Titelbild: Proton Cascade in a Molecular Solid: H/D Exchange on Mobile and Immobile Water (Angew. Chem. 50/2013)
Identifieur interne : 002863 ( Istex/Corpus ); précédent : 002862; suivant : 002864Titelbild: Proton Cascade in a Molecular Solid: H/D Exchange on Mobile and Immobile Water (Angew. Chem. 50/2013)
Auteurs : Silvia C. Capelli ; Larry R. Falvello ; Elena Forcén-Vázquez ; Garry J. Mcintyre ; Fernando Palacio ; Sergio Sanz ; Milagros TomásSource :
- Angewandte Chemie [ 0044-8249 ] ; 2013-12-09.
Abstract
Ein Gegenstück zum Grotthuß‐Mechanismus des Protonentransports beobachten L. R. Falvello, G. J. McIntyre, M. Tomás et al. in ihrer Zuschrift auf S. 13705 ff. in nichtporösen Einkristallen. Die Pirouette steht für die Drehung von Wassermolekülen, die einen Schritt im Mechanismus darstellt, die Grand jeté verbildlicht das Hüpfen von Protonen entlang einer Wasserkette, ein weiterer Schritt im Mechanismus. Als Hintergrund sind zwei Stränge des Polymers im Kristall gezeigt, dessen Elementarzelle der ganzen Szene als dreidimensionaler Rahmen dient.
Url:
DOI: 10.1002/ange.201309817
Links to Exploration step
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Pedro Cerbuna 12, 50009 Zaragoza (Spain) ===</mods:affiliation></affiliation></author><author><name sortKey="Palacio, Fernando" sort="Palacio, Fernando" uniqKey="Palacio F" first="Fernando" last="Palacio">Fernando Palacio</name><affiliation><mods:affiliation>Dpto. de Física de la Materia Condensada and I.C.M.A., Universidad de Zaragoza—C.S.I.C. Pedro Cerbuna 12, 50009 Zaragoza (Spain)</mods:affiliation></affiliation></author><author><name sortKey="Sanz, Sergio" sort="Sanz, Sergio" uniqKey="Sanz S" first="Sergio" last="Sanz">Sergio Sanz</name><affiliation><mods:affiliation>Dpto. de Química Inorgánica and I.C.M.A. Universidad de Zaragoza—C.S.I.C. Pedro Cerbuna 12, 50009 Zaragoza (Spain)</mods:affiliation></affiliation><affiliation><mods:affiliation>Current address: EastCHEM School of Chemistry, University of Edinburgh, West Mains Road, Edinburgh, EH9 3JJ (UK)</mods:affiliation></affiliation></author><author><name sortKey="Tomas, Milagros" sort="Tomas, Milagros" uniqKey="Tomas M" first="Milagros" last="Tomás">Milagros Tomás</name><affiliation><mods:affiliation>Dpto. de Química Inorgánica and I.S.Q.C.H. Universidad de Zaragoza—C.S.I.C. Pedro Cerbuna 12, 50009 Zaragoza (Spain) http://www.chemcrystal.org</mods:affiliation></affiliation><affiliation><mods:affiliation>E-mail: milagros@unizar.es</mods:affiliation></affiliation><affiliation><mods:affiliation>Larry R. Falvello, Dpto. de Química Inorgánica and I.C.M.A., Universidad de Zaragoza—C.S.I.C. Pedro Cerbuna 12, 50009 Zaragoza (Spain) ===Garry J. McIntyre, Australian Nuclear Science and Technology Organisation, Lucas Heights NSW 2234 (Australia) ===Milagros Tomás, Dpto. de Química Inorgánica and I.S.Q.C.H. Universidad de Zaragoza—C.S.I.C. Pedro Cerbuna 12, 50009 Zaragoza (Spain) ===</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">Angewandte Chemie</title><title level="j" type="alt">ANGEWANDTE CHEMIE</title><idno type="ISSN">0044-8249</idno><idno type="eISSN">1521-3757</idno><imprint><biblScope unit="vol">125</biblScope><biblScope unit="issue">50</biblScope><biblScope unit="page" from="13345">13345</biblScope><biblScope unit="page" to="13345">13345</biblScope><biblScope unit="page-count">1</biblScope><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2013-12-09">2013-12-09</date></imprint><idno type="ISSN">0044-8249</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0044-8249</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="de">Ein Gegenstück zum Grotthuß‐Mechanismus des Protonentransports beobachten L. R. Falvello, G. J. McIntyre, M. Tomás et al. in ihrer Zuschrift auf S. 13705 ff. in nichtporösen Einkristallen. Die Pirouette steht für die Drehung von Wassermolekülen, die einen Schritt im Mechanismus darstellt, die Grand jeté verbildlicht das Hüpfen von Protonen entlang einer Wasserkette, ein weiterer Schritt im Mechanismus. Als Hintergrund sind zwei Stränge des Polymers im Kristall gezeigt, dessen Elementarzelle der ganzen Szene als dreidimensionaler Rahmen dient.