Hybrid layered double hydroxides-polypyrrole composites for construction of glucose/O2 biofuel cell
Identifieur interne : 006A32 ( Main/Exploration ); précédent : 006A31; suivant : 006A33Hybrid layered double hydroxides-polypyrrole composites for construction of glucose/O2 biofuel cell
Auteurs : Abdelkader Zebda [France] ; Sophie Tingry [France] ; Christophe Innocent [France] ; Serge Cosnier [France] ; Claude Forano [France] ; Christine Mousty [France]Source :
- Electrochimica acta [ 0013-4686 ] ; 2011.
Descripteurs français
- Pascal (Inist)
- Hydroxyde double lamellaire, Pyrrole polymère, Matériau composite, Glucose oxidase, Pile combustible biochimique, Laccase, Enzyme immobilisée, Diffraction RX, Glucose, Oxygène, Oxydation, Réduction chimique, Catalyse enzymatique, Electrocatalyse, Polymère conducteur, Spectrométrie IR, Transformation Fourier, Réaction électrochimique, FT IR.
- Wicri :
- topic : Matériau composite, Glucose, Oxygène.
English descriptors
- KwdEn :
- Biochemical fuel cell, Chemical reduction, Composite material, Conducting polymers, Electrocatalysis, Electrochemical reaction, Enzymatic catalysis, Fourier transformation, Glucose, Glucose oxidase, Immobilized enzyme, Infrared spectrometry, Laccase, Layered double hydroxide, Oxidation, Oxygen, Pyrrole polymer, X ray diffraction.
Abstract
In this work, two layered double hydroxides, Zn2Cr-ABTS and Zn2Al-Fe(CN)6 LDH, have been synthesized and characterized by X ray diffraction and FTIR spectroscopy to confirm the intercalation of redox anions between inorganic layers. These redox active hybrid materials have been used to electrically connect laccase (Lac) and glucose oxidase (GOx) in biofuel cell devices. Co-immobilization of hybrid LDH and enzymes has been performed by entrapment in electropolymerized films of polypyrrole deposited on porous carbon tubular electrodes. Lac/Zn2Cr-ABTS cathodic electrode allows the electro-enzymatic reduction of O2, whereas the anodic electrode GOx/Zn2Al-FeIII(CN)6was used for the electro-enzymatic oxidation of glucose. With a two compartment configuration, a maximum power density of 45 μW cm-2 was obtained at 0.2 V.
Affiliations:
- France
- Auvergne (région administrative), Auvergne-Rhône-Alpes, Languedoc-Roussillon, Occitanie (région administrative), Rhône-Alpes
- Aubière, Grenoble, Montpellier
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Le document en format XML
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<series><title level="j" type="main">Electrochimica acta</title>
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<term>Chemical reduction</term>
<term>Composite material</term>
<term>Conducting polymers</term>
<term>Electrocatalysis</term>
<term>Electrochemical reaction</term>
<term>Enzymatic catalysis</term>
<term>Fourier transformation</term>
<term>Glucose</term>
<term>Glucose oxidase</term>
<term>Immobilized enzyme</term>
<term>Infrared spectrometry</term>
<term>Laccase</term>
<term>Layered double hydroxide</term>
<term>Oxidation</term>
<term>Oxygen</term>
<term>Pyrrole polymer</term>
<term>X ray diffraction</term>
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<keywords scheme="Pascal" xml:lang="fr"><term>Hydroxyde double lamellaire</term>
<term>Pyrrole polymère</term>
<term>Matériau composite</term>
<term>Glucose oxidase</term>
<term>Pile combustible biochimique</term>
<term>Laccase</term>
<term>Enzyme immobilisée</term>
<term>Diffraction RX</term>
<term>Glucose</term>
<term>Oxygène</term>
<term>Oxydation</term>
<term>Réduction chimique</term>
<term>Catalyse enzymatique</term>
<term>Electrocatalyse</term>
<term>Polymère conducteur</term>
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<term>FT IR</term>
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<front><div type="abstract" xml:lang="en">In this work, two layered double hydroxides, Zn<sub>2</sub>
Cr-ABTS and Zn<sub>2</sub>
Al-Fe(CN)<sub>6</sub>
LDH, have been synthesized and characterized by X ray diffraction and FTIR spectroscopy to confirm the intercalation of redox anions between inorganic layers. These redox active hybrid materials have been used to electrically connect laccase (Lac) and glucose oxidase (GOx) in biofuel cell devices. Co-immobilization of hybrid LDH and enzymes has been performed by entrapment in electropolymerized films of polypyrrole deposited on porous carbon tubular electrodes. Lac/Zn<sub>2</sub>
Cr-ABTS cathodic electrode allows the electro-enzymatic reduction of O<sub>2</sub>
, whereas the anodic electrode GOx/Zn<sub>2</sub>
Al-Fe<sup>III</sup>
(CN)<sub>6</sub>
was used for the electro-enzymatic oxidation of glucose. With a two compartment configuration, a maximum power density of 45 μW cm<sup>-2 </sup>
was obtained at 0.2 V.</div>
</front>
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