Raman spectroscopy of gallium‐ and zinc‐based hydrotalcites
Identifieur interne : 006341 ( Main/Exploration ); précédent : 006340; suivant : 006342Raman spectroscopy of gallium‐ and zinc‐based hydrotalcites
Auteurs : Sara J. Palmer [Australie] ; Ray L. Frost [Australie] ; Laure-Marie Grand [Australie, France]Source :
- Journal of Raman Spectroscopy [ 0377-0486 ] ; 2011-05.
Descripteurs français
- Wicri :
- topic : Droit d'auteur.
English descriptors
- KwdEn :
- Ambient temperature, Anion, Carbonate, Carbonate anion, Carbonate anions, Cation, Clays clay miner, Colloid interface, Copyright, Different environments, Different types, Divalent cation, Double hydroxides, Grand figure, Hydroxide layers, Hydroxyl, Infrared bands, Infrared spectra, Infrared spectroscopy, Infrared spectrum, Ingaas detector, Intense band, Interlayer, Interlayer spacing, John wiley sons, Multiple bands, Multiple carbonate species, Online version, Overall band, Perturbed state, Queensland university, Raman, Raman bands, Raman spectra, Raman spectrosc, Raman spectroscopy, Raman spectrum, Reference pattern, Spectrosc, Spectroscopy, Trivalent cation, Zinc content.
- Teeft :
- Ambient temperature, Anion, Carbonate, Carbonate anion, Carbonate anions, Cation, Clays clay miner, Colloid interface, Copyright, Different environments, Different types, Divalent cation, Double hydroxides, Grand figure, Hydroxide layers, Hydroxyl, Infrared bands, Infrared spectra, Infrared spectroscopy, Infrared spectrum, Ingaas detector, Intense band, Interlayer, Interlayer spacing, John wiley sons, Multiple bands, Multiple carbonate species, Online version, Overall band, Perturbed state, Queensland university, Raman, Raman bands, Raman spectra, Raman spectrosc, Raman spectroscopy, Raman spectrum, Reference pattern, Spectrosc, Spectroscopy, Trivalent cation, Zinc content.
Abstract
Insight into the unique structure of hydrotalcites (HTs) has been obtained using Raman spectroscopy. Gallium‐containing HTs of formula Zn4 Ga2(CO3)(OH)12 · xH2O (2:1 ZnGa‐HT), Zn6 Ga2(CO3)(OH)16 · xH2O (3:1 ZnGa‐HT) and Zn8 Ga2(CO3)(OH)18 · xH2O (4:1 ZnGa‐HT) have been successfully synthesised and characterised by X‐ray diffraction (XRD) and Raman spectroscopy. The d(003) spacing varies from 7.62 Å for the 2:1 ZnGa‐HT to 7.64 Å for the 3:1 ZnGa‐HT. The 4:1 ZnGa‐HT showed a decrease in the d(003) spacing, compared to the 2:1 and 3:1 compounds. Raman spectroscopy complemented with selected infrared data has been used to characterise the synthesised gallium‐containing HTs. Raman bands observed at around 1050, 1060 and 1067 cm−1 are attributed to the symmetric stretching modes of the (CO32−) units. Multiple ν3 (CO32−) antisymmetric stretching modes are found between 1350 and 1520 cm−1, confirming multiple carbonate species in the HT structure. The splitting of this mode indicates that the carbonate anion is in a perturbed state. Raman bands observed at 710 and 717 cm−1 and assigned to the ν4 (CO32−) modes support the concept of multiple carbonate species in the interlayer. Copyright © 2010 John Wiley & Sons, Ltd.
Url:
DOI: 10.1002/jrs.2831
Affiliations:
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Le document en format XML
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<front><div type="abstract" xml:lang="en">Insight into the unique structure of hydrotalcites (HTs) has been obtained using Raman spectroscopy. Gallium‐containing HTs of formula Zn4 Ga2(CO3)(OH)12 · xH2O (2:1 ZnGa‐HT), Zn6 Ga2(CO3)(OH)16 · xH2O (3:1 ZnGa‐HT) and Zn8 Ga2(CO3)(OH)18 · xH2O (4:1 ZnGa‐HT) have been successfully synthesised and characterised by X‐ray diffraction (XRD) and Raman spectroscopy. The d(003) spacing varies from 7.62 Å for the 2:1 ZnGa‐HT to 7.64 Å for the 3:1 ZnGa‐HT. The 4:1 ZnGa‐HT showed a decrease in the d(003) spacing, compared to the 2:1 and 3:1 compounds. Raman spectroscopy complemented with selected infrared data has been used to characterise the synthesised gallium‐containing HTs. Raman bands observed at around 1050, 1060 and 1067 cm−1 are attributed to the symmetric stretching modes of the (CO32−) units. Multiple ν3 (CO32−) antisymmetric stretching modes are found between 1350 and 1520 cm−1, confirming multiple carbonate species in the HT structure. The splitting of this mode indicates that the carbonate anion is in a perturbed state. Raman bands observed at 710 and 717 cm−1 and assigned to the ν4 (CO32−) modes support the concept of multiple carbonate species in the interlayer. Copyright © 2010 John Wiley & Sons, Ltd.</div>
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