Size and Composition Effects in Sb-Carbon Nanocomposites for Sodium-Ion Batteries.
Identifieur interne : 001681 ( PubMed/Checkpoint ); précédent : 001680; suivant : 001682Size and Composition Effects in Sb-Carbon Nanocomposites for Sodium-Ion Batteries.
Auteurs : Thrinathreddy Ramireddy [Australie] ; Neeraj Sharma [Australie] ; Tan Xing [Australie] ; Ying Chen [Australie] ; Jeremie Leforestier [Australie] ; Alexey M. Glushenkov [Australie]Source :
- ACS applied materials & interfaces [ 1944-8252 ] ; 2016.
Abstract
Sodium-ion batteries are in the spotlight as viable alternatives to lithium-ion batteries in stationary storage and power grid applications. Among possible anode materials, Sb is one of the interesting candidates due to a combination of battery-type potential plateaus in the charge-discharge profiles, high capacity (theoretical capacity of 660 mAh g(-1)), and demonstrated good cyclic stability. The influence of Sb particle size (particularly at the nanoscale range) and the composition of Sb-carbon composites on the electrode performance, stability, and charge storage mechanism is systematically evaluated here for the first time. A range of Sb-carbon nanocomposites with varied Sb particle size (between 50 and ∼1 nm) are studied. The control of the particle size is achieved via varying the carbon and Sb weight ratio in the precursors. The shape of charge-discharge profiles, hysteresis, and the difference in cyclic stabilities and rate performance are analyzed. The nanocomposite with the smallest particle size (∼1 nm) and the largest carbon content provides the most stable cyclic behavior and a better rate capability but suffers from an increased hysteresis between charge and discharge curves. In situ synchrotron X-ray diffraction experiments indicate that the storage mechanism in the Sb-carbon nanocomposites containing Sb nanoparticles is different from the electrodes with bulkier, micron-sized Sb particles, and the electrochemical reaction proceeds through a number of crystalline intermediates.
DOI: 10.1021/acsami.6b09619
PubMed: 27753471
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Glushenkov</name><affiliation wicri:level="1"><nlm:affiliation>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216, Australia.</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216</wicri:regionArea><wicri:noRegion>Victoria 3216</wicri:noRegion></affiliation></author></analytic><series><title level="j">ACS applied materials & interfaces</title><idno type="eISSN">1944-8252</idno><imprint><date when="2016" type="published">2016</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Sodium-ion batteries are in the spotlight as viable alternatives to lithium-ion batteries in stationary storage and power grid applications. Among possible anode materials, Sb is one of the interesting candidates due to a combination of battery-type potential plateaus in the charge-discharge profiles, high capacity (theoretical capacity of 660 mAh g(-1)), and demonstrated good cyclic stability. The influence of Sb particle size (particularly at the nanoscale range) and the composition of Sb-carbon composites on the electrode performance, stability, and charge storage mechanism is systematically evaluated here for the first time. A range of Sb-carbon nanocomposites with varied Sb particle size (between 50 and ∼1 nm) are studied. The control of the particle size is achieved via varying the carbon and Sb weight ratio in the precursors. The shape of charge-discharge profiles, hysteresis, and the difference in cyclic stabilities and rate performance are analyzed. The nanocomposite with the smallest particle size (∼1 nm) and the largest carbon content provides the most stable cyclic behavior and a better rate capability but suffers from an increased hysteresis between charge and discharge curves. In situ synchrotron X-ray diffraction experiments indicate that the storage mechanism in the Sb-carbon nanocomposites containing Sb nanoparticles is different from the electrodes with bulkier, micron-sized Sb particles, and the electrochemical reaction proceeds through a number of crystalline intermediates.</div></front></TEI><pubmed><MedlineCitation Status="In-Data-Review" Owner="NLM"><PMID Version="1">27753471</PMID><DateCreated><Year>2016</Year><Month>10</Month><Day>18</Day></DateCreated><DateRevised><Year>2016</Year><Month>12</Month><Day>09</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1944-8252</ISSN><JournalIssue CitedMedium="Internet"><Volume>8</Volume><Issue>44</Issue><PubDate><Year>2016</Year><Month>Nov</Month><Day>09</Day></PubDate></JournalIssue><Title>ACS applied materials & interfaces</Title><ISOAbbreviation>ACS Appl Mater Interfaces</ISOAbbreviation></Journal><ArticleTitle>Size and Composition Effects in Sb-Carbon Nanocomposites for Sodium-Ion Batteries.