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Thermally stimulated luminescence and exoelectron emission mechanism of the 430 K (D') dosimetric peak of α-Al2O3

Identifieur interne : 006276 ( PascalFrancis/Corpus ); précédent : 006275; suivant : 006277

Thermally stimulated luminescence and exoelectron emission mechanism of the 430 K (D') dosimetric peak of α-Al2O3

Auteurs : G. Molnar ; E. Papin ; P. Grosseau ; B. Guilhot ; J. Borossay ; M. Benabdesselam ; P. Iacconi ; D. Lapraz

Source :

RBID : Pascal:99-0414305

Descripteurs français

English descriptors

Abstract

Several α-Al2O3 samples were studied in order to determine the mechanism of electron-hole processes of the 430 K (D') thermoluminescence (TL) and thermally stimulated exoelectron emission (TSEE) dosimetric peak. Single crystals prepared in highly reducing conditions were treated in different, atmospheres (reducing/oxidising) and their optical absorption (after isochronous annealing), fluorescence and TL properties were investigated. From these results an electron trap is suggested for the 430 K peak which is in contradiction to some data taken from the literature: this problem is then discussed. Pure and Th4+ doped α-Al2O3powders were studied by TL methods regarding doping concentration and preparation conditions. In this way the role of aluminium vacancies is proved. Considering these new results, literature data and different hypotheses, the possible nature of the trap is discussed. ew results, data and different hypotheses, the possible nature of the trap is discussed.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

pA  
A01 01  1    @0 0144-8420
A02 01      @0 RPDODE
A03   1    @0 Radiat. prot. dosim.
A05       @2 84
A06       @2 1-4
A08 01  1  ENG  @1 Thermally stimulated luminescence and exoelectron emission mechanism of the 430 K (D') dosimetric peak of α-Al2O3
A09 01  1  ENG  @1 Solid state dosimetry. Part I
A11 01  1    @1 MOLNAR (G.)
A11 02  1    @1 PAPIN (E.)
A11 03  1    @1 GROSSEAU (P.)
A11 04  1    @1 GUILHOT (B.)
A11 05  1    @1 BOROSSAY (J.)
A11 06  1    @1 BENABDESSELAM (M.)
A11 07  1    @1 IACCONI (P.)
A11 08  1    @1 LAPRAZ (D.)
A12 01  1    @1 DELGADO (A.) @9 ed.
A12 02  1    @1 GOMEZ ROS (J. M.) @9 ed.
A12 03  1    @1 BOS (A. J. J.) @9 ed.
A12 04  1    @1 BØTTER-JENSEN (L.) @9 ed.
A12 05  1    @1 HOROWITZ (Y. S.) @9 ed.
A12 06  1    @1 JULIUS (H. W.) @9 ed.
A12 07  1    @1 KLEMIC (G.) @9 ed.
A12 08  1    @1 KRON (T.) @9 ed.
A14 01      @1 LPES-CRESA, Université de Nice-Sophia Antipolis, Parc Valrose @2 06108 Nice @3 FRA @Z 1 aut. @Z 6 aut. @Z 7 aut. @Z 8 aut.
A14 02      @1 Department of General and Inorganic Chemistry, Eötvös Loránd University, P.O. Box 32 @2 1518, Budapest 112 @3 HUN @Z 1 aut. @Z 5 aut.
A14 03      @1 SPIN-CRESA, Ecole des Mines de Saint-Etienne, 158 cours Fauriel @2 42023 Saint-Etienne @3 FRA @Z 2 aut. @Z 3 aut. @Z 4 aut.
