AustralieFrV1, PascalFrancis, Curation, bibRecord, 000C48

Superionic AgI-MIn-Sb2S3 glasses (M=Pb, Sb): conduction pathways associated with additional metal iodide

Identifieur interne : 000C48 ( PascalFrancis/Curation ); précédent : 000C47; suivant : 000C49

Superionic AgI-MIn-Sb2S3 glasses (M=Pb, Sb): conduction pathways associated with additional metal iodide

Auteurs : C. Renard [France] ; G. Coquet [France] ; E. Bychkov [France]

Source :

Solid state ionics [ 0167-2738 ] ; 2002.

RBID : Pascal:03-0071218

Descripteurs français

Pascal (Inist)
- Conductivité ionique, Energie activation, Modèle structure, Diffraction neutron, EXAFS, Effet Mössbauer, Effet composition, Conducteur superionique, Verre, Antimoine sulfure, Argent iodure, Plomb iodure, Antimoine iodure, Système ternaire, Composé n éléments, Système AgI PbI2 Sb2S3, Ag I Pb Sb S, Système AgI SbI3 Sb2S3, 6630H, Etude expérimentale, Ag I S Sb.
Wicri :
- topic : Verre.

English descriptors

KwdEn :
- Activation energy, Antimony iodides, Antimony sulfides, Composition effect, EXAFS, Experimental study, Glass, Ionic conductivity, Lead iodides, Moessbauer effect, Multi-element compounds, Neutron diffraction, Silver iodides, Structural models, Superionic conductors, Ternary systems.

Abstract

The ionic conductivity of the 0.5 AgI.xSbI₃.(0.5-x)Sb₂S₃ and 0.5 AgI.xPbI₂.(0.5-x)Sb₂S₃ glassy systems with a constant silver concentration has been investigated. It was found that the Ag⁺ ion transport is closely related to the heavy metal iodide content. The conductivity activation energy decreases from 0.38 to 0.28 eV, and the room temperature conductivity increases by a factor of 100 with increasing x. A structural model based on available neutron diffraction, EXAFS and ¹²⁹I-Mössbauer spectroscopy data was proposed to explain the observed phenomena.

