Different Complexation Behavior of P-Functionalized Ferrocene Derivatives Towards SnCl2 , SnCl4 and SnPh2 Cl2 : Auto-ionization and Redox-Type Reactions.
Identifieur interne : 002F24 ( Main/Exploration ); précédent : 002F23; suivant : 002F25Different Complexation Behavior of P-Functionalized Ferrocene Derivatives Towards SnCl2 , SnCl4 and SnPh2 Cl2 : Auto-ionization and Redox-Type Reactions.
Auteurs : Matthias Gawron ; Christina Dietz ; Michael Lutter ; Andrew Duthie ; Viatcheslav Jouikov ; Klaus Jurkschat [Allemagne]Source :
- Chemistry (Weinheim an der Bergstrasse, Germany) [ 1521-3765 ] ; 2015.
Abstract
The novel phosphonyl-substituted ferrocene derivatives [Fe(η(5) -Cp)(η(5) -C5 H3 {P(O)(O-iPr)2 }2 -1,2)] (Fc(1,2) ) and [Fe{η(5) -C5 H4 P(O)(O-iPr)2 }2 ] (Fc(1,1') ) react with SnCl2 , SnCl4 , and SnPh2 Cl2 , giving the corresponding complexes [(Fc(1,2) )2 SnCl][SnCl3 ] (1), [{(Fc(1,1') )SnCl2 }n ] (2), [(Fc(1,1') )SnCl4 ] (3), [{(Fc(1,1') )SnPh2 Cl2 }n ] (4), and [(Fc(1,2) )SnCl4 ] (5), respectively. The compounds are characterized by elemental analyses, (1) H, (13) C, (31) P, (119) Sn NMR and IR spectroscopy, (31) P and (119) Sn CP-MAS NMR spectroscopy, cyclovoltammetry, electrospray ionization mass spectrometry, and single-crystal as well as powder X-ray diffraction analyses. The experimental work is accompanied by DFT calculations, which help to shed light on the origin for the different reaction behavior of Fc(1,1') and Fc(1,2) towards tin(II) chloride.
DOI: 10.1002/chem.201501999
PubMed: 26480839
Affiliations:
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uniqKey="Gawron M" first="Matthias" last="Gawron">Matthias Gawron</name><affiliation><nlm:affiliation>Lehrstuhl für Anorganische Chemie II, Fakultät Chemie und Chemische Biologie der Technischen Universität Dortmund, 44221 Dortmund (Germany).</nlm:affiliation><wicri:noCountry code="subField">44221 Dortmund (Germany)</wicri:noCountry></affiliation></author><author><name sortKey="Dietz, Christina" sort="Dietz, Christina" uniqKey="Dietz C" first="Christina" last="Dietz">Christina Dietz</name><affiliation><nlm:affiliation>Lehrstuhl für Anorganische Chemie II, Fakultät Chemie und Chemische Biologie der Technischen Universität Dortmund, 44221 Dortmund (Germany).</nlm:affiliation><wicri:noCountry code="subField">44221 Dortmund (Germany)</wicri:noCountry></affiliation></author><author><name sortKey="Lutter, Michael" sort="Lutter, Michael" uniqKey="Lutter M" first="Michael" last="Lutter">Michael Lutter</name><affiliation><nlm:affiliation>Lehrstuhl für Anorganische Chemie II, Fakultät Chemie und 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[(Fc(1,2) )2 SnCl][SnCl3 ] (1), [{(Fc(1,1') )SnCl2 }n ] (2), [(Fc(1,1') )SnCl4 ] (3), [{(Fc(1,1') )SnPh2 Cl2 }n ] (4), and [(Fc(1,2) )SnCl4 ] (5), respectively. The compounds are characterized by elemental analyses, (1) H, (13) C, (31) P, (119) Sn NMR and IR spectroscopy, (31) P and (119) Sn CP-MAS NMR spectroscopy, cyclovoltammetry, electrospray ionization mass spectrometry, and single-crystal as well as powder X-ray diffraction analyses. 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