Structural Evolution of Self‐Assembling Nanohybrid Thin Films from Functionalized Urea Precursors
Identifieur interne : 001414 ( Istex/Corpus ); précédent : 001413; suivant : 001415Structural Evolution of Self‐Assembling Nanohybrid Thin Films from Functionalized Urea Precursors
Auteurs : I. Karatchevtseva ; D. Cassidy ; M. Wong Hi An ; D. Mitchell ; J. Hanna ; C. Carcel ; C. Bied ; J. Moreau ; J. BartlettSource :
- Advanced Functional Materials [ 1616-301X ] ; 2007-12-17.
English descriptors
- KwdEn :
- Acidic, Acidic conditions, Adjacent urea groups, Ageing, Ageing time, Aggregate size, Ambient temperature, Amide, Basic conditions, Bied, Bulk materials, Chem, Chiral precursor, Coating solutions, Corresponding bulk materials, Corresponding films, Corresponding increase, Corriu, Film morphology, Ftir, Ftir spectra, Full paper, Funct, Gmbh, Hollow tubes, Hybrid, Hybrid films, Hybrid materials, Hydrolytic condensation, Karatchevtseva, Kgaa, Mater, Moreau, Morphology, Nanohybrid, Noyes publications, Optical images, Oxide electronics, Precursor, Precursor molecules, Primary particles, Same time, Secondary structures, Shear stress, Significant differences, Significant extent, Sol, Specialty shapes, Strong hydrogen, Strong interactions, Structural evolution, Supramolecular species, Thin coatings, Thin films, Urea, Urea groups, Urea nitrogen, Verlag, Verlag gmbh, Vibration shifts, Weak hydrogen, Weinheim, Wong.
- Teeft :
- Acidic, Acidic conditions, Adjacent urea groups, Ageing, Ageing time, Aggregate size, Ambient temperature, Amide, Basic conditions, Bied, Bulk materials, Chem, Chiral precursor, Coating solutions, Corresponding bulk materials, Corresponding films, Corresponding increase, Corriu, Film morphology, Ftir, Ftir spectra, Full paper, Funct, Gmbh, Hollow tubes, Hybrid, Hybrid films, Hybrid materials, Hydrolytic condensation, Karatchevtseva, Kgaa, Mater, Moreau, Morphology, Nanohybrid, Noyes publications, Optical images, Oxide electronics, Precursor, Precursor molecules, Primary particles, Same time, Secondary structures, Shear stress, Significant differences, Significant extent, Sol, Specialty shapes, Strong hydrogen, Strong interactions, Structural evolution, Supramolecular species, Thin coatings, Thin films, Urea, Urea groups, Urea nitrogen, Verlag, Verlag gmbh, Vibration shifts, Weak hydrogen, Weinheim, Wong.
Abstract
Hybrid organic‐inorganic thin films exhibiting patterned structuring on the nanometer scale have been prepared through the controlled hydrolysis‐condensation of enantiomerically pure chiral urea‐based silyl compounds. The thin films are obtained by spin‐coating of sols obtained via acid‐ or base‐catalyzed hydrolytic condensation of these molecular precursors. A self‐templating process is demonstrated via atomic force and transmission electron microscopy, showing the formation of nanometer size aggregates consisting of interconnected spherulates under acidic condition and of assembled fibers under basic conditions.
