AustralieFrV1, Main, Curation, bibRecord, 00BF74

Linear, Divergent Molecular Receptors – Subtle Effects of Transition Metal Coordination Geometry

Identifieur interne : 00BF74 ( Main/Curation ); précédent : 00BF73; suivant : 00BF75

Linear, Divergent Molecular Receptors – Subtle Effects of Transition Metal Coordination Geometry

Auteurs : Alexander Bilyk ; Annegret K. Hall ; Jack M. Harrowfield [Australie] ; Mir Wais Hosseini [France] ; Gilles Mislin [France] ; Brian W. Skelton [Australie] ; Christopher Taylor [Australie] ; Allan H. White [Australie]

Source :

European Journal of Inorganic Chemistry [ 1434-1948 ] ; 2000-05.

RBID : ISTEX:A7B779B8AF903C7DBCAB9EA9A50E731D4B219749

English descriptors

KwdEn :
- Calixarene, Calixarene cones, Chem, Coii, Coordination geometry, Cuii compound, Electronic spectrum, Inorg, Metal atom, Metal atoms, Mmol, Phenoxide, Residual, Residual protons, Short communication, Solid state, Space group, Stoichiometry, Structural determination, Vacuum filtration, Western australia, White powder.
Teeft :
- Calixarene, Calixarene cones, Chem, Coii, Coordination geometry, Cuii compound, Electronic spectrum, Inorg, Metal atom, Metal atoms, Mmol, Phenoxide, Residual, Residual protons, Short communication, Solid state, Space group, Stoichiometry, Structural determination, Vacuum filtration, Western australia, White powder.

Abstract

Reaction between deprotonated p‐tert‐butyltetrathiacalix[4]arene and CoII or ZnII under strictly defined conditions leads to the formation of sandwich species in which a trimetallic unit is held between two opposed, divergently oriented, staggered O‐ and S‐bound calixarene ligands in the cone conformation. Despite the isomorphous nature of the crystalline compounds, there is a subtle difference in the coordination of CoII and ZnII, presumably related to the differences in metal radius and electron configuration combined with structural restrictions imposed by the calixarene framework, in that whereas all three Co atoms may be considered six‐coordinate (and approximately octahedral), only two of the Zn atoms appear so, the third being five‐coordinate and more nearly trigonal bipyramidal in its coordination geometry.

Url:

https://api.istex.fr/document/A7B779B8AF903C7DBCAB9EA9A50E731D4B219749/fulltext/pdf

DOI: 10.1002/(SICI)1099-0682(200005)2000:5<823::AID-EJIC823>3.0.CO;2-Z

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ISTEX:A7B779B8AF903C7DBCAB9EA9A50E731D4B219749

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Alexander Bilyk

<affiliation><wicri:noCountry code="subField">61‐89/380‐1116</wicri:noCountry>
</affiliation>

Annegret K. Hall

<affiliation><wicri:noCountry code="subField">61‐89/380‐1116</wicri:noCountry>
</affiliation>

Le document en format XML

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<front><div type="abstract" xml:lang="en">Reaction between deprotonated p‐tert‐butyltetrathiacalix[4]arene and CoII or ZnII under strictly defined conditions leads to the formation of sandwich species in which a trimetallic unit is held between two opposed, divergently oriented, staggered O‐ and S‐bound calixarene ligands in the cone conformation. Despite the isomorphous nature of the crystalline compounds, there is a subtle difference in the coordination of CoII and ZnII, presumably related to the differences in metal radius and electron configuration combined with structural restrictions imposed by the calixarene framework, in that whereas all three Co atoms may be considered six‐coordinate (and approximately octahedral), only two of the Zn atoms appear so, the third being five‐coordinate and more nearly trigonal bipyramidal in its coordination geometry.</div>
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Linear, Divergent Molecular Receptors – Subtle Effects of Transition Metal Coordination Geometry

Linear, Divergent Molecular Receptors – Subtle Effects of Transition Metal Coordination Geometry

Source :

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Curation

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Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri