Electrochemical properties of graphite electrode in propylene carbonate-based electrolytes containing lithium and calcium ions
Identifieur interne : 001B39 ( PascalFrancis/Checkpoint ); précédent : 001B38; suivant : 001B40Electrochemical properties of graphite electrode in propylene carbonate-based electrolytes containing lithium and calcium ions
Auteurs : S. Takeuchi [Japon] ; K. Miyazaki [Japon] ; F. Sagane [Japon] ; T. Fukutsuka [Japon] ; S.-K. Jeong [Japon] ; T. Abe [Japon]Source :
- Electrochimica acta [ 0013-4686 ] ; 2011.
Descripteurs français
- Pascal (Inist)
- Effet milieu, Graphite, Electrode, Solution électrolyte, Spectrométrie impédance électrochimique, Insertion, Ion lithium, Carbonate organique, Accumulateur électrochimique, 1,3-Dioxolan-2-one(méthyl), Lithium amidure(bis[trifluorosulfonyl]), Calcium amidure(bis[trifluorosulfonyl]), Batterie lithium ion.
English descriptors
- KwdEn :
Abstract
Electrochemical properties of graphite electrode are studied in propylene carbonate (PC) electrolytes containing both LiN(SO2CF3)2 and Ca(N(SO2CF3)2)2 salts, and the influence of the salt concentrations on the intercalation/de-intercalation properties of graphite electrode is clarified. In the higher concentration electrolytes, reversible lithium-ion intercalation/de-intercalation at graphite electrode takes place. In contrast, only the exfoliation of graphite occurs in the lower concentration electrolytes. The effect of the salt concentrations on the electrochemical properties of graphite is discussed.
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Takeuchi</name><affiliation wicri:level="4"><inist:fA14 i1="01"><s1>Graduate School of Engineering, Kyoto University</s1><s2>Nishikyo-ku, Kyoto 615-8510</s2><s3>JPN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Japon</country><placeName><settlement type="city">Kyoto</settlement><region type="prefecture">Région du Kansai</region></placeName><orgName type="university">Université de Kyoto</orgName></affiliation></author><author><name sortKey="Miyazaki, K" sort="Miyazaki, K" uniqKey="Miyazaki K" first="K." last="Miyazaki">K. Miyazaki</name><affiliation wicri:level="4"><inist:fA14 i1="01"><s1>Graduate School of Engineering, Kyoto University</s1><s2>Nishikyo-ku, Kyoto 615-8510</s2><s3>JPN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Japon</country><placeName><settlement type="city">Kyoto</settlement><region type="prefecture">Région du Kansai</region></placeName><orgName type="university">Université de Kyoto</orgName></affiliation></author><author><name sortKey="Sagane, F" sort="Sagane, F" uniqKey="Sagane F" first="F." last="Sagane">F. Sagane</name><affiliation wicri:level="4"><inist:fA14 i1="01"><s1>Graduate School of Engineering, Kyoto University</s1><s2>Nishikyo-ku, Kyoto 615-8510</s2><s3>JPN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Japon</country><placeName><settlement type="city">Kyoto</settlement><region type="prefecture">Région du Kansai</region></placeName><orgName type="university">Université de Kyoto</orgName></affiliation></author><author><name sortKey="Fukutsuka, T" sort="Fukutsuka, T" uniqKey="Fukutsuka T" first="T." last="Fukutsuka">T. Fukutsuka</name><affiliation wicri:level="4"><inist:fA14 i1="01"><s1>Graduate School of Engineering, Kyoto University</s1><s2>Nishikyo-ku, Kyoto 615-8510</s2><s3>JPN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Japon</country><placeName><settlement type="city">Kyoto</settlement><region type="prefecture">Région du Kansai</region></placeName><orgName type="university">Université de Kyoto</orgName></affiliation></author><author><name sortKey="Jeong, S K" sort="Jeong, S K" uniqKey="Jeong S" first="S.-K." last="Jeong">S.-K. Jeong</name><affiliation wicri:level="4"><inist:fA14 i1="01"><s1>Graduate School of Engineering, Kyoto University</s1><s2>Nishikyo-ku, Kyoto 615-8510</s2><s3>JPN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Japon</country><placeName><settlement type="city">Kyoto</settlement><region type="prefecture">Région du Kansai</region></placeName><orgName type="university">Université de Kyoto</orgName></affiliation></author><author><name sortKey="Abe, T" sort="Abe, T" uniqKey="Abe T" first="T." last="Abe">T. Abe</name><affiliation wicri:level="4"><inist:fA14 i1="01"><s1>Graduate School of Engineering, Kyoto University</s1><s2>Nishikyo-ku, Kyoto 615-8510</s2><s3>JPN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Japon</country><placeName><settlement type="city">Kyoto</settlement><region type="prefecture">Région du Kansai</region></placeName><orgName type="university">Université de Kyoto</orgName></affiliation></author></analytic><series><title level="j" type="main">Electrochimica acta</title><title level="j" type="abbreviated">Electrochim. acta</title><idno type="ISSN">0013-4686</idno><imprint><date when="2011">2011</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">Electrochimica acta</title><title level="j" type="abbreviated">Electrochim. acta</title><idno type="ISSN">0013-4686</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Electrochemical impedance spectroscopy</term><term>Electrodes</term><term>Electrolyte solution</term><term>Graphite</term><term>Insertion</term><term>Lithion ion batteries</term><term>Lithium ion</term><term>Medium effect</term><term>Organic carbonate</term><term>Secondary cell</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Effet milieu</term><term>Graphite</term><term>Electrode</term><term>Solution électrolyte</term><term>Spectrométrie impédance électrochimique</term><term>Insertion</term><term>Ion lithium</term><term>Carbonate organique</term><term>Accumulateur électrochimique</term><term>1,3-Dioxolan-2-one(méthyl)</term><term>Lithium amidure(bis[trifluorosulfonyl])</term><term>Calcium amidure(bis[trifluorosulfonyl])</term><term>Batterie lithium ion</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Electrochemical properties of graphite electrode are studied in propylene carbonate (PC) electrolytes containing both LiN(SO<sub>2</sub>CF<sub>3</sub>)<sub>2</sub> and Ca(N(SO<sub>2</sub>CF<sub>3</sub>)<sub>2</sub>)<sub>2</sub> salts, and the influence of the salt concentrations on the intercalation/de-intercalation properties of graphite electrode is clarified. In the higher concentration electrolytes, reversible lithium-ion intercalation/de-intercalation at graphite electrode takes place. In contrast, only the exfoliation of graphite occurs in the lower concentration electrolytes. The effect of the salt concentrations on the electrochemical properties of graphite is discussed.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0013-4686</s0></fA01><fA02 i1="01"><s0>ELCAAV</s0></fA02><fA03 i2="1"><s0>Electrochim. acta</s0></fA03><fA05><s2>56</s2></fA05><fA06><s2>28</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Electrochemical properties of graphite electrode in propylene carbonate-based electrolytes containing lithium and calcium ions</s1></fA08><fA09 i1="01" i2="1" l="ENG"><s1>Electrochemistry from Biology to Physics</s1></fA09><fA11 i1="01" i2="1"><s1>TAKEUCHI (S.)</s1></fA11><fA11 i1="02" i2="1"><s1>MIYAZAKI (K.)</s1></fA11><fA11 i1="03" i2="1"><s1>SAGANE (F.)</s1></fA11><fA11 i1="04" i2="1"><s1>FUKUTSUKA (T.)</s1></fA11><fA11 i1="05" i2="1"><s1>JEONG (S.-K.)</s1></fA11><fA11 i1="06" i2="1"><s1>ABE (T.)</s1></fA11><fA12 i1="01" i2="1"><s1>BERGEL (A.)</s1><s9>ed.</s9></fA12><fA12 i1="02" i2="1"><s1>BOND (A. 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All rights reserved.</s1></fA44><fA45><s0>17 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>12-0325092</s0></fA47><fA60><s1>P</s1><s2>C</s2></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Electrochimica acta</s0></fA64><fA66 i1="01"><s0>GBR</s0></fA66><fC01 i1="01" l="ENG"><s0>Electrochemical properties of graphite electrode are studied in propylene carbonate (PC) electrolytes containing both LiN(SO<sub>2</sub>CF<sub>3</sub>)<sub>2</sub> and Ca(N(SO<sub>2</sub>CF<sub>3</sub>)<sub>2</sub>)<sub>2</sub> salts, and the influence of the salt concentrations on the intercalation/de-intercalation properties of graphite electrode is clarified. In the higher concentration electrolytes, reversible lithium-ion intercalation/de-intercalation at graphite electrode takes place. In contrast, only the exfoliation of graphite occurs in the lower concentration electrolytes. The effect of the salt concentrations on the electrochemical properties of graphite is discussed.