AustralieFrV1, Main, Exploration, bibRecord, 00AF02

Pendent Arm Formation and Extension accompanying Macrocycle Synthesis − A New Class of Ryongamines?

Identifieur interne : 00AF02 ( Main/Exploration ); précédent : 00AF01; suivant : 00AF03

Pendent Arm Formation and Extension accompanying Macrocycle Synthesis − A New Class of Ryongamines?

Auteurs : Jack Harrowfield [Australie] ; Yang Kim [Corée du Sud] ; Young Hoon Lee [Corée du Sud] ; Pierre Thuéry [France]

Source :

European Journal of Inorganic Chemistry [ 1434-1948 ] ; 2003-08.

RBID : ISTEX:D9ADA2DC9E24BA32268AB575E7AC5D025E19F7EE

English descriptors

KwdEn :
- Aminal, Aminal bridge, Bernhardt, Carbanion addition, Chem, Chiral, Chiral centre, Cuii, Dalton trans, Donor atoms, Formaldehyde, Gmbh, Harrowfield, Hydrogen atoms, Imine, Inorg, Kgaa, Ligand, Macrocycle, Macrocyclic, Macrocyclic ring, Nitroethane, Oxygen atoms, Partial oxidation, Pendent, Possible sequence, Reaction mixture, Short communication, Sodium citrate, Trans, Verlag, Verlag gmbh, Weinheim.
Teeft :
- Aminal, Aminal bridge, Bernhardt, Carbanion addition, Chem, Chiral, Chiral centre, Cuii, Dalton trans, Donor atoms, Formaldehyde, Gmbh, Harrowfield, Hydrogen atoms, Imine, Inorg, Kgaa, Ligand, Macrocycle, Macrocyclic, Macrocyclic ring, Nitroethane, Oxygen atoms, Partial oxidation, Pendent, Possible sequence, Reaction mixture, Short communication, Sodium citrate, Trans, Verlag, Verlag gmbh, Weinheim.

Abstract

Reaction of the CuII complex of the podand hexamine “sen”, CH3C(CH2NHCH2CH2NH2)3, with formaldehyde and nitroethane under basic conditions provides, as one of the principal products, a complex containing a new ligand which is not only macrocyclic but which has resulted also from reactions to extend one podand arm, to introduce an aminal bridge and to oxidise one of the donor‐N atom units to an imine. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

Url:

https://api.istex.fr/document/D9ADA2DC9E24BA32268AB575E7AC5D025E19F7EE/fulltext/pdf

DOI: 10.1002/ejic.200300349

Affiliations:

Links toward previous steps (curation, corpus...)

to stream Istex, to step Corpus: 002861
to stream Istex, to step Curation: 002861
to stream Istex, to step Checkpoint: 001B08
to stream Main, to step Merge: 00BC41
to stream Main, to step Curation: 00AF02

Le document en format XML

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<term>Partial oxidation</term>
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<term>Possible sequence</term>
<term>Reaction mixture</term>
<term>Short communication</term>
<term>Sodium citrate</term>
<term>Trans</term>
<term>Verlag</term>
<term>Verlag gmbh</term>
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<front><div type="abstract" xml:lang="en">Reaction of the CuII complex of the podand hexamine “sen”, CH3C(CH2NHCH2CH2NH2)3, with formaldehyde and nitroethane under basic conditions provides, as one of the principal products, a complex containing a new ligand which is not only macrocyclic but which has resulted also from reactions to extend one podand arm, to introduce an aminal bridge and to oxidise one of the donor‐N atom units to an imine. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)</div>
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Pendent Arm Formation and Extension accompanying Macrocycle Synthesis − A New Class of Ryongamines?

Pendent Arm Formation and Extension accompanying Macrocycle Synthesis − A New Class of Ryongamines?

Source :

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri