Amphiphile Structures in the Solid State: Complex Cations with Lipophilic Substituents
Identifieur interne : 001302 ( Istex/Curation ); précédent : 001301; suivant : 001303Amphiphile Structures in the Solid State: Complex Cations with Lipophilic Substituents
Auteurs : Jack M. Harrowfield [France, Australie] ; George A. Koutsantonis [Australie] ; Gareth L. Nealon [Australie] ; Brian W. Skelton [Australie] ; Allan H. White [Australie]Source :
- European Journal of Inorganic Chemistry [ 1434-1948 ] ; 2005-06.
English descriptors
- KwdEn :
- Absolute etoh, Aggregation, Amine, Amphiphile structures, Anion, Aqueous solution, Asymmetric unit, Butyl, Butyl chain, Butyl substituents, Cage amine, Cage units, Cation, Centre, Chem, Chloride anions, Chloride ions, Coiii, Columnar arrays, Complex cations, Complex unit, Crystal structure, Dalton trans, Dialkylated, Dialkylated product, Dialkylated species, Formula unit, Full paper, Gmbh, Harrowfield, Head group, Hydrogen atoms, Inorg, Kgaa, Lattice, Lattice energy, Ligand, Other components, Present case, Reaction mixture, Same chirality, Sargeson, Simple salts, Skelton, Small amount, Solid state, Steam bath, Surfactant, Surfactant properties, Trial refinement, Unit cell contents, Vapour diffusion, Verlag, Verlag gmbh, Water molecule, Water molecules, Weinheim, Western australia.
- Teeft :
- Absolute etoh, Aggregation, Amine, Amphiphile structures, Anion, Aqueous solution, Asymmetric unit, Butyl, Butyl chain, Butyl substituents, Cage amine, Cage units, Cation, Centre, Chem, Chloride anions, Chloride ions, Coiii, Columnar arrays, Complex cations, Complex unit, Crystal structure, Dalton trans, Dialkylated, Dialkylated product, Dialkylated species, Formula unit, Full paper, Gmbh, Harrowfield, Head group, Hydrogen atoms, Inorg, Kgaa, Lattice, Lattice energy, Ligand, Other components, Present case, Reaction mixture, Same chirality, Sargeson, Simple salts, Skelton, Small amount, Solid state, Steam bath, Surfactant, Surfactant properties, Trial refinement, Unit cell contents, Vapour diffusion, Verlag, Verlag gmbh, Water molecule, Water molecules, Weinheim, Western australia.
Abstract
Structural characterisation of hexamine cage complexes, two containing diamagnetic CoIII and one containing paramagnetic CuII, to which both rather short (C4) and relatively long (C13) alkyl substituents have been attached, shows that while the longer “tail” introduces an anticipated bilayer form to the crystalline solid, even the shorter tail can be associated with a form of aggregation of lipophilic entities in the crystal. The short tail at least may also be involved in interactions with anions of a complex type. As surfactants, functionalised cage complexes contain a head group, which is a multi‐site hydrogen‐bonding entity, and which can thus provide a mechanism for further aggregation concomitant with that of any apolar functionality. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
Url:
DOI: 10.1002/ejic.200500085
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The short tail at least may also be involved in interactions with anions of a complex type. As surfactants, functionalised cage complexes contain a head group, which is a multi‐site hydrogen‐bonding entity, and which can thus provide a mechanism for further aggregation concomitant with that of any apolar functionality. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)</div></front></TEI></record>Pour manipuler ce document sous Unix (Dilib)
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