AustralieFrV1, Istex, Curation, bibRecord, 001108

Interlaboratory comparison study of calibration standards for foraminiferal Mg/Ca thermometry

Identifieur interne : 001108 ( Istex/Curation ); précédent : 001107; suivant : 001109

Interlaboratory comparison study of calibration standards for foraminiferal Mg/Ca thermometry

Auteurs : M. Greaves [Royaume-Uni] ; N. Caillon [France] ; H. Rebaubier [France] ; G. Bartoli [Allemagne, Suisse] ; S. Bohaty [États-Unis, Royaume-Uni] ; I. Cacho [Espagne] ; L. Clarke [Royaume-Uni] ; M. Cooper [Royaume-Uni] ; C. Daunt [Royaume-Uni] ; M. Delaney [États-Unis] ; P. Demenocal [États-Unis] ; A. Dutton [Australie] ; S. Eggins [Australie] ; H. Elderfield [Royaume-Uni] ; D. Garbe-Schoenberg [Allemagne] ; E. Goddard [États-Unis] ; D. Green [Royaume-Uni] ; J. Groeneveld [Allemagne] ; D. Hastings [États-Unis] ; E. Hathorne [Royaume-Uni, Allemagne] ; K. Kimoto [Japon] ; G. Klinkhammer [États-Unis] ; L. Labeyrie [France] ; D. W. Lea [États-Unis] ; T. Marchitto [États-Unis] ; M. A. Martínez-Botí [Espagne] ; P. G. Mortyn [Espagne] ; Y. Ni [Royaume-Uni] ; D. Nuernberg [Allemagne] ; G. Paradis [États-Unis] ; L. Pena [Espagne] ; T. Quinn [États-Unis] ; Y. Rosenthal [États-Unis] ; A. Russell [États-Unis] ; T. Sagawa [Japon] ; S. Sosdian [États-Unis] ; L. Stott [États-Unis] ; K. Tachikawa [France] ; E. Tappa [États-Unis] ; R. Thunell [États-Unis] ; P. A. Wilson [Royaume-Uni]

Source :

Geochemistry, Geophysics, Geosystems [ 1525-2027 ] ; 2008-08.

RBID : ISTEX:5A2F2A65E4761438CD02460D6A0E72947665DD01

Descripteurs français

Wicri :
- topic : Sciences de la terre, Géochimie, Géophysique.

English descriptors

Abstract

An interlaboratory study of Mg/Ca and Sr/Ca ratios in three commercially available carbonate reference materials (BAM RS3, CMSI 1767, and ECRM 752‐1) was performed with the participation of 25 laboratories that determine foraminiferal Mg/Ca ratios worldwide. These reference materials containing Mg/Ca in the range of foraminiferal calcite (0.8 mmol/mol to 6 mmol/mol) were circulated with a dissolution protocol for analysis. Participants were asked to make replicate dissolutions of the powdered samples and to analyze them using the instruments and calibration standards routinely used in their laboratories. Statistical analysis was performed in accordance with the International Standardization Organization standard 5725, which is based on the analysis of variance (ANOVA) technique. Repeatability (RSDr%), an indicator of intralaboratory precision, for Mg/Ca determinations in solutions after centrifuging increased with decreasing Mg/Ca, ranging from 0.78% at Mg/Ca = 5.56 mmol/mol to 1.15% at Mg/Ca = 0.79 mmol/mol. Reproducibility (RSDR%), an indicator of the interlaboratory method precision, for Mg/Ca determinations in centrifuged solutions was noticeably worse than repeatability, ranging from 4.5% at Mg/Ca = 5.56 mmol/mol to 8.7% at Mg/Ca = 0.79 mmol/mol. Results of this study show that interlaboratory variability is dominated by inconsistencies among instrument calibrations and highlight the need to improve interlaboratory compatibility. Additionally, the study confirmed the suitability of these solid standards as reference materials for foraminiferal Mg/Ca (and Sr/Ca) determinations, provided that appropriate procedures are adopted to minimize and to monitor possible contamination from silicate mineral phases.

Url:

https://api.istex.fr/document/5A2F2A65E4761438CD02460D6A0E72947665DD01/fulltext/pdf