A15 01      @1 CIEMAT @3 ESP @Z 1 aut.
A15 02      @1 Delft T. University @3 NLD @Z 3 aut.
A15 03      @1 Ben Gurion University @3 ISR @Z 5 aut.
A15 04      @1 TNO @3 NLD @Z 6 aut.
A15 05      @1 EML (DOE) @3 USA @Z 7 aut.
A15 06      @1 Newcastle Mater Misericordiae Hospital @3 AUS @Z 8 aut.
A20       @1 253-256
A21       @1 1999
A23 01      @0 ENG
A43 01      @1 INIST @2 19318 @5 354000085782220550
A44       @0 0000 @1 © 1999 INIST-CNRS. All rights reserved.
A45       @0 8 ref.
A47 01  1    @0 99-0414305
A60       @1 P @2 C
A61       @0 A
A64 01  1    @0 Radiation protection dosimetry
A66 01      @0 GBR
C01 01    ENG  @0 Several α-Al2O3 samples were studied in order to determine the mechanism of electron-hole processes of the 430 K (D') thermoluminescence (TL) and thermally stimulated exoelectron emission (TSEE) dosimetric peak. Single crystals prepared in highly reducing conditions were treated in different, atmospheres (reducing/oxidising) and their optical absorption (after isochronous annealing), fluorescence and TL properties were investigated. From these results an electron trap is suggested for the 430 K peak which is in contradiction to some data taken from the literature: this problem is then discussed. Pure and Th4+ doped α-Al2O3powders were studied by TL methods regarding doping concentration and preparation conditions. In this way the role of aluminium vacancies is proved. Considering these new results, literature data and different hypotheses, the possible nature of the trap is discussed. ew results, data and different hypotheses, the possible nature of the trap is discussed.
C02 01  X    @0 002A08F05
C03 01  X  FRE  @0 Mécanisme action @5 01
C03 01  X  ENG  @0 Mechanism of action @5 01
C03 01  X  SPA  @0 Mecanismo acción @5 01
C03 02  X  FRE  @0 Thermoluminescence @5 02
C03 02  X  ENG  @0 Thermoluminescence @5 02
C03 02  X  SPA  @0 Termoluminescencia @5 02
C03 03  X  FRE  @0 Emission exoélectronique @5 03
C03 03  X  ENG  @0 Exoelectron emission @5 03
C03 03  X  SPA  @0 Emisión exoelectrónica @5 03
C03 04  X  FRE  @0 Aluminium oxyde @5 04
C03 04  X  ENG  @0 Aluminium oxide @5 04
C03 04  X  SPA  @0 Aluminio óxido @5 04
C03 05  X  FRE  @0 Paire électron trou @5 05
C03 05  X  ENG  @0 Electron hole pair @5 05
C03 05  X  SPA  @0 Par electrón hueco @5 05
C03 06  X  FRE  @0 Propriété optique @5 06
C03 06  X  ENG  @0 Optical properties @5 06
C03 06  X  SPA  @0 Propiedad óptica @5 06
C03 07  X  FRE  @0 Piégeage @5 07
C03 07  X  ENG  @0 Trapping @5 07
C03 07  X  SPA  @0 Captura @5 07
C03 08  X  FRE  @0 Dosimétrie @5 08
C03 08  X  ENG  @0 Dosimetry @5 08
C03 08  X  SPA  @0 Dosimetría @5 08
C03 09  X  FRE  @0 Cristal @5 09
C03 09  X  ENG  @0 Crystals @5 09
C03 09  X  SPA  @0 Cristal @5 09
N21       @1 263
pR  
A30 01  1  ENG  @1 International Conference on Solid State Dosimetry @2 12 @3 Burgos ESP @4 1998-07-05

