Inside Cover: Hysteretic Three‐Step Spin Crossover in a Thermo‐ and Photochromic 3D Pillared Hofmann‐type Metal–Organic Framework (Angew. Chem. Int. Ed. 40/2012)
Identifieur interne : 002F44 ( Istex/Corpus ); précédent : 002F43; suivant : 002F45Inside Cover: Hysteretic Three‐Step Spin Crossover in a Thermo‐ and Photochromic 3D Pillared Hofmann‐type Metal–Organic Framework (Angew. Chem. Int. Ed. 40/2012)
Auteurs : Natasha F. Sciortino ; Katrin R. Scherl-Gruenwald ; Guillaume Chastanet ; Gregory J. Halder ; Karena W. Chapman ; Jean-François Létard ; Cameron J. KepertSource :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2012-10-01.
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Abstract
Multistable molecular materials address fundamental questions in the solid state and promise application in a range of molecular devices. In their Communication on page 10154 ff. C. J. Kepert and co‐workers present a metal–organic framework that exhibits a unique hysteretic three‐step spin‐crossover transition. The transition spans four separate lattice spin states and includes two temperature regions over which the material is formally tristable; that is, three of the four states are stable within each of these regions and may be individually accessed through thermal control. (Graphic design by Karl Mutimer.)
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DOI: 10.1002/anie.201207301
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Ed. 40/2012)</title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#aa"><personName><honorifics>Dr.</honorifics><givenNames>Natasha F.</givenNames><familyName>Sciortino</familyName></personName></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#aa"><personName><honorifics>Dr.</honorifics><givenNames>Katrin R.</givenNames><familyName>Scherl‐Gruenwald</familyName></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#ab"><personName><honorifics>Dr.</honorifics><givenNames>Guillaume</givenNames><familyName>Chastanet</familyName></personName></creator><creator xml:id="au4" creatorRole="author" affiliationRef="#ac"><personName><honorifics>Dr.</honorifics><givenNames>Gregory J.</givenNames><familyName>Halder</familyName></personName></creator><creator xml:id="au5" creatorRole="author" affiliationRef="#ac"><personName><honorifics>Dr.</honorifics><givenNames>Karena W.</givenNames><familyName>Chapman</familyName></personName></creator><creator xml:id="au6" creatorRole="author" affiliationRef="#ab"><personName><honorifics>Prof.</honorifics><givenNames>Jean‐François</givenNames><familyName>Létard</familyName></personName></creator><creator xml:id="au7" creatorRole="author" affiliationRef="#aa" corresponding="yes"><personName><honorifics>Prof.</honorifics><givenNames>Cameron J.</givenNames><familyName>Kepert</familyName></personName><contactDetails><email>c.kepert@sydney.edu.au</email></contactDetails></creator></creators><affiliationGroup><affiliation xml:id="aa" countryCode="AU" type="organization"><unparsedAffiliation>School of Chemistry, The University of Sydney, Sydney NSW 2006 (Australia)</unparsedAffiliation></affiliation><affiliation xml:id="ab" countryCode="FR" type="organization"><unparsedAffiliation>Sciences Moléculaires, ICMCB, UPR CNRS 9048, Université Bordeaux I, 87 Av. Du Doc. A. Schweitzer, 33608 Pessac (France)</unparsedAffiliation></affiliation><affiliation xml:id="ac" countryCode="US" type="organization"><unparsedAffiliation>X‐ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, IL 60439 (USA)</unparsedAffiliation></affiliation></affiliationGroup><keywordGroup xml:lang="en" type="author"><keyword xml:id="kwd1">Hofmann framework</keyword><keyword xml:id="kwd2">metal–organic frameworks</keyword><keyword xml:id="kwd3">molecular electronics</keyword><keyword xml:id="kwd4">photophysics</keyword><keyword xml:id="kwd5">spin crossover</keyword></keywordGroup><abstractGroup><abstract type="graphical" xml:lang="en"><p><b>Multistable molecular materials</b> address fundamental questions in the solid state and promise application in a range of molecular devices. In their Communication on <accessionId ref="info:doi/10.1002/anie.201204387">page 10154 ff.</accessionId> C. J. Kepert and co‐workers present a metal–organic framework that exhibits a unique hysteretic three‐step spin‐crossover transition. The transition spans four separate lattice spin states and includes two temperature regions over which the material is formally tristable; that is, three of the four states are stable within each of these regions and may be individually accessed through thermal control. (Graphic design by Karl Mutimer.)