A01	`01`	`1`		`@0 0167-2738`
A02	`01`			`@0 SSIOD3`
A03		`1`		`@0 Solid state ion.`
A05				`@2 154-5`
A08	`01`	`1`	`ENG`	`@1 Superionic AgI-MI_n-Sb₂S₃ glasses (M=Pb, Sb): conduction pathways associated with additional metal iodide`
A09	`01`	`1`	`ENG`	`@1 Materials and Processes for Energy and Environment. Part B`
A11	`01`	`1`		`@1 RENARD (C.)`
A11	`02`	`1`		`@1 COQUET (G.)`
A11	`03`	`1`		`@1 BYCHKOV (E.)`
A12	`01`	`1`		`@1 BADWAL (S. P. S.) @9 ed.`
A14	`01`			`@1 LPCA, UMR CARS 8101, Université du Littoral Côte d'Opale, 145 Avenue Marice Schumann @2 59140 Dunkirk @3 FRA @Z 1 aut. @Z 2 aut. @Z 3 aut.`
A15	`01`			`@1 CSIRO Manufacturing and Infrastructure Technology, Private Bag 33 @2 Clayton South, Victoria @3 AUS @Z 1 aut.`
A18	`01`	`1`		`@1 International Society for Solid State Ionics (ISSI) @3 INT @9 patr.`
A20				`@1 749-757`
A21				`@1 2002`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 18305 @5 354000106857911060`
A44				`@0 0000 @1 © 2003 INIST-CNRS. All rights reserved.`
A45				`@0 24 ref.`
A47	`01`	`1`		`@0 03-0071218`
A60				`@1 P @2 C`
A61				`@0 A`
A64	`01`	`1`		`@0 Solid state ionics`
A66	`01`			`@0 NLD`
C01	`01`		`ENG`	@0 The ionic conductivity of the 0.5 AgI.xSbI₃.(0.5-x)Sb₂S₃ and 0.5 AgI.xPbI₂.(0.5-x)Sb₂S₃ glassy systems with a constant silver concentration has been investigated. It was found that the Ag⁺ ion transport is closely related to the heavy metal iodide content. The conductivity activation energy decreases from 0.38 to 0.28 eV, and the room temperature conductivity increases by a factor of 100 with increasing x. A structural model based on available neutron diffraction, EXAFS and ¹²⁹I-Mössbauer spectroscopy data was proposed to explain the observed phenomena.
C02	`01`	`3`		`@0 001B60F30H`
C03	`01`	`3`	`FRE`	`@0 Conductivité ionique @5 02`
C03	`01`	`3`	`ENG`	`@0 Ionic conductivity @5 02`
C03	`02`	`3`	`FRE`	`@0 Energie activation @5 04`
C03	`02`	`3`	`ENG`	`@0 Activation energy @5 04`
C03	`03`	`3`	`FRE`	`@0 Modèle structure @5 05`
C03	`03`	`3`	`ENG`	`@0 Structural models @5 05`
C03	`04`	`3`	`FRE`	`@0 Diffraction neutron @5 06`
C03	`04`	`3`	`ENG`	`@0 Neutron diffraction @5 06`
C03	`05`	`3`	`FRE`	`@0 EXAFS @5 07`
C03	`05`	`3`	`ENG`	`@0 EXAFS @5 07`
C03	`06`	`3`	`FRE`	`@0 Effet Mössbauer @5 08`
C03	`06`	`3`	`ENG`	`@0 Moessbauer effect @5 08`
C03	`07`	`X`	`FRE`	`@0 Effet composition @5 13`
C03	`07`	`X`	`ENG`	`@0 Composition effect @5 13`
C03	`07`	`X`	`SPA`	`@0 Efecto composición @5 13`
C03	`08`	`3`	`FRE`	`@0 Conducteur superionique @5 14`
C03	`08`	`3`	`ENG`	`@0 Superionic conductors @5 14`
C03	`09`	`3`	`FRE`	`@0 Verre @5 15`
C03	`09`	`3`	`ENG`	`@0 Glass @5 15`
C03	`10`	`3`	`FRE`	`@0 Antimoine sulfure @2 NK @5 16`
C03	`10`	`3`	`ENG`	`@0 Antimony sulfides @2 NK @5 16`
C03	`11`	`3`	`FRE`	`@0 Argent iodure @2 NK @5 17`
C03	`11`	`3`	`ENG`	`@0 Silver iodides @2 NK @5 17`
C03	`12`	`3`	`FRE`	`@0 Plomb iodure @2 NK @5 18`
C03	`12`	`3`	`ENG`	`@0 Lead iodides @2 NK @5 18`
C03	`13`	`3`	`FRE`	`@0 Antimoine iodure @2 NK @5 19`
C03	`13`	`3`	`ENG`	`@0 Antimony iodides @2 NK @5 19`
C03	`14`	`3`	`FRE`	`@0 Système ternaire @5 20`
C03	`14`	`3`	`ENG`	`@0 Ternary systems @5 20`
C03	`15`	`3`	`FRE`	`@0 Composé n éléments @5 21`
C03	`15`	`3`	`ENG`	`@0 Multi-element compounds @5 21`
C03	`16`	`3`	`FRE`	`@0 Système AgI PbI2 Sb2S3 @4 INC @5 53`
C03	`17`	`3`	`FRE`	`@0 Ag I Pb Sb S @4 INC @5 54`
C03	`18`	`3`	`FRE`	`@0 Système AgI SbI3 Sb2S3 @4 INC @5 55`
C03	`19`	`3`	`FRE`	`@0 6630H @2 PAC @4 INC @5 56`
C03	`20`	`3`	`FRE`	`@0 Etude expérimentale @5 84`
C03	`20`	`3`	`ENG`	`@0 Experimental study @5 84`
C03	`21`	`3`	`FRE`	`@0 Ag I S Sb @4 INC @5 92`
C07	`01`	`3`	`FRE`	`@0 Composé minéral @5 48`
C07	`01`	`3`	`ENG`	`@0 Inorganic compounds @5 48`
C07	`02`	`3`	`FRE`	`@0 Métal transition composé @5 49`
C07	`02`	`3`	`ENG`	`@0 Transition element compounds @5 49`
N21				`@1 041`
N82				`@1 PSI`

A30	`01`	`1`	`ENG`	`@1 SSI 2001 International Conference on Solid State Ionics @3 Cairns AUS @4 2001-07-08`