Format Inist (serveur)

NO : PASCAL 99-0414305 INIST
ET : Thermally stimulated luminescence and exoelectron emission mechanism of the 430 K (D') dosimetric peak of α-Al2O3
AU : MOLNAR (G.); PAPIN (E.); GROSSEAU (P.); GUILHOT (B.); BOROSSAY (J.); BENABDESSELAM (M.); IACCONI (P.); LAPRAZ (D.); DELGADO (A.); GOMEZ ROS (J. M.); BOS (A. J. J.); BØTTER-JENSEN (L.); HOROWITZ (Y. S.); JULIUS (H. W.); KLEMIC (G.); KRON (T.)
AF : LPES-CRESA, Université de Nice-Sophia Antipolis, Parc Valrose/06108 Nice/France (1 aut., 6 aut., 7 aut., 8 aut.); Department of General and Inorganic Chemistry, Eötvös Loránd University, P.O. Box 32/1518, Budapest 112/Hongrie (1 aut., 5 aut.); SPIN-CRESA, Ecole des Mines de Saint-Etienne, 158 cours Fauriel/42023 Saint-Etienne/France (2 aut., 3 aut., 4 aut.); CIEMAT/Espagne (1 aut.); Delft T. University/Pays-Bas (3 aut.); Ben Gurion University/Israël (5 aut.); TNO/Pays-Bas (6 aut.); EML (DOE)/Etats-Unis (7 aut.); Newcastle Mater Misericordiae Hospital/Australie (8 aut.)
DT : Publication en série; Congrès; Niveau analytique
SO : Radiation protection dosimetry; ISSN 0144-8420; Coden RPDODE; Royaume-Uni; Da. 1999; Vol. 84; No. 1-4; Pp. 253-256; Bibl. 8 ref.
LA : Anglais
EA : Several α-Al2O3 samples were studied in order to determine the mechanism of electron-hole processes of the 430 K (D') thermoluminescence (TL) and thermally stimulated exoelectron emission (TSEE) dosimetric peak. Single crystals prepared in highly reducing conditions were treated in different, atmospheres (reducing/oxidising) and their optical absorption (after isochronous annealing), fluorescence and TL properties were investigated. From these results an electron trap is suggested for the 430 K peak which is in contradiction to some data taken from the literature: this problem is then discussed. Pure and Th4+ doped α-Al2O3powders were studied by TL methods regarding doping concentration and preparation conditions. In this way the role of aluminium vacancies is proved. Considering these new results, literature data and different hypotheses, the possible nature of the trap is discussed. ew results, data and different hypotheses, the possible nature of the trap is discussed.
CC : 002A08F05
FD : Mécanisme action; Thermoluminescence; Emission exoélectronique; Aluminium oxyde; Paire électron trou; Propriété optique; Piégeage; Dosimétrie; Cristal
ED : Mechanism of action; Thermoluminescence; Exoelectron emission; Aluminium oxide; Electron hole pair; Optical properties; Trapping; Dosimetry; Crystals
SD : Mecanismo acción; Termoluminescencia; Emisión exoelectrónica; Aluminio óxido; Par electrón hueco; Propiedad óptica; Captura; Dosimetría; Cristal
LO : INIST-19318.354000085782220550
ID : 99-0414305