DOI: 10.1029/2008GC001974

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<affiliation wicri:level="1"><mods:affiliation>Department of Earth Sciences, University of Cambridge, Downing Street,, CB2 3EQ, Cambridge, UK</mods:affiliation>
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<author><name sortKey="Clarke, L" sort="Clarke, L" uniqKey="Clarke L" first="L." last="Clarke">L. Clarke</name>
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<author><name sortKey="Cooper, M" sort="Cooper, M" uniqKey="Cooper M" first="M." last="Cooper">M. Cooper</name>
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<author><name sortKey="Daunt, C" sort="Daunt, C" uniqKey="Daunt C" first="C." last="Daunt">C. Daunt</name>
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<country xml:lang="fr">Royaume-Uni</country>
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<author><name sortKey="Delaney, M" sort="Delaney, M" uniqKey="Delaney M" first="M." last="Delaney">M. Delaney</name>
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<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Ocean Sciences, University of California, Santa Cruz, California, 95060, Santa Cruz</wicri:regionArea>
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<author><name sortKey="Demenocal, P" sort="Demenocal, P" uniqKey="Demenocal P" first="P." last="Demenocal">P. Demenocal</name>
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<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Lamont‐Doherty Earth Observatory, Columbia University, Geoscience 211, Route 9W,, New York, 10964, Palisades</wicri:regionArea>
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<author><name sortKey="Dutton, A" sort="Dutton, A" uniqKey="Dutton A" first="A." last="Dutton">A. Dutton</name>
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<author><name sortKey="Eggins, S" sort="Eggins, S" uniqKey="Eggins S" first="S." last="Eggins">S. Eggins</name>
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<author><name sortKey="Elderfield, H" sort="Elderfield, H" uniqKey="Elderfield H" first="H." last="Elderfield">H. Elderfield</name>
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<country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>Department of Earth Sciences, University of Cambridge, Downing Street,, CB2 3EQ, Cambridge</wicri:regionArea>
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<author><name sortKey="Garbe Choenberg, D" sort="Garbe Choenberg, D" uniqKey="Garbe Choenberg D" first="D." last="Garbe-Schoenberg">D. Garbe-Schoenberg</name>
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<author><name sortKey="Goddard, E" sort="Goddard, E" uniqKey="Goddard E" first="E." last="Goddard">E. Goddard</name>
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<country xml:lang="fr">États-Unis</country>
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<author><name sortKey="Green, D" sort="Green, D" uniqKey="Green D" first="D." last="Green">D. Green</name>
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<affiliation wicri:level="1"><mods:affiliation>Now at Research Center Ocean Margins, University of Bremen, D‐28359 Bremen, Germany.</mods:affiliation>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea>Now at Research Center Ocean Margins, University of Bremen, D‐28359 Bremen</wicri:regionArea>
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<author><name sortKey="Hastings, D" sort="Hastings, D" uniqKey="Hastings D" first="D." last="Hastings">D. Hastings</name>
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<country xml:lang="fr">États-Unis</country>
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<author><name sortKey="Hathorne, E" sort="Hathorne, E" uniqKey="Hathorne E" first="E." last="Hathorne">E. Hathorne</name>
<affiliation wicri:level="1"><mods:affiliation>Department of Earth Sciences, Open University, Milton Keynes, UK</mods:affiliation>
<country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>Department of Earth Sciences, Open University, Milton Keynes</wicri:regionArea>
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<affiliation wicri:level="1"><mods:affiliation>Now at Research Center Ocean Margins, University of Bremen, D‐28359 Bremen, Germany.</mods:affiliation>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea>Now at Research Center Ocean Margins, University of Bremen, D‐28359 Bremen</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Kimoto, K" sort="Kimoto, K" uniqKey="Kimoto K" first="K." last="Kimoto">K. Kimoto</name>
<affiliation wicri:level="1"><mods:affiliation>Institute of Observational Research for Global Change, JAMSTEC, 2–15, Natsushima‐cho,, 247‐0061, Yokosuka, Japan</mods:affiliation>
<country xml:lang="fr">Japon</country>
<wicri:regionArea>Institute of Observational Research for Global Change, JAMSTEC, 2–15, Natsushima‐cho,, 247‐0061, Yokosuka</wicri:regionArea>
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<author><name sortKey="Klinkhammer, G" sort="Klinkhammer, G" uniqKey="Klinkhammer G" first="G." last="Klinkhammer">G. Klinkhammer</name>
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<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>College of Oceanography, Oregon State University, Oceanography Administration Building 104,, Oregon, 97331, Corvallis</wicri:regionArea>
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<author><name sortKey="Labeyrie, L" sort="Labeyrie, L" uniqKey="Labeyrie L" first="L." last="Labeyrie">L. Labeyrie</name>
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<country xml:lang="fr">France</country>
<wicri:regionArea>LSCE/IPSL, UMR CNRS, CEA, UVSQ, Bâtiment 12, avenue de la Terrasse,, F‐91198, Gif sur Yvette</wicri:regionArea>
</affiliation>
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<author><name sortKey="Lea, D W" sort="Lea, D W" uniqKey="Lea D" first="D. W." last="Lea">D. W. Lea</name>
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<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Geological Sciences, University of California, Santa Barbara, Mail Stop 9630,, California, 93106, Santa Barbara</wicri:regionArea>
</affiliation>
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<author><name sortKey="Marchitto, T" sort="Marchitto, T" uniqKey="Marchitto T" first="T." last="Marchitto">T. Marchitto</name>