</s0></fC01><fC02 i1="01" i2="X"><s0>001D05I03E</s0></fC02><fC03 i1="01" i2="X" l="FRE"><s0>Effet milieu</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="ENG"><s0>Medium effect</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="SPA"><s0>Efecto medio</s0><s5>01</s5></fC03><fC03 i1="02" i2="X" l="FRE"><s0>Graphite</s0><s2>NC</s2><s5>02</s5></fC03><fC03 i1="02" i2="X" l="ENG"><s0>Graphite</s0><s2>NC</s2><s5>02</s5></fC03><fC03 i1="02" i2="X" l="SPA"><s0>Grafito</s0><s2>NC</s2><s5>02</s5></fC03><fC03 i1="03" i2="X" l="FRE"><s0>Electrode</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="ENG"><s0>Electrodes</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="SPA"><s0>Electrodo</s0><s5>03</s5></fC03><fC03 i1="04" i2="X" l="FRE"><s0>Solution électrolyte</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="ENG"><s0>Electrolyte solution</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="SPA"><s0>Solución electrólito</s0><s5>04</s5></fC03><fC03 i1="05" i2="3" l="FRE"><s0>Spectrométrie impédance électrochimique</s0><s5>05</s5></fC03><fC03 i1="05" i2="3" l="ENG"><s0>Electrochemical impedance spectroscopy</s0><s5>05</s5></fC03><fC03 i1="06" i2="X" l="FRE"><s0>Insertion</s0><s5>07</s5></fC03><fC03 i1="06" i2="X" l="ENG"><s0>Insertion</s0><s5>07</s5></fC03><fC03 i1="06" i2="X" l="SPA"><s0>Inserción</s0><s5>07</s5></fC03><fC03 i1="07" i2="X" l="FRE"><s0>Ion lithium</s0><s5>08</s5></fC03><fC03 i1="07" i2="X" l="ENG"><s0>Lithium ion</s0><s5>08</s5></fC03><fC03 i1="07" i2="X" l="SPA"><s0>Litio ión</s0><s5>08</s5></fC03><fC03 i1="08" i2="X" l="FRE"><s0>Carbonate organique</s0><s5>32</s5></fC03><fC03 i1="08" i2="X" l="ENG"><s0>Organic carbonate</s0><s5>32</s5></fC03><fC03 i1="08" i2="X" l="SPA"><s0>Carbonato orgánico</s0><s5>32</s5></fC03><fC03 i1="09" i2="X" l="FRE"><s0>Accumulateur électrochimique</s0><s5>33</s5></fC03><fC03 i1="09" i2="X" l="ENG"><s0>Secondary cell</s0><s5>33</s5></fC03><fC03 i1="09" i2="X" l="SPA"><s0>Acumulador electroquímico</s0><s5>33</s5></fC03><fC03 i1="10" i2="X" l="FRE"><s0>1,3-Dioxolan-2-one(méthyl)</s0><s2>NK</s2><s4>INC</s4><s5>76</s5></fC03><fC03 i1="11" i2="X" l="FRE"><s0>Lithium amidure(bis[trifluorosulfonyl])</s0><s2>NK</s2><s4>INC</s4><s5>77</s5></fC03><fC03 i1="12" i2="X" l="FRE"><s0>Calcium amidure(bis[trifluorosulfonyl])</s0><s2>NK</s2><s4>INC</s4><s5>78</s5></fC03><fC03 i1="13" i2="X" l="FRE"><s0>Batterie lithium ion</s0><s4>CD</s4><s5>96</s5></fC03><fC03 i1="13" i2="X" l="ENG"><s0>Lithion ion batteries</s0><s4>CD</s4><s5>96</s5></fC03><fN21><s1>247</s1></fN21></pA><pR><fA30 i1="01" i2="1" l="ENG"><s1>International Society of Electrochemistry (ISE) Meeting</s1><s2>61</s2><s3>Nice FRA</s3><s4>2010-09-26</s4></fA30></pR></standard></inist><affiliations><list><country><li>Japon</li></country><region><li>Région du Kansai</li></region><settlement><li>Kyoto</li></settlement><orgName><li>Université de Kyoto</li></orgName></list><tree><country name="Japon"><region name="Région du Kansai"><name sortKey="Takeuchi, S" sort="Takeuchi, S" uniqKey="Takeuchi S" first="S." last="Takeuchi">S. Takeuchi</name></region><name sortKey="Abe, T" sort="Abe, T" uniqKey="Abe T" first="T." last="Abe">T. Abe</name><name sortKey="Fukutsuka, T" sort="Fukutsuka, T" uniqKey="Fukutsuka T" first="T." last="Fukutsuka">T. Fukutsuka</name><name sortKey="Jeong, S K" sort="Jeong, S K" uniqKey="Jeong S" first="S.-K." last="Jeong">S.-K. Jeong</name><name sortKey="Miyazaki, K" sort="Miyazaki, K" uniqKey="Miyazaki K" first="K." last="Miyazaki">K. Miyazaki</name><name sortKey="Sagane, F" sort="Sagane, F" uniqKey="Sagane F" first="F." last="Sagane">F. Sagane</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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