Url:
DOI: 10.1002/adfm.200700299
Links to Exploration step
ISTEX:6BB5302775E3DDD1396E2D91770134F7EEE8B508Le document en format XML
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Karatchevtseva</name><affiliation><mods:affiliation>E-mail: ikm@ansto.gov.au</mods:affiliation></affiliation><affiliation><mods:affiliation>ANSTO Institute of Materials and Engineering Science, PMB 1, Menai NSW 2234 (Australia)</mods:affiliation></affiliation><affiliation><mods:affiliation>E-mail: ikm@ansto.gov.au</mods:affiliation></affiliation></author><author><name sortKey="Cassidy, D" sort="Cassidy, D" uniqKey="Cassidy D" first="D." last="Cassidy">D. Cassidy</name><affiliation><mods:affiliation>ANSTO Institute of Materials and Engineering Science, PMB 1, Menai NSW 2234 (Australia)</mods:affiliation></affiliation></author><author><name sortKey="Wong Hi An, M" sort="Wong Hi An, M" uniqKey="Wong Hi An M" first="M." last="Wong Hi An">M. Wong Hi An</name><affiliation><mods:affiliation>ICG Montpellier (UMR 5253), ENSCM CNRS UM I UM II, Laboratoire Architectures Moléculaires et Matériaux Nanostructurés, Ecole Nationale Supérieure de Chimie de Montpellier, 8, rue de l'école normale, 34296 Montpellier cedex 5 (France)</mods:affiliation></affiliation></author><author><name sortKey="Mitchell, D" sort="Mitchell, D" uniqKey="Mitchell D" first="D." last="Mitchell">D. Mitchell</name><affiliation><mods:affiliation>ANSTO Institute of Materials and Engineering Science, PMB 1, Menai NSW 2234 (Australia)</mods:affiliation></affiliation></author><author><name sortKey="Hanna, J" sort="Hanna, J" uniqKey="Hanna J" first="J." last="Hanna">J. Hanna</name><affiliation><mods:affiliation>ANSTO Institute of Materials and Engineering Science, PMB 1, Menai NSW 2234 (Australia)</mods:affiliation></affiliation></author><author><name sortKey="Carcel, C" sort="Carcel, C" uniqKey="Carcel C" first="C." last="Carcel">C. Carcel</name><affiliation><mods:affiliation>ICG Montpellier (UMR 5253), ENSCM CNRS UM I UM II, Laboratoire Architectures Moléculaires et Matériaux Nanostructurés, Ecole Nationale Supérieure de Chimie de Montpellier, 8, rue de l'école normale, 34296 Montpellier cedex 5 (France)</mods:affiliation></affiliation></author><author><name sortKey="Bied, C" sort="Bied, C" uniqKey="Bied C" first="C." last="Bied">C. Bied</name><affiliation><mods:affiliation>ICG Montpellier (UMR 5253), ENSCM CNRS UM I UM II, Laboratoire Architectures Moléculaires et Matériaux Nanostructurés, Ecole Nationale Supérieure de Chimie de Montpellier, 8, rue de l'école normale, 34296 Montpellier cedex 5 (France)</mods:affiliation></affiliation></author><author><name sortKey="Moreau, J" sort="Moreau, J" uniqKey="Moreau J" first="J." last="Moreau">J. Moreau</name><affiliation><mods:affiliation>ICG Montpellier (UMR 5253), ENSCM CNRS UM I UM II, Laboratoire Architectures Moléculaires et Matériaux Nanostructurés, Ecole Nationale Supérieure de Chimie de Montpellier, 8, rue de l'école normale, 34296 Montpellier cedex 5 (France)</mods:affiliation></affiliation></author><author><name sortKey="Bartlett, J" sort="Bartlett, J" uniqKey="Bartlett J" first="J." last="Bartlett">J. Bartlett</name><affiliation><mods:affiliation>School of Natural Sciences, University of Western Sydney, Locked Bag 1797, Penrith South DC, NSW 1797 (Australia)</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">Advanced Functional Materials</title><title level="j" type="alt">ADVANCED FUNCTIONAL MATERIALS</title><idno type="ISSN">1616-301X</idno><idno type="eISSN">1616-3028</idno><imprint><biblScope unit="vol">17</biblScope><biblScope unit="issue">18</biblScope><biblScope unit="page" from="3926">3926</biblScope><biblScope unit="page" to="3932">3932</biblScope><biblScope unit="page-count">7</biblScope><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2007-12-17">2007-12-17</date></imprint><idno type="ISSN">1616-301X</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">1616-301X</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Acidic</term><term>Acidic