Enhanced ionic liquid mobility induced by confinement in 1D CNT membranes.
Identifieur interne : 001F38 ( PubMed/Checkpoint ); précédent : 001F37; suivant : 001F39Enhanced ionic liquid mobility induced by confinement in 1D CNT membranes.
Auteurs : Q. Berrod [France] ; F. Ferdeghini [France] ; P. Judeinstein [France] ; N. Genevaz [France] ; R. Ramos [France] ; A. Fournier [France] ; J. Dijon [France] ; J. Ollivier [France] ; S. Rols [France] ; D. Yu [Australie] ; R A Mole [Australie] ; J-M Zanotti [France]Source :
- Nanoscale [ 2040-3372 ] ; 2016.
Abstract
Water confined within carbon nanotubes (CNT) exhibits tremendous enhanced transport properties. Here, we extend this result to ionic liquids (IL) confined in vertically aligned CNT membranes. Under confinement, the IL self-diffusion coefficient is increased by a factor 3 compared to its bulk reference. This could lead to high power battery separators.
DOI: 10.1039/c6nr01445c
PubMed: 27021047
Affiliations:
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Berrod</name><affiliation wicri:level="3"><nlm:affiliation>LLB, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191, Gif-sur-Yvette, France. jmzanotti@cea.fr.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>LLB, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191, Gif-sur-Yvette</wicri:regionArea><placeName><region type="region" nuts="2">Île-de-France</region><settlement type="city">Gif-sur-Yvette</settlement></placeName></affiliation></author><author><name sortKey="Ferdeghini, F" sort="Ferdeghini, F" uniqKey="Ferdeghini F" first="F" last="Ferdeghini">F. Ferdeghini</name><affiliation wicri:level="3"><nlm:affiliation>LLB, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191, Gif-sur-Yvette, France. jmzanotti@cea.fr.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>LLB, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191, Gif-sur-Yvette</wicri:regionArea><placeName><region type="region" nuts="2">Île-de-France</region><settlement type="city">Gif-sur-Yvette</settlement></placeName></affiliation></author><author><name sortKey="Judeinstein, P" sort="Judeinstein, P" uniqKey="Judeinstein P" first="P" last="Judeinstein">P. Judeinstein</name><affiliation wicri:level="3"><nlm:affiliation>LLB, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191, Gif-sur-Yvette, France. jmzanotti@cea.fr.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>LLB, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191, Gif-sur-Yvette</wicri:regionArea><placeName><region type="region" nuts="2">Île-de-France</region><settlement type="city">Gif-sur-Yvette</settlement></placeName></affiliation></author><author><name sortKey="Genevaz, N" sort="Genevaz, N" uniqKey="Genevaz N" first="N" last="Genevaz">N. Genevaz</name><affiliation wicri:level="3"><nlm:affiliation>LLB, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191, Gif-sur-Yvette, France. jmzanotti@cea.fr.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>LLB, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191, Gif-sur-Yvette</wicri:regionArea><placeName><region type="region" nuts="2">Île-de-France</region><settlement type="city">Gif-sur-Yvette</settlement></placeName></affiliation></author><author><name sortKey="Ramos, R" sort="Ramos, R" uniqKey="Ramos R" first="R" last="Ramos">R. Ramos</name><affiliation wicri:level="3"><nlm:affiliation>CEA, LITEN, DTNM, F-38054 Grenoble, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>CEA, LITEN, DTNM, F-38054 Grenoble</wicri:regionArea><placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region><region type="old region" nuts="2">Rhône-Alpes</region><settlement type="city">Grenoble</settlement></placeName></affiliation></author><author><name sortKey="Fournier, A" sort="Fournier, A" uniqKey="Fournier A" first="A" last="Fournier">A. Fournier</name><affiliation wicri:level="3"><nlm:affiliation>CEA, LITEN, DTNM, F-38054 Grenoble, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>CEA, LITEN, DTNM, F-38054 Grenoble</wicri:regionArea><placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region><region type="old region" nuts="2">Rhône-Alpes</region><settlement type="city">Grenoble</settlement></placeName></affiliation></author><author><name sortKey="Dijon, J" sort="Dijon, J" uniqKey="Dijon J" first="J" last="Dijon">J. Dijon</name><affiliation wicri:level="3"><nlm:affiliation>CEA, LITEN, DTNM, F-38054 Grenoble, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>CEA, LITEN, DTNM, F-38054 Grenoble</wicri:regionArea><placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region><region type="old region" nuts="2">Rhône-Alpes</region><settlement