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The secondary passive film for Type 304 stainless steel in 0.5 M H2SO4

Identifieur interne : 006794 ( PascalFrancis/Curation ); précédent : 006793; suivant : 006795

The secondary passive film for Type 304 stainless steel in 0.5 M H2SO4

Auteurs : A. Atrens [Australie] ; B. Baroux [France] ; M. Mantel [France]

Source :

RBID : Pascal:98-0013286

Descripteurs français

English descriptors

Abstract

An examination has been carried out of the secondary passive film on Type 304 stainless steel in 0.5 M H2SO4. The characterization techniques used were electrochemical (potentiodynamic, potentiostatic, and film reduction experiments) and surface analytical. A bilayer model for the secondary passive film is proposed. It appears that next to the metal, there is a modified passive film which controls the electrochemical response; i.e., governs the current for any applied potential. On top of this modified passive film, the experimental data are consistent with a "porous" corrosion-product film which adds to the total film thickness but has little influence on the electrochemical response. The composition of the secondary passive film corresponds most probably to a mixed Fe/Cr oxide/hydroxide enriched in Cr3+, with a composition similar to a primary passive film.
pA  
A01 01  1    @0 0013-4651
A02 01      @0 JESOAN
A03   1    @0 J. Electrochem. Soc.
A05       @2 144
A06       @2 11
A08 01  1  ENG  @1 The secondary passive film for Type 304 stainless steel in 0.5 M H2SO4
A11 01  1    @1 ATRENS (A.)
A11 02  1    @1 BAROUX (B.)
A11 03  1    @1 MANTEL (M.)
A14 01      @1 The Department of Mining, Minerals, and Materials Engineering, The University of Queensland @2 Brisbane, Queensland, 4072 @3 AUS @Z 1 aut.
A14 02      @1 Ugine Research Centre @2 73400 Ugine @3 FRA @Z 2 aut. @Z 3 aut.
A20       @1 3697-3704
A21       @1 1997
A23 01      @0 ENG
A43 01      @1 INIST @2 4925 @5 354000079416780080
A44       @0 0000 @1 © 1997 INIST-CNRS. All rights reserved.
A45       @0 49 ref.
A47 01  1    @0 98-0013286
A60       @1 P
A61       @0 A
A64   1    @0 Journal of the Electrochemical Society
A66 01      @0 USA
C01 01    ENG  @0 An examination has been carried out of the secondary passive film on Type 304 stainless steel in 0.5 M H2SO4. The characterization techniques used were electrochemical (potentiodynamic, potentiostatic, and film reduction experiments) and surface analytical. A bilayer model for the secondary passive film is proposed. It appears that next to the metal, there is a modified passive film which controls the electrochemical response; i.e., governs the current for any applied potential. On top of this modified passive film, the experimental data are consistent with a "porous" corrosion-product film which adds to the total film thickness but has little influence on the electrochemical response. The composition of the secondary passive film corresponds most probably to a mixed Fe/Cr oxide/hydroxide enriched in Cr3+, with a composition similar to a primary passive film.
C02 01  X    @0 001C01H02B
C02 02  X    @0 001D11E01
C02 03  X    @0 240
C03 01  X  FRE  @0 Etude expérimentale @5 01
C03 01  X  ENG  @0 Experimental study @5 01
C03 01  X  GER  @0 Experimentelle Untersuchung @5 01
C03 01  X  SPA  @0 Estudio experimental @5 01
C03 02  X  FRE  @0 Passivation @5 03
C03 02  X  ENG  @0 Passivation @5 03
C03 02  X  GER  @0 Passivierung @5 03
C03 02  X  SPA  @0 Pasivación @5 03
C03 03  X  FRE  @0 Réaction électrochimique @5 04
C03 03  X  ENG  @0 Electrochemical reaction @5 04
C03 03  X  SPA  @0 Reacción electroquímica @5 04
C03 04  X  FRE  @0 Electrode @5 06
C03 04  X  ENG  @0 Electrodes @5 06
C03 04  X  GER  @0 Elektrode @5 06
C03 04  X  SPA  @0 Electrodo @5 06
C03 05  3  FRE  @0 Acier inoxydable 304 @1 ACT @5 07
C03 05  3  ENG  @0 Stainless steel-304 @1 ACT @5 07
C03 06  X  FRE  @0 Solution acide @5 08
C03 06  X  ENG  @0 Acidic solution @5 08
C03 06  X  SPA  @0 Solución ácida @5 08
C03 07  X  FRE  @0 Sulfurique acide @1 SOL @2 NK @2 FX @5 09
C03 07  X  ENG  @0 Sulfuric acid @1 SOL @2 NK @2 FX @5 09
C03 07  X  GER  @0 Schwefelsaeure @1 SOL @2 NK @2 FX @5 09
C03 07  X  SPA  @0 Sulfúrico ácido @1 SOL @2 NK @2 FX @5 09
C03 08  X  FRE  @0 Couche bimoléculaire @5 10
C03 08  X  ENG  @0 Bilayer @5 10
C03 08  X  SPA  @0 Capa bimolecular @5 10
C03 09  X  FRE  @0 Méthode potentiostatique @5 12
C03 09  X  ENG  @0 Potentiostatic method @5 12
C03 09  X  GER  @0 Potentiostatische Pruefung @5 12
C03 09  X  SPA  @0 Método potenciostático @5 12
C03 10  X  FRE  @0 Spectrométrie photoélectron @5 13
C03 10  X  ENG  @0 Photoelectron spectrometry @5 13
C03 10  X  GER  @0 ESCA Spektrometrie @5 13
C03 10  X  SPA  @0 Espectrometría fotoelectrón @5 13
C03 11  X  FRE  @0 Rayon X @5 14
C03 11  X  ENG  @0 X ray @5 14
C03 11  X  GER  @0 Roentgenstrahlen @5 14
C03 11  X  SPA  @0 Rayos X @5 14
C03 12  X  FRE  @0 Modélisation @5 16
C03 12  X  ENG  @0 Modeling @5 16
C03 12  X  SPA  @0 Modelización @5 16
N21       @1 364

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Pascal:98-0013286

Le document en format XML

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SO
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SO
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   |étape=   Curation
   |type=    RBID
   |clé=     Pascal:98-0013286
   |texte=   The secondary passive film for Type 304 stainless steel in 0.5 M H2SO4
}}
Wicri

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