conditions</term><term>Adjacent urea groups</term><term>Ageing</term><term>Ageing time</term><term>Aggregate size</term><term>Ambient temperature</term><term>Amide</term><term>Basic conditions</term><term>Bied</term><term>Bulk materials</term><term>Chem</term><term>Chiral precursor</term><term>Coating solutions</term><term>Corresponding bulk materials</term><term>Corresponding films</term><term>Corresponding increase</term><term>Corriu</term><term>Film morphology</term><term>Ftir</term><term>Ftir spectra</term><term>Full paper</term><term>Funct</term><term>Gmbh</term><term>Hollow tubes</term><term>Hybrid</term><term>Hybrid films</term><term>Hybrid materials</term><term>Hydrolytic condensation</term><term>Karatchevtseva</term><term>Kgaa</term><term>Mater</term><term>Moreau</term><term>Morphology</term><term>Nanohybrid</term><term>Noyes publications</term><term>Optical images</term><term>Oxide electronics</term><term>Precursor</term><term>Precursor molecules</term><term>Primary particles</term><term>Same time</term><term>Secondary structures</term><term>Shear stress</term><term>Significant differences</term><term>Significant extent</term><term>Sol</term><term>Specialty shapes</term><term>Strong hydrogen</term><term>Strong interactions</term><term>Structural evolution</term><term>Supramolecular species</term><term>Thin coatings</term><term>Thin films</term><term>Urea</term><term>Urea groups</term><term>Urea nitrogen</term><term>Verlag</term><term>Verlag gmbh</term><term>Vibration shifts</term><term>Weak hydrogen</term><term>Weinheim</term><term>Wong</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Acidic</term><term>Acidic conditions</term><term>Adjacent urea groups</term><term>Ageing</term><term>Ageing time</term><term>Aggregate size</term><term>Ambient temperature</term><term>Amide</term><term>Basic conditions</term><term>Bied</term><term>Bulk materials</term><term>Chem</term><term>Chiral precursor</term><term>Coating solutions</term><term>Corresponding bulk materials</term><term>Corresponding films</term><term>Corresponding increase</term><term>Corriu</term><term>Film morphology</term><term>Ftir</term><term>Ftir spectra</term><term>Full paper</term><term>Funct</term><term>Gmbh</term><term>Hollow tubes</term><term>Hybrid</term><term>Hybrid films</term><term>Hybrid materials</term><term>Hydrolytic condensation</term><term>Karatchevtseva</term><term>Kgaa</term><term>Mater</term><term>Moreau</term><term>Morphology</term><term>Nanohybrid</term><term>Noyes publications</term><term>Optical images</term><term>Oxide electronics</term><term>Precursor</term><term>Precursor molecules</term><term>Primary particles</term><term>Same time</term><term>Secondary structures</term><term>Shear stress</term><term>Significant differences</term><term>Significant extent</term><term>Sol</term><term>Specialty shapes</term><term>Strong hydrogen</term><term>Strong interactions</term><term>Structural evolution</term><term>Supramolecular species</term><term>Thin coatings</term><term>Thin films</term><term>Urea</term><term>Urea groups</term><term>Urea nitrogen</term><term>Verlag</term><term>Verlag gmbh</term><term>Vibration shifts</term><term>Weak hydrogen</term><term>Weinheim</term><term>Wong</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Hybrid organic‐inorganic thin films exhibiting patterned structuring on the nanometer scale have been prepared through the controlled hydrolysis‐condensation of enantiomerically pure chiral urea‐based silyl compounds. The thin films are obtained by spin‐coating of sols obtained via acid‐ or base‐catalyzed hydrolytic condensation of these molecular precursors. A self‐templating process is demonstrated via atomic force and transmission electron microscopy, showing the formation of nanometer size aggregates consisting of interconnected spherulates under acidic condition and of assembled fibers under basic conditions.