<affiliation wicri:level="1"><mods:affiliation>INSTAAR, University of Colorado, Colorado, 80309, Boulder, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>INSTAAR, University of Colorado, Colorado, 80309, Boulder</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Martinez Oti, M A" sort="Martinez Oti, M A" uniqKey="Martinez Oti M" first="M. A." last="Martínez-Botí">M. A. Martínez-Botí</name>
<affiliation wicri:level="1"><mods:affiliation>ICTA, Universitat Autònoma de Barcelona, Edifici Cn ‐ Campus UAB,, E‐08193, Bellaterra, Spain</mods:affiliation>
<country xml:lang="fr">Espagne</country>
<wicri:regionArea>ICTA, Universitat Autònoma de Barcelona, Edifici Cn ‐ Campus UAB,, E‐08193, Bellaterra</wicri:regionArea>
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</author>
<author><name sortKey="Mortyn, P G" sort="Mortyn, P G" uniqKey="Mortyn P" first="P. G." last="Mortyn">P. G. Mortyn</name>
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<country xml:lang="fr">Espagne</country>
<wicri:regionArea>ICTA, Universitat Autònoma de Barcelona, Edifici Cn ‐ Campus UAB,, E‐08193, Bellaterra</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Ni, Y" sort="Ni, Y" uniqKey="Ni Y" first="Y." last="Ni">Y. Ni</name>
<affiliation wicri:level="1"><mods:affiliation>Department of Earth Sciences, University of Bristol, Bristol, UK</mods:affiliation>
<country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>Department of Earth Sciences, University of Bristol, Bristol</wicri:regionArea>
</affiliation>
<affiliation><mods:affiliation>Now at Research Institute of Petroleum Exploration and Development, PetroChina, 20 Xueyuan Road, Haidian District, Beijing, China, 100083.</mods:affiliation>
<wicri:noCountry code="subField">100083.</wicri:noCountry>
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<author><name sortKey="Nuernberg, D" sort="Nuernberg, D" uniqKey="Nuernberg D" first="D." last="Nuernberg">D. Nuernberg</name>
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<country xml:lang="fr">Allemagne</country>
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</affiliation>
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<author><name sortKey="Paradis, G" sort="Paradis, G" uniqKey="Paradis G" first="G." last="Paradis">G. Paradis</name>
<affiliation wicri:level="1"><mods:affiliation>Department of Geological Sciences, University of California, Santa Barbara, Mail Stop 9630,, California, 93106, Santa Barbara, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Geological Sciences, University of California, Santa Barbara, Mail Stop 9630,, California, 93106, Santa Barbara</wicri:regionArea>
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<author><name sortKey="Pena, L" sort="Pena, L" uniqKey="Pena L" first="L." last="Pena">L. Pena</name>
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<country xml:lang="fr">Espagne</country>
<wicri:regionArea>GRC Geociències Marines, Department of Stratigraphy, Paleontology and Marine Geosciences, University of Barcelona, C/Martí i Franquès, s/n,, E‐08028, Barcelona</wicri:regionArea>
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<author><name sortKey="Quinn, T" sort="Quinn, T" uniqKey="Quinn T" first="T." last="Quinn">T. Quinn</name>
<affiliation wicri:level="1"><mods:affiliation>College of Marine Science, University of South Florida, Florida, 33701, St. Petersburg, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>College of Marine Science, University of South Florida, Florida, 33701, St. Petersburg</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Rosenthal, Y" sort="Rosenthal, Y" uniqKey="Rosenthal Y" first="Y." last="Rosenthal">Y. Rosenthal</name>
<affiliation wicri:level="1"><mods:affiliation>Institute of Marine and Coastal Sciences, Department of Geology, Rutgers, State University of New Jersey, 71 Dudley Road,, New Jersey, 08901, New Brunswick, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Institute of Marine and Coastal Sciences, Department of Geology, Rutgers, State University of New Jersey, 71 Dudley Road,, New Jersey, 08901, New Brunswick</wicri:regionArea>
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<author><name sortKey="Russell, A" sort="Russell, A" uniqKey="Russell A" first="A." last="Russell">A. Russell</name>
<affiliation wicri:level="1"><mods:affiliation>Department of Geology, University of California, Davis, One Shields Avenue,, California, 95616, Davis, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Geology, University of California, Davis, One Shields Avenue,, California, 95616, Davis</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Sagawa, T" sort="Sagawa, T" uniqKey="Sagawa T" first="T." last="Sagawa">T. Sagawa</name>
<affiliation wicri:level="1"><mods:affiliation>Center for Advanced Marine Core Research, Kochi University, B200 Monobe, Nankoku,, 783–8502, Kochi, Japan</mods:affiliation>
<country xml:lang="fr">Japon</country>
<wicri:regionArea>Center for Advanced Marine Core Research, Kochi University, B200 Monobe, Nankoku,, 783–8502, Kochi</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Sosdian, S" sort="Sosdian, S" uniqKey="Sosdian S" first="S." last="Sosdian">S. Sosdian</name>
<affiliation wicri:level="1"><mods:affiliation>Institute of Marine and Coastal Sciences, Department of Geology, Rutgers, State University of New Jersey, 71 Dudley Road,, New Jersey, 08901, New Brunswick, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Institute of Marine and Coastal Sciences, Department of Geology, Rutgers, State University of New Jersey, 71 Dudley Road,, New Jersey, 08901, New Brunswick</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Stott, L" sort="Stott, L" uniqKey="Stott L" first="L." last="Stott">L. Stott</name>
<affiliation wicri:level="1"><mods:affiliation>Department of Earth Sciences, University of South California, California, 90089, Los Angeles, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Earth Sciences, University of South California, California, 90089, Los Angeles</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Tachikawa, K" sort="Tachikawa, K" uniqKey="Tachikawa K" first="K." last="Tachikawa">K. Tachikawa</name>
<affiliation wicri:level="1"><mods:affiliation>CEREGE, UMR UAMIII, CNRS, CDF, IRD, Europôle Méditerranéen de l'Arbois,, BP 80, F‐13545, Aix‐en‐Provence, France</mods:affiliation>
