Reduction of a Chelating Bis(NHC) Palladium(II) Complex to [{μ‐bis(NHC)}2Pd2H]+: A Terminal Hydride in a Binuclear Palladium(I) Species Formed under Catalytically Relevant Conditions
Identifieur interne : 001047 ( Istex/Curation ); précédent : 001046; suivant : 001048Reduction of a Chelating Bis(NHC) Palladium(II) Complex to [{μ‐bis(NHC)}2Pd2H]+: A Terminal Hydride in a Binuclear Palladium(I) Species Formed under Catalytically Relevant Conditions
Auteurs : Peter Boyd [Nouvelle-Zélande] ; Alison Edwards [Australie] ; Michael Gardiner [Australie] ; Curtis Ho ; Marie-Hélène Lemée-Cailleau [France] ; David Mcguinness ; Anung Riapanitra [Indonésie] ; Jonathan Steed [Royaume-Uni] ; Damien Stringer ; Brian YatesSource :
- Angewandte Chemie [ 0044-8249 ] ; 2010-08-23.
English descriptors
- KwdEn :
- Angew, Chem, Current address, Dalton trans, Fluxional behavior, Hydride, Ligand, Mass spectrometry, Meoh, Neutron, Organometallics, Palladium, Prismatic crystals, Qmax rint prisms, Radiation crystal dimensions, Solid state, Space group, Space group aba2, Synchrotron radiation crystal dimensions, Terminal hydride, Terminal hydride ligand, Verlag gmbh, Weinheim angew.
- Teeft :
- Angew, Chem, Current address, Dalton trans, Fluxional behavior, Hydride, Ligand, Mass spectrometry, Meoh, Neutron, Organometallics, Palladium, Prismatic crystals, Qmax rint prisms, Radiation crystal dimensions, Solid state, Space group, Space group aba2, Synchrotron radiation crystal dimensions, Terminal hydride, Terminal hydride ligand, Verlag gmbh, Weinheim angew.
Abstract
Durch basenunterstützte Reduktion einer Palladium(II)‐Vorstufe wurde der erste Palladium(I)‐NHC‐Komplex (NHC=N‐heterocyclisches Carben) in hoher Ausbeute hergestellt und isoliert. Die Position des einzigartigen terminalen Hydridliganden (siehe Bild; PdI cyan, H weiß, N blau) wurde durch Neutronenbeugung am Einkristall bestimmt, und das fluktuierende Verhalten des Komplexes in Lösung wurde untersucht.
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DOI: 10.1002/ange.201003177
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Curtis Ho<affiliation><mods:affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</mods:affiliation><wicri:noCountry code="subField">(+61) 3‐6229‐2858</wicri:noCountry></affiliation><affiliation><mods:affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</mods:affiliation><wicri:noCountry code="subField">(+61) 3‐6229‐2858</wicri:noCountry></affiliation><affiliation><mods:affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</mods:affiliation><wicri:noCountry code="subField">(+61) 3‐6229‐2858</wicri:noCountry></affiliation><affiliation><mods:affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</mods:affiliation><wicri:noCountry code="subField">(+61) 3‐6229‐2858</wicri:noCountry></affiliation>Le document en format XML
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Dr. Soeparno 61</wicri:regionArea></affiliation></author><author><name sortKey="Steed, Jonathan" sort="Steed, Jonathan" uniqKey="Steed J" first="Jonathan" last="Steed">Jonathan Steed</name><affiliation wicri:level="1"><mods:affiliation>Department of Chemistry, South Road, University of Durham, Durham DH1 3LE (UK)</mods:affiliation><country xml:lang="fr">Royaume-Uni</country><wicri:regionArea>Department of Chemistry, South Road, University of Durham</wicri:regionArea></affiliation></author><author><name sortKey="Stringer, Damien" sort="Stringer, Damien" uniqKey="Stringer D" first="Damien" last="Stringer">Damien Stringer</name><affiliation><mods:affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</mods:affiliation><wicri:noCountry code="subField">(+61) 3‐6229‐2858</wicri:noCountry></affiliation></author><author><name sortKey="Yates, Brian" sort="Yates, Brian" uniqKey="Yates B" first="Brian" last="Yates">Brian Yates</name><affiliation><mods:affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</mods:affiliation><wicri:noCountry