</div></front></TEI><istex><corpusName>wiley</corpusName><keywords><teeft><json:string>chem</json:string><json:string>moreau</json:string><json:string>wong</json:string><json:string>thin films</json:string><json:string>precursor</json:string><json:string>ageing</json:string><json:string>bied</json:string><json:string>nanohybrid</json:string><json:string>karatchevtseva</json:string><json:string>ageing time</json:string><json:string>weinheim</json:string><json:string>urea</json:string><json:string>corriu</json:string><json:string>ftir</json:string><json:string>verlag</json:string><json:string>gmbh</json:string><json:string>verlag gmbh</json:string><json:string>kgaa</json:string><json:string>acidic</json:string><json:string>funct</json:string><json:string>primary particles</json:string><json:string>amide</json:string><json:string>strong hydrogen</json:string><json:string>structural evolution</json:string><json:string>acidic conditions</json:string><json:string>adjacent urea groups</json:string><json:string>full paper</json:string><json:string>ftir spectra</json:string><json:string>bulk materials</json:string><json:string>mater</json:string><json:string>morphology</json:string><json:string>secondary structures</json:string><json:string>hybrid</json:string><json:string>shear stress</json:string><json:string>optical images</json:string><json:string>basic conditions</json:string><json:string>weak hydrogen</json:string><json:string>corresponding films</json:string><json:string>noyes publications</json:string><json:string>sol</json:string><json:string>corresponding increase</json:string><json:string>coating solutions</json:string><json:string>hybrid materials</json:string><json:string>supramolecular species</json:string><json:string>significant extent</json:string><json:string>vibration shifts</json:string><json:string>same time</json:string><json:string>urea nitrogen</json:string><json:string>film morphology</json:string><json:string>thin coatings</json:string><json:string>corresponding bulk materials</json:string><json:string>strong interactions</json:string><json:string>aggregate size</json:string><json:string>significant differences</json:string><json:string>ambient temperature</json:string><json:string>hollow tubes</json:string><json:string>urea groups</json:string><json:string>chiral precursor</json:string><json:string>hybrid films</json:string><json:string>oxide electronics</json:string><json:string>specialty shapes</json:string><json:string>precursor molecules</json:string><json:string>hydrolytic condensation</json:string></teeft></keywords><author><json:item><name>I. Karatchevtseva</name><affiliations><json:string>E-mail: ikm@ansto.gov.au</json:string><json:string>ANSTO Institute of Materials and Engineering Science, PMB 1, Menai NSW 2234 (Australia)</json:string><json:string>E-mail: ikm@ansto.gov.au</json:string></affiliations></json:item><json:item><name>D. J. Cassidy</name><affiliations><json:string>ANSTO Institute of Materials and Engineering Science, PMB 1, Menai NSW 2234 (Australia)</json:string></affiliations></json:item><json:item><name>M. Wong Chi Man</name><affiliations><json:string>ICG Montpellier (UMR 5253), ENSCM CNRS UM I UM II, Laboratoire Architectures Moléculaires et Matériaux Nanostructurés, Ecole Nationale Supérieure de Chimie de Montpellier, 8, rue de l'école normale, 34296 Montpellier cedex 5 (France)</json:string></affiliations></json:item><json:item><name>D. R. G. Mitchell</name><affiliations><json:string>ANSTO Institute of Materials and Engineering Science, PMB 1, Menai NSW 2234 (Australia)</json:string></affiliations></json:item><json:item><name>J. V. Hanna</name><affiliations><json:string>ANSTO Institute of Materials and Engineering Science, PMB 1, Menai NSW 2234 (Australia)</json:string></affiliations></json:item><json:item><name>C. Carcel</name><affiliations><json:string>ICG Montpellier (UMR 5253), ENSCM CNRS UM I UM II, Laboratoire Architectures Moléculaires et Matériaux Nanostructurés, Ecole Nationale Supérieure de Chimie de Montpellier, 8, rue de l'école normale, 34296 