<country xml:lang="fr">France</country>
<wicri:regionArea>CEREGE, UMR UAMIII, CNRS, CDF, IRD, Europôle Méditerranéen de l'Arbois,, BP 80, F‐13545, Aix‐en‐Provence</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Tappa, E" sort="Tappa, E" uniqKey="Tappa E" first="E." last="Tappa">E. Tappa</name>
<affiliation wicri:level="1"><mods:affiliation>Department of Geological Sciences, University of South Carolina, 701 Sumter Street, EWSC Room 617,, South Carolina, 29208, Columbia, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Geological Sciences, University of South Carolina, 701 Sumter Street, EWSC Room 617,, South Carolina, 29208, Columbia</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Thunell, R" sort="Thunell, R" uniqKey="Thunell R" first="R." last="Thunell">R. Thunell</name>
<affiliation wicri:level="1"><mods:affiliation>Department of Geological Sciences, University of South Carolina, 701 Sumter Street, EWSC Room 617,, South Carolina, 29208, Columbia, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Geological Sciences, University of South Carolina, 701 Sumter Street, EWSC Room 617,, South Carolina, 29208, Columbia</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Wilson, P A" sort="Wilson, P A" uniqKey="Wilson P" first="P. A." last="Wilson">P. A. Wilson</name>
<affiliation wicri:level="1"><mods:affiliation>National Oceanography Centre, European Way, SO14 3ZH, Southampton, UK</mods:affiliation>
<country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>National Oceanography Centre, European Way, SO14 3ZH, Southampton</wicri:regionArea>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:5A2F2A65E4761438CD02460D6A0E72947665DD01</idno>
<date when="2008" year="2008">2008</date>
<idno type="doi">10.1029/2008GC001974</idno>
<idno type="url">https://api.istex.fr/document/5A2F2A65E4761438CD02460D6A0E72947665DD01/fulltext/pdf</idno>
<idno type="wicri:Area/Istex/Corpus">001108</idno>
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<idno type="wicri:Area/Istex/Curation">001108</idno>
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<sourceDesc><biblStruct><analytic><title level="a" type="main">Interlaboratory comparison study of calibration standards for foraminiferal Mg/Ca thermometry</title>
<author><name sortKey="Greaves, M" sort="Greaves, M" uniqKey="Greaves M" first="M." last="Greaves">M. Greaves</name>
<affiliation wicri:level="1"><mods:affiliation>E-mail: mg109@esc.cam.ac.uk</mods:affiliation>
<country wicri:rule="url">Royaume-Uni</country>
</affiliation>
<affiliation wicri:level="1"><mods:affiliation>Department of Earth Sciences, University of Cambridge, Downing Street,, CB2 3EQ, Cambridge, UK</mods:affiliation>
<country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>Department of Earth Sciences, University of Cambridge, Downing Street,, CB2 3EQ, Cambridge</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><mods:affiliation>E-mail: mg109@esc.cam.ac.uk</mods:affiliation>
<country wicri:rule="url">Royaume-Uni</country>
</affiliation>
</author>
<author><name sortKey="Caillon, N" sort="Caillon, N" uniqKey="Caillon N" first="N." last="Caillon">N. Caillon</name>
<affiliation wicri:level="1"><mods:affiliation>LSCE/IPSL, UMR CNRS, CEA, UVSQ, Bâtiment 12, avenue de la Terrasse,, F‐91198, Gif sur Yvette, France</mods:affiliation>
<country xml:lang="fr">France</country>
<wicri:regionArea>LSCE/IPSL, UMR CNRS, CEA, UVSQ, Bâtiment 12, avenue de la Terrasse,, F‐91198, Gif sur Yvette</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Rebaubier, H" sort="Rebaubier, H" uniqKey="Rebaubier H" first="H." last="Rebaubier">H. Rebaubier</name>
<affiliation wicri:level="1"><mods:affiliation>LSCE/IPSL, UMR CNRS, CEA, UVSQ, Bâtiment 12, avenue de la Terrasse,, F‐91198, Gif sur Yvette, France</mods:affiliation>
<country xml:lang="fr">France</country>
<wicri:regionArea>LSCE/IPSL, UMR CNRS, CEA, UVSQ, Bâtiment 12, avenue de la Terrasse,, F‐91198, Gif sur Yvette</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Bartoli, G" sort="Bartoli, G" uniqKey="Bartoli G" first="G." last="Bartoli">G. Bartoli</name>
<affiliation wicri:level="1"><mods:affiliation>Institute für Geowissenschaften, Kiel University, Olshausenstrasse 40,, D‐24118, Kiel, Germany</mods:affiliation>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea>Institute für Geowissenschaften, Kiel University, Olshausenstrasse 40,, D‐24118, Kiel</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><mods:affiliation>Now at ETH Zentrum, Chemie Altbau, CAB E64, Universitätstrasse 6, CH‐8092 Zurich, Switzerland.</mods:affiliation>
<country xml:lang="fr">Suisse</country>
<wicri:regionArea>Now at ETH Zentrum, Chemie Altbau, CAB E64, Universitätstrasse 6, CH‐8092 Zurich</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Bohaty, S" sort="Bohaty, S" uniqKey="Bohaty S" first="S." last="Bohaty">S. Bohaty</name>
<affiliation wicri:level="1"><mods:affiliation>Department of Ocean Sciences, University of California, Santa Cruz, 95060, Santa Cruz, California, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Ocean Sciences, University of California, Santa Cruz, 95060, Santa Cruz, California</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><mods:affiliation>Now at School of Ocean and Earth Science, University of Southampton, National Oceanography Centre, European Way, Southampton SO14 3ZH, UK.</mods:affiliation>
<country xml:lang="fr" wicri:curation="lc">Royaume-Uni</country>
<wicri:regionArea>Now at School of Ocean and Earth Science, University of Southampton, National Oceanography Centre, European Way, Southampton SO14 3ZH</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Cacho, I" sort="Cacho, I" uniqKey="Cacho I" first="I." last="Cacho">I. Cacho</name>
<affiliation wicri:level="1"><mods:affiliation>GRC Geociències Marines, Department of Stratigraphy, Paleontology and Marine Geosciences, University of Barcelona, C/Martí i Franquès, s/n,, E‐08028, Barcelona, Spain</mods:affiliation>
<country xml:lang="fr">Espagne</country>
<wicri:regionArea>GRC Geociències Marines, Department of Stratigraphy, Paleontology and Marine Geosciences, University of Barcelona, C/Martí i Franquès, s/n,, E‐08028, Barcelona</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Clarke, L" sort="Clarke, L" uniqKey="Clarke L" first="L." last="Clarke">L. Clarke</name>