</ArticleTitle><Pagination><MedlinePgn>30152-30164</MedlinePgn></Pagination><Abstract><AbstractText>Sodium-ion batteries are in the spotlight as viable alternatives to lithium-ion batteries in stationary storage and power grid applications. Among possible anode materials, Sb is one of the interesting candidates due to a combination of battery-type potential plateaus in the charge-discharge profiles, high capacity (theoretical capacity of 660 mAh g(-1)), and demonstrated good cyclic stability. The influence of Sb particle size (particularly at the nanoscale range) and the composition of Sb-carbon composites on the electrode performance, stability, and charge storage mechanism is systematically evaluated here for the first time. A range of Sb-carbon nanocomposites with varied Sb particle size (between 50 and ∼1 nm) are studied. The control of the particle size is achieved via varying the carbon and Sb weight ratio in the precursors. The shape of charge-discharge profiles, hysteresis, and the difference in cyclic stabilities and rate performance are analyzed. The nanocomposite with the smallest particle size (∼1 nm) and the largest carbon content provides the most stable cyclic behavior and a better rate capability but suffers from an increased hysteresis between charge and discharge curves. In situ synchrotron X-ray diffraction experiments indicate that the storage mechanism in the Sb-carbon nanocomposites containing Sb nanoparticles is different from the electrodes with bulkier, micron-sized Sb particles, and the electrochemical reaction proceeds through a number of crystalline intermediates.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Ramireddy</LastName><ForeName>Thrinathreddy</ForeName><Initials>T</Initials><AffiliationInfo><Affiliation>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216, Australia.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Sharma</LastName><ForeName>Neeraj</ForeName><Initials>N</Initials><AffiliationInfo><Affiliation>School of Chemistry, University of New South Wales , Sydney, New South Wales 2052, Australia.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Xing</LastName><ForeName>Tan</ForeName><Initials>T</Initials><AffiliationInfo><Affiliation>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216, Australia.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Chen</LastName><ForeName>Ying</ForeName><Initials>Y</Initials><AffiliationInfo><Affiliation>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216, Australia.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Leforestier</LastName><ForeName>Jeremie</ForeName><Initials>J</Initials><AffiliationInfo><Affiliation>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216, Australia.</Affiliation></AffiliationInfo><AffiliationInfo><Affiliation>Université de Nantes, Polytech Nantes, Institut des Matériaux Jean Rouxel, CNRS, Rue Christian Pauc, BP 50609, Nantes, 44306 CEDEX 3, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Glushenkov</LastName><ForeName>Alexey M</ForeName><Initials>AM</Initials><AffiliationInfo><Affiliation>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216, Australia.</Affiliation></AffiliationInfo></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2016</Year><Month>10</Month><Day>31</Day></ArticleDate></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>ACS Appl Mater Interfaces</MedlineTA><NlmUniqueID>101504991</NlmUniqueID><ISSNLinking>1944-8244</ISSNLinking></MedlineJournalInfo><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">anode</Keyword><Keyword MajorTopicYN="N">antimony</Keyword><Keyword MajorTopicYN="N">ball milling</Keyword><Keyword MajorTopicYN="N">size</Keyword><Keyword MajorTopicYN="N">sodium-ion battery</Keyword></KeywordList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="pubmed"><Year>2016</Year><Month>11</Month><Day>1</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2016</Year><Month>11</Month><Day>1</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2016</Year><Month>11</Month><Day>1</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">27753471</ArticleId><ArticleId IdType="doi">10.1021/acsami.6b09619</ArticleId></ArticleIdList></PubmedData></pubmed><affiliations><list><country><li>Australie</li></country></list><tree><country name="Australie"><noRegion><name sortKey="Ramireddy, Thrinathreddy" sort="Ramireddy, Thrinathreddy" uniqKey="Ramireddy T" first="Thrinathreddy" last="Ramireddy">Thrinathreddy Ramireddy</name></noRegion><name sortKey="Chen, Ying" sort="Chen, Ying" uniqKey="Chen Y" first="Ying" last="Chen">Ying Chen</name><name sortKey="Glushenkov, Alexey M" sort="Glushenkov, Alexey M" uniqKey="Glushenkov A" first="Alexey M" last="Glushenkov">Alexey M. Glushenkov</name><name sortKey="Leforestier, Jeremie" sort="Leforestier, Jeremie" uniqKey="Leforestier J" first="Jeremie" last="Leforestier">Jeremie Leforestier</name><name sortKey="Sharma, Neeraj" sort="Sharma, Neeraj" uniqKey="Sharma N" first="Neeraj" last="Sharma">Neeraj Sharma</name><name sortKey="Xing, Tan" sort="Xing, Tan" uniqKey="Xing T" first="Tan" last="Xing">Tan Xing</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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