type="city">Grenoble</settlement></placeName></affiliation></author><author><name sortKey="Ollivier, J" sort="Ollivier, J" uniqKey="Ollivier J" first="J" last="Ollivier">J. Ollivier</name><affiliation wicri:level="3"><nlm:affiliation>Institut Laue Langevin, F-38002 Grenoble, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Institut Laue Langevin, F-38002 Grenoble</wicri:regionArea><placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region><region type="old region" nuts="2">Rhône-Alpes</region><settlement type="city">Grenoble</settlement></placeName></affiliation></author><author><name sortKey="Rols, S" sort="Rols, S" uniqKey="Rols S" first="S" last="Rols">S. Rols</name><affiliation wicri:level="3"><nlm:affiliation>Institut Laue Langevin, F-38002 Grenoble, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Institut Laue Langevin, F-38002 Grenoble</wicri:regionArea><placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region><region type="old region" nuts="2">Rhône-Alpes</region><settlement type="city">Grenoble</settlement></placeName></affiliation></author><author><name sortKey="Yu, D" sort="Yu, D" uniqKey="Yu D" first="D" last="Yu">D. Yu</name><affiliation wicri:level="1"><nlm:affiliation>ANSTO, Bragg Institute Lucas Heights, NSW 2234, Australia.</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>ANSTO, Bragg Institute Lucas Heights, NSW 2234</wicri:regionArea><wicri:noRegion>NSW 2234</wicri:noRegion></affiliation></author><author><name sortKey="Mole, R A" sort="Mole, R A" uniqKey="Mole R" first="R A" last="Mole">R A Mole</name><affiliation wicri:level="1"><nlm:affiliation>ANSTO, Bragg Institute Lucas Heights, NSW 2234, Australia.</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>ANSTO, Bragg Institute Lucas Heights, NSW 2234</wicri:regionArea><wicri:noRegion>NSW 2234</wicri:noRegion></affiliation></author><author><name sortKey="Zanotti, J M" sort="Zanotti, J M" uniqKey="Zanotti J" first="J-M" last="Zanotti">J-M Zanotti</name><affiliation wicri:level="1"><nlm:affiliation>LLB, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191, Gif-sur-Yvette, France. jmzanotti@cea.fr.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>LLB, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191, Gif-sur-Yvette</wicri:regionArea><wicri:noRegion>91191, Gif-sur-Yvette</wicri:noRegion><wicri:noRegion>91191, Gif-sur-Yvette</wicri:noRegion></affiliation></author></analytic><series><title level="j">Nanoscale</title><idno type="eISSN">2040-3372</idno><imprint><date when="2016" type="published">2016</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Water confined within carbon nanotubes (CNT) exhibits tremendous enhanced transport properties. Here, we extend this result to ionic liquids (IL) confined in vertically aligned CNT membranes. Under confinement, the IL self-diffusion coefficient is increased by a factor 3 compared to its bulk reference. This could lead to high power battery separators.</div></front></TEI><pubmed><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">27021047</PMID><DateCreated><Year>2016</Year><Month>04</Month><Day>14</Day></DateCreated><DateCompleted><Year>2016</Year><Month>12</Month><Day>13</Day></DateCompleted><DateRevised><Year>2016</Year><Month>12</Month><Day>30</Day></DateRevised><Article PubModel="Print"><Journal><ISSN IssnType="Electronic">2040-3372</ISSN><JournalIssue CitedMedium="Internet"><Volume>8</Volume><Issue>15</Issue><PubDate><Year>2016</Year><Month>Apr</Month><Day>21</Day></PubDate></JournalIssue><Title>Nanoscale</Title><ISOAbbreviation>Nanoscale</ISOAbbreviation></Journal><ArticleTitle>Enhanced ionic liquid mobility induced by confinement in 1D CNT membranes.</ArticleTitle><Pagination><MedlinePgn>7845-8</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1039/c6nr01445c</ELocationID><Abstract><AbstractText>Water confined within carbon nanotubes (CNT) exhibits tremendous enhanced transport properties. Here, we extend this result to ionic liquids (IL) confined in vertically aligned CNT membranes. Under confinement, the IL self-diffusion coefficient is increased by a factor 3 compared to its bulk reference. This could lead to high power battery separators.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Berrod</LastName><ForeName>Q</ForeName><Initials>Q</Initials><AffiliationInfo><Affiliation>LLB, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191, Gif-sur-Yvette, France. jmzanotti@cea.fr.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Ferdeghini</LastName><ForeName>F</ForeName><Initials>F</Initials><AffiliationInfo><Affiliation>LLB, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191, Gif-sur-Yvette, France. jmzanotti@cea.fr.