<blockFixed type="graphic"><mediaResourceGroup><mediaResource alt="image" eRights="yes" copyright="WILEY-VCH" href="urn:x-wiley:14337851:media:ANIE201207301:content"></mediaResource></mediaResourceGroup></blockFixed></p></abstract></abstractGroup></contentMeta></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Inside Cover: Hysteretic Three‐Step Spin Crossover in a Thermo‐ and Photochromic 3D Pillared Hofmann‐type Metal–Organic Framework (Angew. Chem. Int. 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Ed. 40/2012)</title></titleInfo><name type="personal"><namePart type="termsOfAddress">Dr.</namePart><namePart type="given">Natasha F.</namePart><namePart type="family">Sciortino</namePart><affiliation>School of Chemistry, The University of Sydney, Sydney NSW 2006 (Australia)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="termsOfAddress">Dr.</namePart><namePart type="given">Katrin R.</namePart><namePart type="family">Scherl‐Gruenwald</namePart><affiliation>School of Chemistry, The University of Sydney, Sydney NSW 2006 (Australia)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="termsOfAddress">Dr.</namePart><namePart type="given">Guillaume</namePart><namePart type="family">Chastanet</namePart><affiliation>Sciences Moléculaires, ICMCB, UPR CNRS 9048, Université Bordeaux I, 87 Av. Du Doc. A. Schweitzer, 33608 Pessac (France)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="termsOfAddress">Dr.</namePart><namePart type="given">Gregory J.</namePart><namePart type="family">Halder</namePart><affiliation>X‐ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, IL 60439 (USA)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="termsOfAddress">Dr.</namePart><namePart type="given">Karena W.</namePart><namePart type="family">Chapman</namePart><affiliation>X‐ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, IL 60439 (USA)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="termsOfAddress">Prof.</namePart><namePart type="given">Jean‐François</namePart><namePart type="family">Létard</namePart><affiliation>Sciences Moléculaires, ICMCB, UPR CNRS 9048, Université Bordeaux I, 87 Av. Du Doc. A. Schweitzer, 33608 Pessac (France)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="termsOfAddress">Prof.</namePart><namePart type="given">Cameron J.</namePart><namePart type="family">Kepert</namePart><affiliation>School of Chemistry, The University of Sydney, Sydney NSW 2006 (Australia)</affiliation><affiliation>E-mail: c.kepert@sydney.edu.au</affiliation><affiliation>Correspondence address: School of Chemistry, The University of Sydney, Sydney NSW 2006 (Australia)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="other" displayLabel="frontmatter" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-7474895G-0">other</genre><originInfo><publisher>WILEY‐VCH Verlag</publisher><place><placeTerm type="text">Weinheim</placeTerm></place><dateIssued encoding="w3cdtf">2012-10-01</dateIssued><copyrightDate encoding="w3cdtf">2012</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><extent unit="figures">1</extent><extent unit="tables">0</extent><extent unit="references">0</extent></physicalDescription><abstract>Multistable molecular materials address fundamental questions in the solid state and promise application in a range of molecular devices. In their Communication on page 10154 ff. C. J. Kepert and co‐workers present a metal–organic framework that exhibits a unique hysteretic three‐step spin‐crossover transition. The transition spans four separate lattice spin states and includes two temperature regions over which the material is formally tristable; that is, three of the four states are stable within each of these regions and may be individually accessed through thermal control. (Graphic design by Karl Mutimer.)</abstract><subject lang="en"><genre>keywords</genre><topic>Hofmann framework</topic><topic>metal–organic frameworks</topic><topic>molecular electronics</topic><topic>photophysics</topic><topic>spin crossover</topic></subject><relatedItem type="host"><titleInfo><title>Angewandte Chemie International Edition</title></titleInfo><titleInfo type="abbreviated"><title>Angew. Chem. Int. 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