<affiliation wicri:level="1"><mods:affiliation>School of Ocean Sciences, College of Natural Sciences, Bangor University, Askew Street, Menai Bridge, Isle of Anglesey,, LL59 5EY, Wales, UK</mods:affiliation>
<country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>School of Ocean Sciences, College of Natural Sciences, Bangor University, Askew Street, Menai Bridge, Isle of Anglesey,, LL59 5EY, Wales</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Cooper, M" sort="Cooper, M" uniqKey="Cooper M" first="M." last="Cooper">M. Cooper</name>
<affiliation wicri:level="1"><mods:affiliation>National Oceanography Centre, European Way, SO14 3ZH, Southampton, UK</mods:affiliation>
<country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>National Oceanography Centre, European Way, SO14 3ZH, Southampton</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Daunt, C" sort="Daunt, C" uniqKey="Daunt C" first="C." last="Daunt">C. Daunt</name>
<affiliation wicri:level="1"><mods:affiliation>Department of Earth Sciences, University of Cambridge, Downing Street,, CB2 3EQ, Cambridge, UK</mods:affiliation>
<country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>Department of Earth Sciences, University of Cambridge, Downing Street,, CB2 3EQ, Cambridge</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Delaney, M" sort="Delaney, M" uniqKey="Delaney M" first="M." last="Delaney">M. Delaney</name>
<affiliation wicri:level="1"><mods:affiliation>Department of Ocean Sciences, University of California, Santa Cruz, California, 95060, Santa Cruz, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Ocean Sciences, University of California, Santa Cruz, California, 95060, Santa Cruz</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Demenocal, P" sort="Demenocal, P" uniqKey="Demenocal P" first="P." last="Demenocal">P. Demenocal</name>
<affiliation wicri:level="1"><mods:affiliation>Lamont‐Doherty Earth Observatory, Columbia University, Geoscience 211, Route 9W,, New York, 10964, Palisades, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Lamont‐Doherty Earth Observatory, Columbia University, Geoscience 211, Route 9W,, New York, 10964, Palisades</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Dutton, A" sort="Dutton, A" uniqKey="Dutton A" first="A." last="Dutton">A. Dutton</name>
<affiliation wicri:level="1"><mods:affiliation>Research School of Earth Sciences, Australian National University, 1 Mills Road,, ACT 0200, Canberra, Australia</mods:affiliation>
<country xml:lang="fr">Australie</country>
<wicri:regionArea>Research School of Earth Sciences, Australian National University, 1 Mills Road,, ACT 0200, Canberra</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Eggins, S" sort="Eggins, S" uniqKey="Eggins S" first="S." last="Eggins">S. Eggins</name>
<affiliation wicri:level="1"><mods:affiliation>Research School of Earth Sciences, Australian National University, 1 Mills Road,, ACT 0200, Canberra, Australia</mods:affiliation>
<country xml:lang="fr">Australie</country>
<wicri:regionArea>Research School of Earth Sciences, Australian National University, 1 Mills Road,, ACT 0200, Canberra</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Elderfield, H" sort="Elderfield, H" uniqKey="Elderfield H" first="H." last="Elderfield">H. Elderfield</name>
<affiliation wicri:level="1"><mods:affiliation>Department of Earth Sciences, University of Cambridge, Downing Street,, CB2 3EQ, Cambridge, UK</mods:affiliation>
<country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>Department of Earth Sciences, University of Cambridge, Downing Street,, CB2 3EQ, Cambridge</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Garbe Choenberg, D" sort="Garbe Choenberg, D" uniqKey="Garbe Choenberg D" first="D." last="Garbe-Schoenberg">D. Garbe-Schoenberg</name>
<affiliation wicri:level="1"><mods:affiliation>Institute für Geowissenschaften, Kiel University, Olshausenstrasse 40,, D‐24118, Kiel, Germany</mods:affiliation>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea>Institute für Geowissenschaften, Kiel University, Olshausenstrasse 40,, D‐24118, Kiel</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Goddard, E" sort="Goddard, E" uniqKey="Goddard E" first="E." last="Goddard">E. Goddard</name>
<affiliation wicri:level="1"><mods:affiliation>College of Marine Science, University of South Florida, Florida, 33701, St. Petersburg, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>College of Marine Science, University of South Florida, Florida, 33701, St. Petersburg</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Green, D" sort="Green, D" uniqKey="Green D" first="D." last="Green">D. Green</name>
<affiliation wicri:level="1"><mods:affiliation>National Oceanography Centre, European Way, SO14 3ZH, Southampton, UK</mods:affiliation>
<country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>National Oceanography Centre, European Way, SO14 3ZH, Southampton</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Groeneveld, J" sort="Groeneveld, J" uniqKey="Groeneveld J" first="J." last="Groeneveld">J. Groeneveld</name>
<affiliation wicri:level="1"><mods:affiliation>IFM‐GEOMAR, Wischhofstrasse 1‐3,, D‐24148, Kiel, Germany</mods:affiliation>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea>IFM‐GEOMAR, Wischhofstrasse 1‐3,, D‐24148, Kiel</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><mods:affiliation>Now at Research Center Ocean Margins, University of Bremen, D‐28359 Bremen, Germany.</mods:affiliation>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea>Now at Research Center Ocean Margins, University of Bremen, D‐28359 Bremen</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Hastings, D" sort="Hastings, D" uniqKey="Hastings D" first="D." last="Hastings">D. Hastings</name>
<affiliation wicri:level="1"><mods:affiliation>Collegium of Natural Sciences, Eckerd College, 4200 54th Avenue South,, Florida, 33713, St. Petersburg, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Collegium of Natural Sciences, Eckerd College, 4200 54th Avenue South,, Florida, 33713, St. Petersburg</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Hathorne, E" sort="Hathorne, E" uniqKey="Hathorne E" first="E." last="Hathorne">E. Hathorne</name>