code="subField">(+61) 3‐6229‐2858</wicri:noCountry></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:579BB6EAD207C7EF9FE09573152F5A43DD83C20A</idno><date when="2010" year="2010">2010</date><idno type="doi">10.1002/ange.201003177</idno><idno type="url">https://api.istex.fr/document/579BB6EAD207C7EF9FE09573152F5A43DD83C20A/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">001047</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">001047</idno><idno type="wicri:Area/Istex/Curation">001047</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Reduction of a Chelating Bis(NHC) Palladium(II) Complex to [{μ‐bis(NHC)}<hi rend="subscript">2</hi>Pd<hi rend="subscript">2</hi>H]<hi rend="superscript">+</hi>: A Terminal Hydride in a Binuclear Palladium(I) Species Formed under Catalytically Relevant Conditions<ref type="note" target="#nss"></ref></title><author><name sortKey="Boyd, Peter" sort="Boyd, Peter" uniqKey="Boyd P" first="Peter" last="Boyd">Peter Boyd</name><affiliation><mods:affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</mods:affiliation></affiliation><affiliation wicri:level="1"><mods:affiliation>Current address: Department of Chemistry, The University of Auckland, Auckland 1142 (New Zealand)</mods:affiliation><country xml:lang="fr">Nouvelle-Zélande</country><wicri:regionArea>Current address: Department of Chemistry, The University of Auckland</wicri:regionArea></affiliation></author><author><name sortKey="Edwards, Alison" sort="Edwards, Alison" uniqKey="Edwards A" first="Alison" last="Edwards">Alison Edwards</name><affiliation wicri:level="1"><mods:affiliation>Bragg Institute, Australian Nuclear Science and Technology Organisation, PMB 1, Menai NSW 2234 (Australia)</mods:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>Bragg Institute, Australian Nuclear Science and Technology Organisation, PMB 1</wicri:regionArea></affiliation></author><author><name sortKey="Gardiner, Michael" sort="Gardiner, Michael" uniqKey="Gardiner M" first="Michael" last="Gardiner">Michael Gardiner</name><affiliation wicri:level="1"><mods:affiliation>E-mail: michael.gardiner@utas.edu.au</mods:affiliation><country wicri:rule="url">Australie</country></affiliation><affiliation><mods:affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</mods:affiliation></affiliation><affiliation wicri:level="1"><mods:affiliation>E-mail: michael.gardiner@utas.edu.au</mods:affiliation><country wicri:rule="url">Australie</country></affiliation></author><author><name sortKey="Ho, Curtis" sort="Ho, Curtis" uniqKey="Ho C" first="Curtis" last="Ho">Curtis Ho</name><affiliation><mods:affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</mods:affiliation><wicri:noCountry code="subField">(+61) 3‐6229‐2858</wicri:noCountry></affiliation></author><author><name sortKey="Lemee Ailleau, Marie Elene" sort="Lemee Ailleau, Marie Elene" uniqKey="Lemee Ailleau M" first="Marie-Hélène" last="Lemée-Cailleau">Marie-Hélène Lemée-Cailleau</name><affiliation wicri:level="1"><mods:affiliation>Institut Laue‐Langevin, B.P.156, 6 rue Jules Horowitz, 38042 Grenoble Cedex 9 (France)</mods:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Institut Laue‐Langevin, B.P.156, 6 rue Jules Horowitz</wicri:regionArea></affiliation></author><author><name sortKey="Mcguinness, David" sort="Mcguinness, David" uniqKey="Mcguinness D" first="David" last="Mcguinness">David Mcguinness</name><affiliation><mods:affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</mods:affiliation><wicri:noCountry code="subField">(+61) 3‐6229‐2858</wicri:noCountry></affiliation></author><author><name sortKey="Riapanitra, Anung" sort="Riapanitra, Anung" uniqKey="Riapanitra A" first="Anung" last="Riapanitra">Anung Riapanitra</name><affiliation><mods:affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</mods:affiliation></affiliation><affiliation wicri:level="1"><mods:affiliation>Current