and Photonics, UMR 6226 ISCR, University of Rennes I, 35042 Rennes (France).</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Jurkschat</LastName><ForeName>Klaus</ForeName><Initials>K</Initials><AffiliationInfo><Affiliation>Lehrstuhl für Anorganische Chemie II, Fakultät Chemie und Chemische Biologie der Technischen Universität Dortmund, 44221 Dortmund (Germany). klaus.jurkschat@tu-dortmund.de.</Affiliation></AffiliationInfo></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2015</Year><Month>10</Month><Day>20</Day></ArticleDate></Article><MedlineJournalInfo><Country>Germany</Country><MedlineTA>Chemistry</MedlineTA><NlmUniqueID>9513783</NlmUniqueID><ISSNLinking>0947-6539</ISSNLinking></MedlineJournalInfo><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">X-ray diffraction</Keyword><Keyword MajorTopicYN="N">density functional calculations</Keyword><Keyword MajorTopicYN="N">ferrocene</Keyword><Keyword MajorTopicYN="N">phosphorus</Keyword><Keyword MajorTopicYN="N">tin</Keyword></KeywordList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2015</Year><Month>05</Month><Day>21</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2015</Year><Month>10</Month><Day>21</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2015</Year><Month>10</Month><Day>21</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2015</Year><Month>10</Month><Day>21</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">26480839</ArticleId><ArticleId IdType="doi">10.1002/chem.201501999</ArticleId></ArticleIdList></PubmedData></pubmed><affiliations><list><country><li>Allemagne</li></country></list><tree><noCountry><name sortKey="Dietz, Christina" sort="Dietz, Christina" uniqKey="Dietz C" first="Christina" last="Dietz">Christina Dietz</name><name sortKey="Duthie, Andrew" sort="Duthie, Andrew" uniqKey="Duthie A" first="Andrew" last="Duthie">Andrew Duthie</name><name sortKey="Gawron, Matthias" sort="Gawron, Matthias" uniqKey="Gawron M" first="Matthias" last="Gawron">Matthias Gawron</name><name sortKey="Jouikov, Viatcheslav" sort="Jouikov, Viatcheslav" uniqKey="Jouikov V" first="Viatcheslav" last="Jouikov">Viatcheslav Jouikov</name><name sortKey="Lutter, Michael" sort="Lutter, Michael" uniqKey="Lutter M" first="Michael" last="Lutter">Michael Lutter</name></noCountry><country name="Allemagne"><noRegion><name sortKey="Jurkschat, Klaus" sort="Jurkschat, Klaus" uniqKey="Jurkschat K" first="Klaus" last="Jurkschat">Klaus Jurkschat</name></noRegion></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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