<affiliation wicri:level="1"><mods:affiliation>Department of Earth Sciences, Open University, Milton Keynes, UK</mods:affiliation>
<country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>Department of Earth Sciences, Open University, Milton Keynes</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><mods:affiliation>Now at Research Center Ocean Margins, University of Bremen, D‐28359 Bremen, Germany.</mods:affiliation>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea>Now at Research Center Ocean Margins, University of Bremen, D‐28359 Bremen</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Kimoto, K" sort="Kimoto, K" uniqKey="Kimoto K" first="K." last="Kimoto">K. Kimoto</name>
<affiliation wicri:level="1"><mods:affiliation>Institute of Observational Research for Global Change, JAMSTEC, 2–15, Natsushima‐cho,, 247‐0061, Yokosuka, Japan</mods:affiliation>
<country xml:lang="fr">Japon</country>
<wicri:regionArea>Institute of Observational Research for Global Change, JAMSTEC, 2–15, Natsushima‐cho,, 247‐0061, Yokosuka</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Klinkhammer, G" sort="Klinkhammer, G" uniqKey="Klinkhammer G" first="G." last="Klinkhammer">G. Klinkhammer</name>
<affiliation wicri:level="1"><mods:affiliation>College of Oceanography, Oregon State University, Oceanography Administration Building 104,, Oregon, 97331, Corvallis, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>College of Oceanography, Oregon State University, Oceanography Administration Building 104,, Oregon, 97331, Corvallis</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Labeyrie, L" sort="Labeyrie, L" uniqKey="Labeyrie L" first="L." last="Labeyrie">L. Labeyrie</name>
<affiliation wicri:level="1"><mods:affiliation>LSCE/IPSL, UMR CNRS, CEA, UVSQ, Bâtiment 12, avenue de la Terrasse,, F‐91198, Gif sur Yvette, France</mods:affiliation>
<country xml:lang="fr">France</country>
<wicri:regionArea>LSCE/IPSL, UMR CNRS, CEA, UVSQ, Bâtiment 12, avenue de la Terrasse,, F‐91198, Gif sur Yvette</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Lea, D W" sort="Lea, D W" uniqKey="Lea D" first="D. W." last="Lea">D. W. Lea</name>
<affiliation wicri:level="1"><mods:affiliation>Department of Geological Sciences, University of California, Santa Barbara, Mail Stop 9630,, California, 93106, Santa Barbara, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Geological Sciences, University of California, Santa Barbara, Mail Stop 9630,, California, 93106, Santa Barbara</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Marchitto, T" sort="Marchitto, T" uniqKey="Marchitto T" first="T." last="Marchitto">T. Marchitto</name>
<affiliation wicri:level="1"><mods:affiliation>INSTAAR, University of Colorado, Colorado, 80309, Boulder, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>INSTAAR, University of Colorado, Colorado, 80309, Boulder</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Martinez Oti, M A" sort="Martinez Oti, M A" uniqKey="Martinez Oti M" first="M. A." last="Martínez-Botí">M. A. Martínez-Botí</name>
<affiliation wicri:level="1"><mods:affiliation>ICTA, Universitat Autònoma de Barcelona, Edifici Cn ‐ Campus UAB,, E‐08193, Bellaterra, Spain</mods:affiliation>
<country xml:lang="fr">Espagne</country>
<wicri:regionArea>ICTA, Universitat Autònoma de Barcelona, Edifici Cn ‐ Campus UAB,, E‐08193, Bellaterra</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Mortyn, P G" sort="Mortyn, P G" uniqKey="Mortyn P" first="P. G." last="Mortyn">P. G. Mortyn</name>
<affiliation wicri:level="1"><mods:affiliation>ICTA, Universitat Autònoma de Barcelona, Edifici Cn ‐ Campus UAB,, E‐08193, Bellaterra, Spain</mods:affiliation>
<country xml:lang="fr">Espagne</country>
<wicri:regionArea>ICTA, Universitat Autònoma de Barcelona, Edifici Cn ‐ Campus UAB,, E‐08193, Bellaterra</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Ni, Y" sort="Ni, Y" uniqKey="Ni Y" first="Y." last="Ni">Y. Ni</name>
<affiliation wicri:level="1"><mods:affiliation>Department of Earth Sciences, University of Bristol, Bristol, UK</mods:affiliation>
<country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>Department of Earth Sciences, University of Bristol, Bristol</wicri:regionArea>
</affiliation>
<affiliation><mods:affiliation>Now at Research Institute of Petroleum Exploration and Development, PetroChina, 20 Xueyuan Road, Haidian District, Beijing, China, 100083.</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Nuernberg, D" sort="Nuernberg, D" uniqKey="Nuernberg D" first="D." last="Nuernberg">D. Nuernberg</name>
<affiliation wicri:level="1"><mods:affiliation>IFM‐GEOMAR, Wischhofstrasse 1‐3,, D‐24148, Kiel, Germany</mods:affiliation>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea>IFM‐GEOMAR, Wischhofstrasse 1‐3,, D‐24148, Kiel</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Paradis, G" sort="Paradis, G" uniqKey="Paradis G" first="G." last="Paradis">G. Paradis</name>
<affiliation wicri:level="1"><mods:affiliation>Department of Geological Sciences, University of California, Santa Barbara, Mail Stop 9630,, California, 93106, Santa Barbara, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Geological Sciences, University of California, Santa Barbara, Mail Stop 9630,, California, 93106, Santa Barbara</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Pena, L" sort="Pena, L" uniqKey="Pena L" first="L." last="Pena">L. Pena</name>
<affiliation wicri:level="1"><mods:affiliation>GRC Geociències Marines, Department of Stratigraphy, Paleontology and Marine Geosciences, University of Barcelona, C/Martí i Franquès, s/n,, E‐08028, Barcelona, Spain</mods:affiliation>
<country xml:lang="fr">Espagne</country>
<wicri:regionArea>GRC Geociències Marines, Department of Stratigraphy, Paleontology and Marine Geosciences, University of Barcelona, C/Martí i Franquès, s/n,, E‐08028, Barcelona</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Quinn, T" sort="Quinn, T" uniqKey="Quinn T" first="T." last="Quinn">T. Quinn</name>
<affiliation wicri:level="1"><mods:affiliation>College of Marine Science, University of South Florida, Florida, 33701, St. Petersburg, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>College of Marine Science, University of South Florida, Florida, 33701, St. Petersburg</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Rosenthal, Y" sort="Rosenthal, Y" uniqKey="Rosenthal Y" first="Y." last="Rosenthal">Y. Rosenthal</name>