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Le document en format XML

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-Sb<sub>2</sub>
S<sub>3</sub>
 glasses (M=Pb, Sb): conduction pathways associated with additional metal iodide</title>
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-Sb<sub>2</sub>
S<sub>3</sub>
 glasses (M=Pb, Sb): conduction pathways associated with additional metal iodide</title>
<author><name sortKey="Renard, C" sort="Renard, C" uniqKey="Renard C" first="C." last="Renard">C. Renard</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>LPCA, UMR CARS 8101, Université du Littoral Côte d'Opale, 145 Avenue Marice Schumann</s1>
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<author><name sortKey="Coquet, G" sort="Coquet, G" uniqKey="Coquet G" first="G." last="Coquet">G. Coquet</name>
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<author><name sortKey="Bychkov, E" sort="Bychkov, E" uniqKey="Bychkov E" first="E." last="Bychkov">E. Bychkov</name>
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<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>France</country>
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</author>
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<series><title level="j" type="main">Solid state ionics</title>
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<seriesStmt><title level="j" type="main">Solid state ionics</title>
<title level="j" type="abbreviated">Solid state ion.</title>
<idno type="ISSN">0167-2738</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Activation energy</term>
<term>Antimony iodides</term>
<term>Antimony sulfides</term>
<term>Composition effect</term>
<term>EXAFS</term>
<term>Experimental study</term>
<term>Glass</term>
<term>Ionic conductivity</term>
<term>Lead iodides</term>
<term>Moessbauer effect</term>
<term>Multi-element compounds</term>
<term>Neutron diffraction</term>
<term>Silver iodides</term>
<term>Structural models</term>
<term>Superionic conductors</term>
<term>Ternary systems</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Conductivité ionique</term>
<term>Energie activation</term>
<term>Modèle structure</term>
<term>Diffraction neutron</term>
<term>EXAFS</term>
<term>Effet Mössbauer</term>
<term>Effet composition</term>
<term>Conducteur superionique</term>
<term>Verre</term>
<term>Antimoine sulfure</term>
<term>Argent iodure</term>
<term>Plomb iodure</term>
<term>Antimoine iodure</term>
<term>Système ternaire</term>
<term>Composé n éléments</term>
<term>Système AgI PbI2 Sb2S3</term>
<term>Ag I Pb Sb S</term>
<term>Système AgI SbI3 Sb2S3</term>
<term>6630H</term>
<term>Etude expérimentale</term>
<term>Ag I S Sb</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Verre</term>
</keywords>
</textClass>
</profileDesc>
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<front><div type="abstract" xml:lang="en">The ionic conductivity of the 0.5 AgI.xSbI<sub>3</sub>
.(0.5-x)Sb<sub>2</sub>
S<sub>3</sub>
 and 0.5 AgI.xPbI<sub>2</sub>
.(0.5-x)Sb<sub>2</sub>
S<sub>3</sub>
 glassy systems with a constant silver concentration has been investigated. It was found that the Ag<sup>+</sup>
 ion transport is closely related to the heavy metal iodide content. The conductivity activation energy decreases from 0.38 to 0.28 eV, and the room temperature conductivity increases by a factor of 100 with increasing x. A structural model based on available neutron diffraction, EXAFS and <sup>129</sup>
I-Mössbauer spectroscopy data was proposed to explain the observed phenomena.</div>
</front>
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<fA05><s2>154-5</s2>
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<fA08 i1="01" i2="1" l="ENG"><s1>Superionic AgI-MI<sub>n</sub>
-Sb<sub>2</sub>
S<sub>3</sub>
 glasses (M=Pb, Sb): conduction pathways associated with additional metal iodide</s1>
</fA08>
<fA09 i1="01" i2="1" l="ENG"><s1>Materials and Processes for Energy and Environment. Part B</s1>
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<fA11 i1="03" i2="1"><s1>BYCHKOV (E.)</s1>
</fA11>
<fA12 i1="01" i2="1"><s1>BADWAL (S. P. S.)</s1>
<s9>ed.</s9>
</fA12>
<fA14 i1="01"><s1>LPCA, UMR CARS 8101, Université du Littoral Côte d'Opale, 145 Avenue Marice Schumann</s1>
<s2>59140 Dunkirk</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</fA14>
<fA15 i1="01"><s1>CSIRO Manufacturing and Infrastructure Technology, Private Bag 33</s1>
<s2>Clayton South, Victoria</s2>
<s3>AUS</s3>
<sZ>1 aut.</sZ>
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<fA18 i1="01" i2="1"><s1>International Society for Solid State Ionics (ISSI)</s1>
<s3>INT</s3>
<s9>patr.</s9>
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<fA20><s1>749-757</s1>
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<fA21><s1>2002</s1>
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<fA23 i1="01"><s0>ENG</s0>
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<fA43 i1="01"><s1>INIST</s1>
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<s5>354000106857911060</s5>
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<fA60><s1>P</s1>
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<fA66 i1="01"><s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>The ionic conductivity of the 0.5 AgI.xSbI<sub>3</sub>