Montpellier cedex 5 (France)</json:string></affiliations></json:item><json:item><name>C. Bied</name><affiliations><json:string>ICG Montpellier (UMR 5253), ENSCM CNRS UM I UM II, Laboratoire Architectures Moléculaires et Matériaux Nanostructurés, Ecole Nationale Supérieure de Chimie de Montpellier, 8, rue de l'école normale, 34296 Montpellier cedex 5 (France)</json:string></affiliations></json:item><json:item><name>J. J. E. Moreau</name><affiliations><json:string>ICG Montpellier (UMR 5253), ENSCM CNRS UM I UM II, Laboratoire Architectures Moléculaires et Matériaux Nanostructurés, Ecole Nationale Supérieure de Chimie de Montpellier, 8, rue de l'école normale, 34296 Montpellier cedex 5 (France)</json:string></affiliations></json:item><json:item><name>J. R. Bartlett</name><affiliations><json:string>School of Natural Sciences, University of Western Sydney, Locked Bag 1797, Penrith South DC, NSW 1797 (Australia)</json:string></affiliations></json:item></author><subject><json:item><lang><json:string>eng</json:string></lang><value>Hybrid materials</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Nanostructures</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Self‐assembly</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Thin films</value></json:item></subject><articleId><json:string>ADFM200700299</json:string></articleId><arkIstex>ark:/67375/WNG-26230NQX-B</arkIstex><language><json:string>eng</json:string></language><originalGenre><json:string>article</json:string></originalGenre><abstract>Hybrid organic‐inorganic thin films exhibiting patterned structuring on the nanometer scale have been prepared through the controlled hydrolysis‐condensation of enantiomerically pure chiral urea‐based silyl compounds. The thin films are obtained by spin‐coating of sols obtained via acid‐ or base‐catalyzed hydrolytic condensation of these molecular precursors. A self‐templating process is demonstrated via atomic force and transmission electron microscopy, showing the formation of nanometer size aggregates consisting of interconnected spherulates under acidic condition and of assembled fibers under basic conditions.</abstract><qualityIndicators><score>7.924</score><pdfWordCount>4988</pdfWordCount><pdfCharCount>29765</pdfCharCount><pdfVersion>1.3</pdfVersion><pdfPageCount>7</pdfPageCount><pdfPageSize>595 x 794 pts</pdfPageSize><refBibsNative>true</refBibsNative><abstractWordCount>78</abstractWordCount><abstractCharCount>621</abstractCharCount><keywordCount>4</keywordCount></qualityIndicators><title>Structural Evolution of Self‐Assembling Nanohybrid Thin Films from Functionalized Urea Precursors</title><genre><json:string>article</json:string></genre><host><title>Advanced Functional Materials</title><language><json:string>unknown</json:string></language><doi><json:string>10.1002/(ISSN)1616-3028</json:string></doi><issn><json:string>1616-301X</json:string></issn><eissn><json:string>1616-3028</json:string></eissn><publisherId><json:string>ADFM</json:string></publisherId><volume>17</volume><issue>18</issue><pages><first>3926</first><last>3932</last><total>7</total></pages><genre><json:string>journal</json:string></genre><subject><json:item><value>Full Paper</value></json:item></subject></host><namedEntities><unitex><date><json:string>2000</json:string><json:string>3360</json:string><json:string>5000</json:string><json:string>8000</json:string><json:string>2007</json:string></date><geogName></geogName><orgName><json:string>Natural Sciences University</json:string><json:string>Headway Research Inc</json:string></orgName><orgName_funder></orgName_funder><orgName_provider></orgName_provider><persName><json:string>A. Sayari</json:string><json:string>W. Kern</json:string><json:string>Chi