<affiliation wicri:level="1"><mods:affiliation>Institute of Marine and Coastal Sciences, Department of Geology, Rutgers, State University of New Jersey, 71 Dudley Road,, New Jersey, 08901, New Brunswick, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Institute of Marine and Coastal Sciences, Department of Geology, Rutgers, State University of New Jersey, 71 Dudley Road,, New Jersey, 08901, New Brunswick</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Russell, A" sort="Russell, A" uniqKey="Russell A" first="A." last="Russell">A. Russell</name>
<affiliation wicri:level="1"><mods:affiliation>Department of Geology, University of California, Davis, One Shields Avenue,, California, 95616, Davis, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Geology, University of California, Davis, One Shields Avenue,, California, 95616, Davis</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Sagawa, T" sort="Sagawa, T" uniqKey="Sagawa T" first="T." last="Sagawa">T. Sagawa</name>
<affiliation wicri:level="1"><mods:affiliation>Center for Advanced Marine Core Research, Kochi University, B200 Monobe, Nankoku,, 783–8502, Kochi, Japan</mods:affiliation>
<country xml:lang="fr">Japon</country>
<wicri:regionArea>Center for Advanced Marine Core Research, Kochi University, B200 Monobe, Nankoku,, 783–8502, Kochi</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Sosdian, S" sort="Sosdian, S" uniqKey="Sosdian S" first="S." last="Sosdian">S. Sosdian</name>
<affiliation wicri:level="1"><mods:affiliation>Institute of Marine and Coastal Sciences, Department of Geology, Rutgers, State University of New Jersey, 71 Dudley Road,, New Jersey, 08901, New Brunswick, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Institute of Marine and Coastal Sciences, Department of Geology, Rutgers, State University of New Jersey, 71 Dudley Road,, New Jersey, 08901, New Brunswick</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Stott, L" sort="Stott, L" uniqKey="Stott L" first="L." last="Stott">L. Stott</name>
<affiliation wicri:level="1"><mods:affiliation>Department of Earth Sciences, University of South California, California, 90089, Los Angeles, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Earth Sciences, University of South California, California, 90089, Los Angeles</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Tachikawa, K" sort="Tachikawa, K" uniqKey="Tachikawa K" first="K." last="Tachikawa">K. Tachikawa</name>
<affiliation wicri:level="1"><mods:affiliation>CEREGE, UMR UAMIII, CNRS, CDF, IRD, Europôle Méditerranéen de l'Arbois,, BP 80, F‐13545, Aix‐en‐Provence, France</mods:affiliation>
<country xml:lang="fr">France</country>
<wicri:regionArea>CEREGE, UMR UAMIII, CNRS, CDF, IRD, Europôle Méditerranéen de l'Arbois,, BP 80, F‐13545, Aix‐en‐Provence</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Tappa, E" sort="Tappa, E" uniqKey="Tappa E" first="E." last="Tappa">E. Tappa</name>
<affiliation wicri:level="1"><mods:affiliation>Department of Geological Sciences, University of South Carolina, 701 Sumter Street, EWSC Room 617,, South Carolina, 29208, Columbia, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Geological Sciences, University of South Carolina, 701 Sumter Street, EWSC Room 617,, South Carolina, 29208, Columbia</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Thunell, R" sort="Thunell, R" uniqKey="Thunell R" first="R." last="Thunell">R. Thunell</name>
<affiliation wicri:level="1"><mods:affiliation>Department of Geological Sciences, University of South Carolina, 701 Sumter Street, EWSC Room 617,, South Carolina, 29208, Columbia, USA</mods:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Department of Geological Sciences, University of South Carolina, 701 Sumter Street, EWSC Room 617,, South Carolina, 29208, Columbia</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Wilson, P A" sort="Wilson, P A" uniqKey="Wilson P" first="P. A." last="Wilson">P. A. Wilson</name>
<affiliation wicri:level="1"><mods:affiliation>National Oceanography Centre, European Way, SO14 3ZH, Southampton, UK</mods:affiliation>
<country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>National Oceanography Centre, European Way, SO14 3ZH, Southampton</wicri:regionArea>
</affiliation>
</author>
</analytic>
<monogr></monogr>
<series><title level="j" type="main">Geochemistry, Geophysics, Geosystems</title>
<title level="j" type="alt">GEOCHEMISTRY, GEOPHYSICS, GEOSYSTEMS</title>
<idno type="ISSN">1525-2027</idno>
<idno type="eISSN">1525-2027</idno>
<imprint><biblScope unit="vol">9</biblScope>
<biblScope unit="issue">8</biblScope>
<biblScope unit="page-count">27</biblScope>
<date type="published" when="2008-08">2008-08</date>
</imprint>
<idno type="ISSN">1525-2027</idno>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><idno type="ISSN">1525-2027</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Analytical methods</term>
<term>Anand</term>
<term>Anova</term>
<term>Auxiliary material tables</term>
<term>Available carbonate reference materials</term>
<term>Benthic</term>
<term>Calcite</term>
<term>Calibration standards</term>
<term>Carbonate</term>
<term>Centrifugation</term>
<term>Cmsi</term>
<term>Cochran</term>
<term>Cochran test</term>
<term>Complete data</term>
<term>Different laboratories</term>
<term>Dissolution</term>
<term>Dissolution protocol</term>
<term>Earth planet</term>
<term>Earth sciences</term>
<term>Ecrm</term>
<term>Elderfield</term>
<term>Element concentrations</term>
<term>Error bars</term>
<term>Foraminifera</term>
<term>Foraminiferal</term>
<term>Foraminiferal calcite</term>
<term>Foraminiferal thermometry</term>
<term>Foraminiferal thermometry figure</term>
<term>Foraminiferal thermometry table</term>
<term>Geochem</term>
<term>Geochemistry</term>
<term>Geochemistry geophysics geosystems</term>
<term>Geological sciences</term>
<term>Geophys</term>
<term>Geophysics</term>
<term>Geosyst</term>
<term>Geosystems</term>
<term>Greaves</term>
<term>Grubbs</term>
<term>Grubbs test</term>
<term>Horwitz</term>
<term>Individual measurements</term>
<term>Instrument calibrations</term>
<term>Interlaboratory</term>
<term>Interlaboratory comparison study</term>
<term>Interlaboratory study</term>
<term>Interlaboratory variability</term>