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Judeinstein</LastName><ForeName>P</ForeName><Initials>P</Initials><AffiliationInfo><Affiliation>LLB, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191, Gif-sur-Yvette, France. jmzanotti@cea.fr.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Genevaz</LastName><ForeName>N</ForeName><Initials>N</Initials><AffiliationInfo><Affiliation>LLB, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191, Gif-sur-Yvette, France. jmzanotti@cea.fr.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Ramos</LastName><ForeName>R</ForeName><Initials>R</Initials><AffiliationInfo><Affiliation>CEA, LITEN, DTNM, F-38054 Grenoble, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Fournier</LastName><ForeName>A</ForeName><Initials>A</Initials><AffiliationInfo><Affiliation>CEA, LITEN, DTNM, F-38054 Grenoble, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Dijon</LastName><ForeName>J</ForeName><Initials>J</Initials><AffiliationInfo><Affiliation>CEA, LITEN, DTNM, F-38054 Grenoble, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Ollivier</LastName><ForeName>J</ForeName><Initials>J</Initials><AffiliationInfo><Affiliation>Institut Laue Langevin, F-38002 Grenoble, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Rols</LastName><ForeName>S</ForeName><Initials>S</Initials><AffiliationInfo><Affiliation>Institut Laue Langevin, F-38002 Grenoble, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Yu</LastName><ForeName>D</ForeName><Initials>D</Initials><AffiliationInfo><Affiliation>ANSTO, Bragg Institute Lucas Heights, NSW 2234, Australia.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Mole</LastName><ForeName>R A</ForeName><Initials>RA</Initials><AffiliationInfo><Affiliation>ANSTO, Bragg Institute Lucas Heights, NSW 2234, Australia.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Zanotti</LastName><ForeName>J-M</ForeName><Initials>JM</Initials><AffiliationInfo><Affiliation>LLB, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191, Gif-sur-Yvette, France. jmzanotti@cea.fr.</Affiliation></AffiliationInfo></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType><PublicationType UI="D013485">Research Support, Non-U.S. Gov't</PublicationType></PublicationTypeList></Article><MedlineJournalInfo><Country>England</Country><MedlineTA>Nanoscale</MedlineTA><NlmUniqueID>101525249</NlmUniqueID><ISSNLinking>2040-3364</ISSNLinking></MedlineJournalInfo><CitationSubset>IM</CitationSubset></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="entrez"><Year>2016</Year><Month>3</Month><Day>30</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2016</Year><Month>3</Month><Day>30</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2016</Year><Month>3</Month><Day>30</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">27021047</ArticleId><ArticleId IdType="doi">10.1039/c6nr01445c</ArticleId></ArticleIdList></PubmedData></pubmed><affiliations><list><country><li>Australie</li><li>France</li></country><region><li>Auvergne-Rhône-Alpes</li><li>Rhône-Alpes</li><li>Île-de-France</li></region><settlement><li>Gif-sur-Yvette</li><li>Grenoble</li></settlement></list><tree><country name="France"><region name="Île-de-France"><name sortKey="Berrod, Q" sort="Berrod, Q" uniqKey="Berrod Q" first="Q" last="Berrod">Q. Berrod</name></region><name sortKey="Dijon, J" sort="Dijon, J" uniqKey="Dijon J" first="J" last="Dijon">J. Dijon</name><name sortKey="Ferdeghini, F" sort="Ferdeghini, F" uniqKey="Ferdeghini F" first="F" last="Ferdeghini">F. Ferdeghini</name><name sortKey="Fournier, A" sort="Fournier, A" uniqKey="Fournier A" first="A" last="Fournier">A. Fournier</name><name sortKey="Genevaz, N" sort="Genevaz, N" uniqKey="Genevaz N" first="N" last="Genevaz">N. Genevaz</name><name sortKey="Judeinstein, P" sort="Judeinstein, P" uniqKey="Judeinstein P" first="P" last="Judeinstein">P. Judeinstein</name><name sortKey="Ollivier, J" sort="Ollivier, J" uniqKey="Ollivier J" first="J" last="Ollivier">J. Ollivier</name><name sortKey="Ramos, R" sort="Ramos, R" uniqKey="Ramos R" first="R" last="Ramos">R. Ramos</name><name sortKey="Rols, S" sort="Rols, S" uniqKey="Rols S" first="S" last="Rols">S. Rols</name><name sortKey="Zanotti, J M" sort="Zanotti, J M" uniqKey="Zanotti J" first="J-M" last="Zanotti">J-M Zanotti</name></country><country name="Australie"><noRegion><name sortKey="Yu, D" sort="Yu, D" uniqKey="Yu D" first="D" last="Yu">D. Yu</name></noRegion><name sortKey="Mole, R A" sort="Mole, R A" uniqKey="Mole R" first="R A" last="Mole">R A Mole</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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