Man</json:string><json:string>S. T. Reed</json:string><json:string>T. Ohsuna</json:string><json:string>S. B. Ogale</json:string><json:string>P. H. Holloway</json:string><json:string>L. C.Klein</json:string><json:string>D. Grosso</json:string><json:string>T. Venkatesan</json:string><json:string>D. J. Cassidy</json:string><json:string>X. Elias</json:string><json:string>G. E. McGuire</json:string><json:string>A. Brethon</json:string><json:string>S. Shinkai</json:string><json:string>J. Mater</json:string><json:string>B. P. Pichon</json:string><json:string>Catherine Bied</json:string><json:string>J. Bartlett</json:string><json:string>Y. G.Yang</json:string><json:string>Carole Carcel</json:string><json:string>D.A. Puotinen</json:string><json:string>H. Dislich</json:string><json:string>G. A. Ozin</json:string><json:string>W. Zhou</json:string><json:string>O. W. Webster</json:string><json:string>J. Jadzyn</json:string><json:string>John Wiley</json:string><json:string>V. N. Kulkarni</json:string><json:string>J. Phys</json:string><json:string>W. Wang</json:string><json:string>K. Hanabusa</json:string><json:string>P. Gomez-Romero</json:string><json:string>J. E. Moreau</json:string><json:string>R. D. Vispute</json:string><json:string>B. Boury</json:string><json:string>C. R. Chim</json:string><json:string>L. Sauvajol</json:string><json:string>M. J. MacLachlan</json:string><json:string>K. Sada</json:string><json:string>C. S. Ashley</json:string><json:string>S. Inagaki</json:string><json:string>J. Chem</json:string><json:string>B. Smarsly</json:string><json:string>Y. G. Yang</json:string><json:string>T. Kishida</json:string><json:string>L. Bantignies</json:string><json:string>O. Conocar</json:string><json:string>I. Lu</json:string><json:string>J. V. Hanna</json:string><json:string>C. Bied</json:string><json:string>S. B.Ogale</json:string><json:string>J. Pang</json:string><json:string>P. Hesemann</json:string><json:string>G. W. Scherer</json:string><json:string>N. Liu</json:string><json:string>K. Yu</json:string><json:string>M. Kimura</json:string><json:string>B. Zywucki</json:string><json:string>Z. Liu</json:string><json:string>O. Terasaki</json:string><json:string>S. Guan</json:string><json:string>D. Maurin</json:string><json:string>D. Chen</json:string><json:string>K. Kuroda</json:string><json:string>G. J. D. A. A. Soler-Illia</json:string><json:string>S. R. Shinde</json:string><json:string>L. Vellutini</json:string><json:string>F. Schoonbeek</json:string><json:string>M. Trilla</json:string><json:string>R. J. P. Corriu</json:string><json:string>L. Yang</json:string><json:string>S. Bourg</json:string><json:string>J. van Esch</json:string><json:string>B.L. Feringa</json:string><json:string>H. Fan</json:string><json:string>M. Nakazawa</json:string><json:string>L. Rejaud</json:string><json:string>A.L. Spek</json:string><json:string>M. Wong</json:string><json:string>J. Tang</json:string><json:string>H. Shirai</json:string><json:string>B. T. Holland</json:string><json:string>P. M. Chevalier</json:string><json:string>D. R. G. Mitchell</json:string><json:string>H. Pritzkow</json:string><json:string>M. Stockhausen</json:string><json:string>A. Shimojima</json:string><json:string>L.Vellutini</json:string><json:string>R. B. Pettit</json:string><json:string>D. A. LaVan</json:string><json:string>H. Kooijman</json:string><json:string>G. Arrachart</json:string><json:string>R. Ramesh</json:string><json:string>R. G. Assink</json:string><json:string>A. Stein</json:string><json:string>T. Asefa</json:string><json:string>G. Socrates</json:string><json:string>P. Thépot</json:string><json:string>M. Suzuki</json:string><json:string>J. P. Lère-Porte</json:string><json:string>B. J. Melde</json:string><json:string>P. Dieudonné</json:string><json:string>Sol Gel</json:string><json:string>C. F. Blanford</json:string><json:string>N. M. Jokerst</json:string><json:string>P. Hermet</json:string><json:string>I. Takeuchi</json:string><json:string>H. S. Ashbaugh</json:string><json:string>C. Sanchez</json:string><json:string>N. Fujita</json:string><json:string>F. Ribot</json:string><json:string>H. A. Mayer</json:string><json:string>Y. Lu</json:string><json:string>M. de