</div></front></TEI><istex><corpusName>wiley</corpusName><author><json:item><name>Dr. Silvia C. Capelli</name><affiliations><json:string>Institut Laue‐Langevin, 6 rue Jules Horowitz, 38042 Grenoble Cedex 9 (France)</json:string></affiliations></json:item><json:item><name>Prof. Larry R. Falvello</name><affiliations><json:string>Dpto. de Química Inorgánica and I.C.M.A., Universidad de Zaragoza—C.S.I.C. Pedro Cerbuna 12, 50009 Zaragoza (Spain) http://www.chemcrystal.org</json:string><json:string>E-mail: falvello@unizar.es</json:string><json:string>Larry R. Falvello, Dpto. de Química Inorgánica and I.C.M.A., Universidad de Zaragoza—C.S.I.C. Pedro Cerbuna 12, 50009 Zaragoza (Spain) ===Garry J. McIntyre, Australian Nuclear Science and Technology Organisation, Lucas Heights NSW 2234 (Australia) ===Milagros Tomás, Dpto. de Química Inorgánica and I.S.Q.C.H. Universidad de Zaragoza—C.S.I.C. Pedro Cerbuna 12, 50009 Zaragoza (Spain) ===</json:string></affiliations></json:item><json:item><name>Elena Forcén‐Vázquez</name><affiliations><json:string>Dpto. de Química Inorgánica and I.C.M.A. Universidad de Zaragoza—C.S.I.C. Pedro Cerbuna 12, 50009 Zaragoza (Spain)</json:string></affiliations></json:item><json:item><name>Prof. Garry J. McIntyre</name><affiliations><json:string>Australian Nuclear Science and Technology Organisation, Lucas Heights NSW 2234 (Australia) http://www.ansto.gov.au/ResearchHub/StaffProfiles/MCINTYRE‐GARRY</json:string><json:string>E-mail: garry.mcintyre@ansto.gov.au</json:string><json:string>Larry R. Falvello, Dpto. de Química Inorgánica and I.C.M.A., Universidad de Zaragoza—C.S.I.C. Pedro Cerbuna 12, 50009 Zaragoza (Spain) ===Garry J. McIntyre, Australian Nuclear Science and Technology Organisation, Lucas Heights NSW 2234 (Australia) ===Milagros Tomás, Dpto. de Química Inorgánica and I.S.Q.C.H. Universidad de Zaragoza—C.S.I.C. Pedro Cerbuna 12, 50009 Zaragoza (Spain) ===</json:string></affiliations></json:item><json:item><name>Prof. Fernando Palacio</name><affiliations><json:string>Dpto. de Física de la Materia Condensada and I.C.M.A., Universidad de Zaragoza—C.S.I.C. Pedro Cerbuna 12, 50009 Zaragoza (Spain)</json:string></affiliations></json:item><json:item><name>Dr. Sergio Sanz</name><affiliations><json:string>Dpto. de Química Inorgánica and I.C.M.A. Universidad de Zaragoza—C.S.I.C. Pedro Cerbuna 12, 50009 Zaragoza (Spain)</json:string><json:string>Current address: EastCHEM School of Chemistry, University of Edinburgh, West Mains Road, Edinburgh, EH9 3JJ (UK)</json:string></affiliations></json:item><json:item><name>Dr. Milagros Tomás</name><affiliations><json:string>Dpto. de Química Inorgánica and I.S.Q.C.H. Universidad de Zaragoza—C.S.I.C. Pedro Cerbuna 12, 50009 Zaragoza (Spain) http://www.chemcrystal.org</json:string><json:string>E-mail: milagros@unizar.es</json:string><json:string>Larry R. Falvello, Dpto. de Química Inorgánica and I.C.M.A., Universidad de Zaragoza—C.S.I.C. Pedro Cerbuna 12, 50009 Zaragoza (Spain) ===Garry J. 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McIntyre, Australian Nuclear Science and Technology Organisation, Lucas Heights NSW 2234 (Australia) http://www.ansto.gov.au/ResearchHub/StaffProfiles/MCINTYRE‐GARRY=== Milagros Tomás, Dpto. de Química Inorgánica and I.S.Q.C.H. Universidad de Zaragoza—C.S.I.C. Pedro Cerbuna 12, 50009 Zaragoza (Spain) http://www.chemcrystal.org===</affiliation></author><author xml:id="author-0002"><persName><forename type="first">Elena</forename><surname>Forcén‐Vázquez</surname></persName><affiliation>Dpto. de Química Inorgánica and I.C.M.A. Universidad de Zaragoza—C.S.I.C. 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McIntyre, Australian Nuclear Science and Technology Organisation, Lucas Heights NSW 2234 (Australia) <url href="http://www.ansto.gov.au/ResearchHub/StaffProfiles/MCINTYRE-GARRY">http://www.ansto.gov.au/ResearchHub/StaffProfiles/MCINTYRE‐GARRY</url>===</line><line>Milagros Tomás, Dpto. de Química Inorgánica and I.S.Q.C.H. Universidad de Zaragoza—C.S.I.C. 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