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Pascal:99-0414305

Le document en format XML

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O
<sub>3</sub>
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<term>Mechanism of action</term>
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<term>Thermoluminescence</term>
<term>Trapping</term>
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<front>
<div type="abstract" xml:lang="en">Several α-Al
<sub>2</sub>
O
<sub>3</sub>
samples were studied in order to determine the mechanism of electron-hole processes of the 430 K (D') thermoluminescence (TL) and thermally stimulated exoelectron emission (TSEE) dosimetric peak. Single crystals prepared in highly reducing conditions were treated in different, atmospheres (reducing/oxidising) and their optical absorption (after isochronous annealing), fluorescence and TL properties were investigated. From these results an electron trap is suggested for the 430 K peak which is in contradiction to some data taken from the literature: this problem is then discussed. Pure and Th
<sup>4+</sup>
doped α-Al
<sub>2</sub>
O
<sub>3</sub>
powders were studied by TL methods regarding doping concentration and preparation conditions. In this way the role of aluminium vacancies is proved. Considering these new results, literature data and different hypotheses, the possible nature of the trap is discussed. ew results, data and different hypotheses, the possible nature of the trap is discussed.</div>
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O
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<s1>GUILHOT (B.)</s1>
</fA11>
<fA11 i1="05" i2="1">
<s1>BOROSSAY (J.)</s1>
</fA11>
<fA11 i1="06" i2="1">
<s1>BENABDESSELAM (M.)</s1>
</fA11>
<fA11 i1="07" i2="1">
<s1>IACCONI (P.)</s1>
</fA11>
<fA11 i1="08" i2="1">
<s1>LAPRAZ (D.)</s1>
</fA11>
<fA12 i1="01" i2="1">
<s1>DELGADO (A.)</s1>
<s9>ed.</s9>
</fA12>
<fA12 i1="02" i2="1">
<s1>GOMEZ ROS (J. M.)</s1>
<s9>ed.</s9>
</fA12>
<fA12 i1="03" i2="1">
<s1>BOS (A. J. J.)</s1>
<s9>ed.</s9>
</fA12>
<fA12 i1="04" i2="1">
<s1>BØTTER-JENSEN (L.)</s1>
<s9>ed.</s9>
</fA12>
<fA12 i1="05" i2="1">
<s1>HOROWITZ (Y. S.)</s1>
<s9>ed.</s9>
</fA12>
<fA12 i1="06" i2="1">
<s1>JULIUS (H. W.)</s1>
<s9>ed.</s9>
</fA12>
<fA12 i1="07" i2="1">
<s1>KLEMIC (G.)</s1>
<s9>ed.</s9>
</fA12>
<fA12 i1="08" i2="1">
<s1>KRON (T.)</s1>
<s9>ed.</s9>
</fA12>
<fA14 i1="01">
<s1>LPES-CRESA, Université de Nice-Sophia Antipolis, Parc Valrose</s1>
<s2>06108 Nice</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>6 aut.</sZ>
<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
</fA14>
<fA14 i1="02">
<s1>Department of General and Inorganic Chemistry, Eötvös Loránd University, P.O. Box 32</s1>
<s2>1518, Budapest 112</s2>
<s3>HUN</s3>
<sZ>1 aut.</sZ>
<sZ>5 aut.</sZ>
</fA14>
<fA14 i1="03">
<s1>SPIN-CRESA, Ecole des Mines de Saint-Etienne, 158 cours Fauriel</s1>
<s2>42023 Saint-Etienne</s2>
<s3>FRA</s3>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</fA14>
<fA15 i1="01">
<s1>CIEMAT</s1>
<s3>ESP</s3>
<sZ>1 aut.</sZ>
</fA15>
<fA15 i1="02">
<s1>Delft T. University</s1>
<s3>NLD</s3>
<sZ>3 aut.</sZ>
</fA15>
<fA15 i1="03">
<s1>Ben Gurion University</s1>
<s3>ISR</s3>
<sZ>5 aut.</sZ>
</fA15>
<fA15 i1="04">
<s1>TNO</s1>
<s3>NLD</s3>
<sZ>6 aut.</sZ>
</fA15>
<fA15 i1="05">
<s1>EML (DOE)</s1>
<s3>USA</s3>
<sZ>7 aut.</sZ>
</fA15>
<fA15 i1="06">
<s1>Newcastle Mater Misericordiae Hospital</s1>
<s3>AUS</s3>
<sZ>8 aut.</sZ>
</fA15>
<fA20>
<s1>253-256</s1>
</fA20>
<fA21>
<s1>1999</s1>
</fA21>
<fA23 i1="01">
<s0>ENG</s0>
</fA23>
<fA43 i1="01">
<s1>INIST</s1>
<s2>19318</s2>
<s5>354000085782220550</s5>
</fA43>
<fA44>
<s0>0000</s0>
<s1>© 1999 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45>
<s0>8 ref.</s0>
</fA45>
<fA47 i1="01" i2="1">
<s0>99-0414305</s0>
</fA47>
<fA60>
<s1>P</s1>
<s2>C</s2>
</fA60>
<fA61>
<s0>A</s0>
</fA61>
<fA64 i1="01" i2="1">
<s0>Radiation protection dosimetry</s0>
</fA64>
<fA66 i1="01">
<s0>GBR</s0>
</fA66>
<fC01 i1="01" l="ENG">
<s0>Several α-Al
<sub>2</sub>
O
<sub>3</sub>
samples were studied in order to determine the mechanism of electron-hole processes of the 430 K (D') thermoluminescence (TL) and thermally stimulated exoelectron emission (TSEE) dosimetric peak. Single crystals prepared in highly reducing conditions were treated in different, atmospheres (reducing/oxidising) and their optical absorption (after isochronous annealing), fluorescence and TL properties were investigated. From these results an electron trap is suggested for the 430 K peak which is in contradiction to some data taken from the literature: this problem is then discussed. Pure and Th
<sup>4+</sup>
doped α-Al
<sub>2</sub>
O
<sub>3</sub>
powders were studied by TL methods regarding doping concentration and preparation conditions. In this way the role of aluminium vacancies is proved. Considering these new results, literature data and different hypotheses, the possible nature of the trap is discussed. ew results, data and different hypotheses, the possible nature of the trap is discussed.</s0>
</fC01>
<fC02 i1="01" i2="X">
<s0>002A08F05</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE">