Loos</json:string><json:string>I. Karatchevtseva</json:string><json:string>N. Doke</json:string><json:string>R. G. Mitchell</json:string><json:string>C. J. Brinker</json:string><json:string>N. Coombs</json:string><json:string>S. Dhar</json:string><json:string>P. Delord</json:string><json:string>B.P. Pichon</json:string><json:string>C. Carcel</json:string><json:string>J. Organomet</json:string><json:string>O. J. Dautel</json:string><json:string>J. Amer</json:string><json:string>Z. Yang</json:string><json:string>A. Adima</json:string><json:string>H. Peng</json:string><json:string>J. R. Bartlett</json:string><json:string>R.M. Kellogg</json:string></persName><placeName><json:string>San Diego</json:string><json:string>Fukui</json:string><json:string>Montpellier</json:string><json:string>Germany</json:string><json:string>NY</json:string><json:string>Australia</json:string><json:string>Melbourne</json:string><json:string>Dover</json:string><json:string>CA</json:string><json:string>York</json:string><json:string>France</json:string><json:string>Sydney</json:string></placeName><ref_url></ref_url><ref_bibl><json:string>[12]</json:string><json:string>I. Karatchevtseva et al.</json:string><json:string>[5,6]</json:string><json:string>[10]</json:string><json:string>[31]</json:string><json:string>[25]</json:string><json:string>[2]</json:string></ref_bibl><bibl></bibl></unitex></namedEntities><ark><json:string>ark:/67375/WNG-26230NQX-B</json:string></ark><categories><inist><json:string>1 - sciences appliquees, technologies et medecines</json:string><json:string>2 - sciences exactes et technologie</json:string><json:string>3 - chimie</json:string><json:string>4 - chimie generale et chimie physique</json:string></inist></categories><publicationDate>2007</publicationDate><copyrightDate>2007</copyrightDate><doi><json:string>10.1002/adfm.200700299</json:string></doi><id>6BB5302775E3DDD1396E2D91770134F7EEE8B508</id><score>1</score><fulltext><json:item><extension>pdf</extension><original>true</original><mimetype>application/pdf</mimetype><uri>https://api.istex.fr/document/6BB5302775E3DDD1396E2D91770134F7EEE8B508/fulltext/pdf</uri></json:item><json:item><extension>zip</extension><original>false</original><mimetype>application/zip</mimetype><uri>https://api.istex.fr/document/6BB5302775E3DDD1396E2D91770134F7EEE8B508/fulltext/zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/document/6BB5302775E3DDD1396E2D91770134F7EEE8B508/fulltext/tei"><teiHeader><fileDesc><titleStmt><title level="a" type="main" xml:lang="en">Structural Evolution of Self‐Assembling Nanohybrid Thin Films from Functionalized Urea Precursors<ref type="note" target="#fn1"></ref></title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><availability><licence>Copyright © 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</licence></availability><date type="published" when="2007-12-17"></date></publicationStmt><notesStmt><note type="content-type" subtype="article" source="article" scheme="https://content-type.data.istex.fr/ark:/67375/XTP-6N5SZHKN-D">article</note><note type="publication-type" subtype="journal" scheme="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</note></notesStmt><sourceDesc><biblStruct type="article"><analytic><title level="a" type="main" xml:lang="en">Structural Evolution of Self‐Assembling Nanohybrid Thin Films from Functionalized Urea Precursors<ref type="note" target="#fn1"></ref></title><author xml:id="author-0000"><persName><forename type="first">I.</forename><surname>Karatchevtseva</surname></persName><email>ikm@ansto.gov.au</email><affiliation>ANSTO Institute of Materials and Engineering Science, PMB 1, Menai NSW 2234 (Australia)<address><country key="AU"></country></address></affiliation></author><author xml:id="author-0001"><persName><forename type="first">D. 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J. E.