<term>International standardization organization</term>
<term>Intralaboratory</term>
<term>Laboratory precisions</term>
<term>Laboratory variance</term>
<term>Little effect</term>
<term>Noncarbonate</term>
<term>Noncentrifuged</term>
<term>Noncentrifuged determinations</term>
<term>Normal distribution</term>
<term>Ocean sciences</term>
<term>Oceanography centre</term>
<term>Open symbols</term>
<term>Other laboratories</term>
<term>Outlier</term>
<term>Paleoceanography</term>
<term>Planktonic</term>
<term>Planktonic foraminifera</term>
<term>Possible contamination</term>
<term>Preliminary homogeneity study</term>
<term>Preliminary studies</term>
<term>Reference materials</term>
<term>Repeatability</term>
<term>Reproducibility</term>
<term>Rosenthal</term>
<term>Rsdr</term>
<term>Sample sizes</term>
<term>Sample weights</term>
<term>Santa barbara</term>
<term>Santa cruz</term>
<term>Silicate</term>
<term>Silicate contamination</term>
<term>Silicate mineral phases</term>
<term>Solid standards</term>
<term>Solid symbols</term>
<term>Solid volume</term>
<term>Standard deviation</term>
<term>Standard solutions</term>
<term>Statistical analysis</term>
<term>Statistical data rejection</term>
<term>Statistical rejection</term>
<term>Thermometry</term>
<term>Trace elements</term>
<term>Variance</term>
<term>Wide range</term>
</keywords>
<keywords scheme="Teeft" xml:lang="en"><term>Analytical methods</term>
<term>Anand</term>
<term>Anova</term>
<term>Auxiliary material tables</term>
<term>Available carbonate reference materials</term>
<term>Benthic</term>
<term>Calcite</term>
<term>Calibration standards</term>
<term>Carbonate</term>
<term>Centrifugation</term>
<term>Cmsi</term>
<term>Cochran</term>
<term>Cochran test</term>
<term>Complete data</term>
<term>Different laboratories</term>
<term>Dissolution</term>
<term>Dissolution protocol</term>
<term>Earth planet</term>
<term>Earth sciences</term>
<term>Ecrm</term>
<term>Elderfield</term>
<term>Element concentrations</term>
<term>Error bars</term>
<term>Foraminifera</term>
<term>Foraminiferal</term>
<term>Foraminiferal calcite</term>
<term>Foraminiferal thermometry</term>
<term>Foraminiferal thermometry figure</term>
<term>Foraminiferal thermometry table</term>
<term>Geochem</term>
<term>Geochemistry</term>
<term>Geochemistry geophysics geosystems</term>
<term>Geological sciences</term>
<term>Geophys</term>
<term>Geophysics</term>
<term>Geosyst</term>
<term>Geosystems</term>
<term>Greaves</term>
<term>Grubbs</term>
<term>Grubbs test</term>
<term>Horwitz</term>
<term>Individual measurements</term>
<term>Instrument calibrations</term>
<term>Interlaboratory</term>
<term>Interlaboratory comparison study</term>
<term>Interlaboratory study</term>
<term>Interlaboratory variability</term>
<term>International standardization organization</term>
<term>Intralaboratory</term>
<term>Laboratory precisions</term>
<term>Laboratory variance</term>
<term>Little effect</term>
<term>Noncarbonate</term>
<term>Noncentrifuged</term>
<term>Noncentrifuged determinations</term>
<term>Normal distribution</term>
<term>Ocean sciences</term>
<term>Oceanography centre</term>
<term>Open symbols</term>
<term>Other laboratories</term>
<term>Outlier</term>
<term>Paleoceanography</term>
<term>Planktonic</term>
<term>Planktonic foraminifera</term>
<term>Possible contamination</term>
<term>Preliminary homogeneity study</term>
<term>Preliminary studies</term>
<term>Reference materials</term>
<term>Repeatability</term>
<term>Reproducibility</term>
<term>Rosenthal</term>
<term>Rsdr</term>
<term>Sample sizes</term>
<term>Sample weights</term>
<term>Santa barbara</term>
<term>Santa cruz</term>
<term>Silicate</term>
<term>Silicate contamination</term>
<term>Silicate mineral phases</term>
<term>Solid standards</term>
<term>Solid symbols</term>
<term>Solid volume</term>
<term>Standard deviation</term>
<term>Standard solutions</term>
<term>Statistical analysis</term>
<term>Statistical data rejection</term>
<term>Statistical rejection</term>
<term>Thermometry</term>
<term>Trace elements</term>
<term>Variance</term>
<term>Wide range</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Sciences de la terre</term>
<term>Géochimie</term>
<term>Géophysique</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract">An interlaboratory study of Mg/Ca and Sr/Ca ratios in three commercially available carbonate reference materials (BAM RS3, CMSI 1767, and ECRM 752‐1) was performed with the participation of 25 laboratories that determine foraminiferal Mg/Ca ratios worldwide. These reference materials containing Mg/Ca in the range of foraminiferal calcite (0.8 mmol/mol to 6 mmol/mol) were circulated with a dissolution protocol for analysis. Participants were asked to make replicate dissolutions of the powdered samples and to analyze them using the instruments and calibration standards routinely used in their laboratories. Statistical analysis was performed in accordance with the International Standardization Organization standard 5725, which is based on the analysis of variance (ANOVA) technique. Repeatability (RSDr%), an indicator of intralaboratory precision, for Mg/Ca determinations in solutions after centrifuging increased with decreasing Mg/Ca, ranging from 0.78% at Mg/Ca = 5.56 mmol/mol to 1.15% at Mg/Ca = 0.79 mmol/mol. Reproducibility (RSDR%), an indicator of the interlaboratory method precision, for Mg/Ca determinations in centrifuged solutions was noticeably worse than repeatability, ranging from 4.5% at Mg/Ca = 5.56 mmol/mol to 8.7% at Mg/Ca = 0.79 mmol/mol. Results of this study show that interlaboratory variability is dominated by inconsistencies among instrument calibrations and highlight the need to improve interlaboratory compatibility. Additionally, the study confirmed the suitability of these solid standards as reference materials for foraminiferal Mg/Ca (and Sr/Ca) determinations, provided that appropriate procedures are adopted to minimize and to monitor possible contamination from silicate mineral phases.</div>
</front>
</TEI>
</record>

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Interlaboratory comparison study of calibration standards for foraminiferal Mg/Ca thermometry

Interlaboratory comparison study of calibration standards for foraminiferal Mg/Ca thermometry

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