.(0.5-x)Sb<sub>2</sub>
S<sub>3</sub>
 and 0.5 AgI.xPbI<sub>2</sub>
.(0.5-x)Sb<sub>2</sub>
S<sub>3</sub>
 glassy systems with a constant silver concentration has been investigated. It was found that the Ag<sup>+</sup>
 ion transport is closely related to the heavy metal iodide content. The conductivity activation energy decreases from 0.38 to 0.28 eV, and the room temperature conductivity increases by a factor of 100 with increasing x. A structural model based on available neutron diffraction, EXAFS and <sup>129</sup>
I-Mössbauer spectroscopy data was proposed to explain the observed phenomena.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B60F30H</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Conductivité ionique</s0>
<s5>02</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG"><s0>Ionic conductivity</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Energie activation</s0>
<s5>04</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>Activation energy</s0>
<s5>04</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Modèle structure</s0>
<s5>05</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>Structural models</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Diffraction neutron</s0>
<s5>06</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Neutron diffraction</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>EXAFS</s0>
<s5>07</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>EXAFS</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Effet Mössbauer</s0>
<s5>08</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Moessbauer effect</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Effet composition</s0>
<s5>13</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Composition effect</s0>
<s5>13</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Efecto composición</s0>
<s5>13</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>Conducteur superionique</s0>
<s5>14</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG"><s0>Superionic conductors</s0>
<s5>14</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE"><s0>Verre</s0>
<s5>15</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG"><s0>Glass</s0>
<s5>15</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Antimoine sulfure</s0>
<s2>NK</s2>
<s5>16</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Antimony sulfides</s0>
<s2>NK</s2>
<s5>16</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>Argent iodure</s0>
<s2>NK</s2>
<s5>17</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG"><s0>Silver iodides</s0>
<s2>NK</s2>
<s5>17</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>Plomb iodure</s0>
<s2>NK</s2>
<s5>18</s5>
</fC03>
<fC03 i1="12" i2="3" l="ENG"><s0>Lead iodides</s0>
<s2>NK</s2>
<s5>18</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>Antimoine iodure</s0>
<s2>NK</s2>
<s5>19</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG"><s0>Antimony iodides</s0>
<s2>NK</s2>
<s5>19</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE"><s0>Système ternaire</s0>
<s5>20</s5>
</fC03>
<fC03 i1="14" i2="3" l="ENG"><s0>Ternary systems</s0>
<s5>20</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE"><s0>Composé n éléments</s0>
<s5>21</s5>
</fC03>
<fC03 i1="15" i2="3" l="ENG"><s0>Multi-element compounds</s0>
<s5>21</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE"><s0>Système AgI PbI2 Sb2S3</s0>
<s4>INC</s4>
<s5>53</s5>
</fC03>
<fC03 i1="17" i2="3" l="FRE"><s0>Ag I Pb Sb S</s0>
<s4>INC</s4>
<s5>54</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE"><s0>Système AgI SbI3 Sb2S3</s0>
<s4>INC</s4>
<s5>55</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE"><s0>6630H</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="20" i2="3" l="FRE"><s0>Etude expérimentale</s0>
<s5>84</s5>
</fC03>
<fC03 i1="20" i2="3" l="ENG"><s0>Experimental study</s0>
<s5>84</s5>
</fC03>
<fC03 i1="21" i2="3" l="FRE"><s0>Ag I S Sb</s0>
<s4>INC</s4>
<s5>92</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE"><s0>Composé minéral</s0>
<s5>48</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG"><s0>Inorganic compounds</s0>
<s5>48</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE"><s0>Métal transition composé</s0>
<s5>49</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG"><s0>Transition element compounds</s0>
<s5>49</s5>
</fC07>
<fN21><s1>041</s1>
</fN21>
<fN82><s1>PSI</s1>
</fN82>
</pA>
<pR><fA30 i1="01" i2="1" l="ENG"><s1>SSI 2001 International Conference on Solid State Ionics</s1>
<s3>Cairns AUS</s3>
<s4>2001-07-08</s4>
</fA30>
</pR>
</standard>
</inist>
</record>

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   |texte=   Superionic AgI-MIn-Sb2S3 glasses (M=Pb, Sb): conduction pathways associated with additional metal iodide
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	Serveur d'exploration sur les relations entre la France et l'Australie
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Superionic AgI-MIn-Sb2S3 glasses (M=Pb, Sb): conduction pathways associated with additional metal iodide

Superionic AgI-MIn-Sb2S3 glasses (M=Pb, Sb): conduction pathways associated with additional metal iodide

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