<s0>Mécanisme action</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG">
<s0>Mechanism of action</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA">
<s0>Mecanismo acción</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE">
<s0>Thermoluminescence</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG">
<s0>Thermoluminescence</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA">
<s0>Termoluminescencia</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE">
<s0>Emission exoélectronique</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG">
<s0>Exoelectron emission</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA">
<s0>Emisión exoelectrónica</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE">
<s0>Aluminium oxyde</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG">
<s0>Aluminium oxide</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA">
<s0>Aluminio óxido</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE">
<s0>Paire électron trou</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG">
<s0>Electron hole pair</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA">
<s0>Par electrón hueco</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE">
<s0>Propriété optique</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG">
<s0>Optical properties</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA">
<s0>Propiedad óptica</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE">
<s0>Piégeage</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG">
<s0>Trapping</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA">
<s0>Captura</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE">
<s0>Dosimétrie</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG">
<s0>Dosimetry</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA">
<s0>Dosimetría</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE">
<s0>Cristal</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG">
<s0>Crystals</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA">
<s0>Cristal</s0>
<s5>09</s5>
</fC03>
<fN21>
<s1>263</s1>
</fN21>
</pA>
<pR>
<fA30 i1="01" i2="1" l="ENG">
<s1>International Conference on Solid State Dosimetry</s1>
<s2>12</s2>
<s3>Burgos ESP</s3>
<s4>1998-07-05</s4>
</fA30>
</pR>
</standard>
<server>
<NO>PASCAL 99-0414305 INIST</NO>
<ET>Thermally stimulated luminescence and exoelectron emission mechanism of the 430 K (D') dosimetric peak of α-Al
<sub>2</sub>
O
<sub>3</sub>
</ET>
<AU>MOLNAR (G.); PAPIN (E.); GROSSEAU (P.); GUILHOT (B.); BOROSSAY (J.); BENABDESSELAM (M.); IACCONI (P.); LAPRAZ (D.); DELGADO (A.); GOMEZ ROS (J. M.); BOS (A. J. J.); BØTTER-JENSEN (L.); HOROWITZ (Y. S.); JULIUS (H. W.); KLEMIC (G.); KRON (T.)</AU>
<AF>LPES-CRESA, Université de Nice-Sophia Antipolis, Parc Valrose/06108 Nice/France (1 aut., 6 aut., 7 aut., 8 aut.); Department of General and Inorganic Chemistry, Eötvös Loránd University, P.O. Box 32/1518, Budapest 112/Hongrie (1 aut., 5 aut.); SPIN-CRESA, Ecole des Mines de Saint-Etienne, 158 cours Fauriel/42023 Saint-Etienne/France (2 aut., 3 aut., 4 aut.); CIEMAT/Espagne (1 aut.); Delft T. University/Pays-Bas (3 aut.); Ben Gurion University/Israël (5 aut.); TNO/Pays-Bas (6 aut.); EML (DOE)/Etats-Unis (7 aut.); Newcastle Mater Misericordiae Hospital/Australie (8 aut.)</AF>
<DT>Publication en série; Congrès; Niveau analytique</DT>
<SO>Radiation protection dosimetry; ISSN 0144-8420; Coden RPDODE; Royaume-Uni; Da. 1999; Vol. 84; No. 1-4; Pp. 253-256; Bibl. 8 ref.</SO>
<LA>Anglais</LA>
<EA>Several α-Al
<sub>2</sub>
O
<sub>3</sub>
samples were studied in order to determine the mechanism of electron-hole processes of the 430 K (D') thermoluminescence (TL) and thermally stimulated exoelectron emission (TSEE) dosimetric peak. Single crystals prepared in highly reducing conditions were treated in different, atmospheres (reducing/oxidising) and their optical absorption (after isochronous annealing), fluorescence and TL properties were investigated. From these results an electron trap is suggested for the 430 K peak which is in contradiction to some data taken from the literature: this problem is then discussed. Pure and Th
<sup>4+</sup>
doped α-Al
<sub>2</sub>
O
<sub>3</sub>
powders were studied by TL methods regarding doping concentration and preparation conditions. In this way the role of aluminium vacancies is proved. Considering these new results, literature data and different hypotheses, the possible nature of the trap is discussed. ew results, data and different hypotheses, the possible nature of the trap is discussed.</EA>
<CC>002A08F05</CC>
<FD>Mécanisme action; Thermoluminescence; Emission exoélectronique; Aluminium oxyde; Paire électron trou; Propriété optique; Piégeage; Dosimétrie; Cristal</FD>
<ED>Mechanism of action; Thermoluminescence; Exoelectron emission; Aluminium oxide; Electron hole pair; Optical properties; Trapping; Dosimetry; Crystals</ED>
<SD>Mecanismo acción; Termoluminescencia; Emisión exoelectrónica; Aluminio óxido; Par electrón hueco; Propiedad óptica; Captura; Dosimetría; Cristal</SD>
<LO>INIST-19318.354000085782220550</LO>
<ID>99-0414305</ID>
</server>
</inist>
</record>

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