address: Department of Chemistry, Universitas Jenderal Soedirman, Jl. Dr. Soeparno 61, Purwokerto 53123 (Indonesia)</mods:affiliation><country xml:lang="fr">Indonésie</country><wicri:regionArea>Current address: Department of Chemistry, Universitas Jenderal Soedirman, Jl. Dr. Soeparno 61</wicri:regionArea></affiliation></author><author><name sortKey="Steed, Jonathan" sort="Steed, Jonathan" uniqKey="Steed J" first="Jonathan" last="Steed">Jonathan Steed</name><affiliation wicri:level="1"><mods:affiliation>Department of Chemistry, South Road, University of Durham, Durham DH1 3LE (UK)</mods:affiliation><country xml:lang="fr">Royaume-Uni</country><wicri:regionArea>Department of Chemistry, South Road, University of Durham</wicri:regionArea></affiliation></author><author><name sortKey="Stringer, Damien" sort="Stringer, Damien" uniqKey="Stringer D" first="Damien" last="Stringer">Damien Stringer</name><affiliation><mods:affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</mods:affiliation><wicri:noCountry code="subField">(+61) 3‐6229‐2858</wicri:noCountry></affiliation></author><author><name sortKey="Yates, Brian" sort="Yates, Brian" uniqKey="Yates B" first="Brian" last="Yates">Brian Yates</name><affiliation><mods:affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</mods:affiliation><wicri:noCountry code="subField">(+61) 3‐6229‐2858</wicri:noCountry></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">Angewandte Chemie</title><title level="j" type="alt">ANGEWANDTE CHEMIE</title><idno type="ISSN">0044-8249</idno><idno type="eISSN">1521-3757</idno><imprint><biblScope unit="vol">122</biblScope><biblScope unit="issue">36</biblScope><biblScope unit="page" from="6459">6459</biblScope><biblScope unit="page" to="6462">6462</biblScope><biblScope unit="page-count">4</biblScope><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2010-08-23">2010-08-23</date></imprint><idno type="ISSN">0044-8249</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0044-8249</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Angew</term><term>Chem</term><term>Current address</term><term>Dalton trans</term><term>Fluxional behavior</term><term>Hydride</term><term>Ligand</term><term>Mass spectrometry</term><term>Meoh</term><term>Neutron</term><term>Organometallics</term><term>Palladium</term><term>Prismatic crystals</term><term>Qmax rint prisms</term><term>Radiation crystal dimensions</term><term>Solid state</term><term>Space group</term><term>Space group aba2</term><term>Synchrotron radiation crystal dimensions</term><term>Terminal hydride</term><term>Terminal hydride ligand</term><term>Verlag gmbh</term><term>Weinheim angew</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Angew</term><term>Chem</term><term>Current address</term><term>Dalton trans</term><term>Fluxional behavior</term><term>Hydride</term><term>Ligand</term><term>Mass spectrometry</term><term>Meoh</term><term>Neutron</term><term>Organometallics</term><term>Palladium</term><term>Prismatic crystals</term><term>Qmax rint prisms</term><term>Radiation crystal dimensions</term><term>Solid state</term><term>Space group</term><term>Space group aba2</term><term>Synchrotron radiation crystal dimensions</term><term>Terminal hydride</term><term>Terminal hydride ligand</term><term>Verlag gmbh</term><term>Weinheim angew</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract">Durch basenunterstützte Reduktion einer Palladium(II)‐Vorstufe wurde der erste Palladium(I)‐NHC‐Komplex (NHC=N‐heterocyclisches Carben) in hoher Ausbeute hergestellt und isoliert. Die Position des einzigartigen terminalen Hydridliganden (siehe Bild; PdI cyan, H weiß, N blau) wurde durch Neutronenbeugung am Einkristall bestimmt, und das fluktuierende Verhalten des Komplexes in Lösung wurde untersucht.</div></front></TEI></record>Pour manipuler ce document sous Unix (Dilib)
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