</forename><surname>Moreau</surname></persName><affiliation>ICG Montpellier (UMR 5253), ENSCM CNRS UM I UM II, Laboratoire Architectures Moléculaires et Matériaux Nanostructurés, Ecole Nationale Supérieure de Chimie de Montpellier, 8, rue de l'école normale, 34296 Montpellier cedex 5 (France)<address><country key="FR"></country></address></affiliation></author><author xml:id="author-0008"><persName><forename type="first">J. 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The thin films are obtained by spin‐coating of sols obtained via acid‐ or base‐catalyzed hydrolytic condensation of these molecular precursors. A self‐templating process is demonstrated via atomic force and transmission electron microscopy, showing the formation of nanometer size aggregates consisting of interconnected spherulates under acidic condition and of assembled fibers under basic conditions.</p></abstract><abstract xml:lang="en" style="graphical"><p><hi rend="bold">Hybrid organic‐inorganic thin films</hi> exhibiting patterned structuring on the nanometer scale have been prepared via the sol‐gel process assisted by spin coating. 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KGaA, Weinheim</copyright><eventGroup><event type="manuscriptReceived" date="2007-03-13"></event><event type="manuscriptRevised" date="2007-07-18"></event><event type="publishedOnlineEarlyUnpaginated" date="2007-11-28"></event><event type="firstOnline" date="2007-11-28"></event><event type="publishedOnlineFinalForm" date="2007-12-06"></event><event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:2.3.2 mode:FullText source:HeaderRef result:HeaderRef" date="2010-03-16"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.8.8" date="2013-12-31"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-10-14"></event></eventGroup><numberingGroup><numbering type="pageFirst">3926</numbering><numbering type="pageLast">3932</numbering></numberingGroup><linkGroup><link type="toTypesetVersion" href="file:ADFM.ADFM200700299.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="8"></count><count type="tableTotal" number="0"></count><count type="referenceTotal" number="31"></count></countGroup><titleGroup><title type="main" xml:lang="en">Structural Evolution of Self‐Assembling Nanohybrid Thin Films from Functionalized Urea Precursors<link href="#fn1"></link></title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#a1"><personName><givenNames>I.</givenNames><familyName>Karatchevtseva</familyName></personName><contactDetails><email>ikm@ansto.gov.au</email></contactDetails></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#a1"><personName><givenNames>D. J.</givenNames><familyName>Cassidy</familyName></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#a2"><personName><givenNames>M.</givenNames><familyName>Wong Chi Man</familyName></personName></creator><creator xml:id="au4" creatorRole="author" affiliationRef="#a1"><personName><givenNames>D. R. G.</givenNames><familyName>Mitchell</familyName></personName></creator><creator xml:id="au5" creatorRole="author" affiliationRef="#a1"><personName><givenNames>J. V.</givenNames><familyName>Hanna</familyName></personName></creator><creator xml:id="au6" creatorRole="author" affiliationRef="#a2"><personName><givenNames>C.</givenNames><familyName>Carcel</familyName></personName></creator><creator xml:id="au7" creatorRole="author" affiliationRef="#a2"><personName><givenNames>C.</givenNames><familyName>Bied</familyName></personName></creator><creator xml:id="au8" creatorRole="author" affiliationRef="#a2"><personName><givenNames>J. J. E.</givenNames><familyName>Moreau</familyName></personName></creator><creator xml:id="au9" creatorRole="author" affiliationRef="#a3"><personName><givenNames>J. R.</givenNames><familyName>Bartlett</familyName></personName></creator></creators><affiliationGroup><affiliation xml:id="a1" countryCode="AU" type="organization"><unparsedAffiliation>ANSTO Institute of Materials and Engineering Science, PMB 1, Menai NSW 2234 (Australia)</unparsedAffiliation></affiliation><affiliation xml:id="a2" countryCode="FR" type="organization"><unparsedAffiliation>ICG Montpellier (UMR 5253), ENSCM CNRS UM I UM II, Laboratoire Architectures Moléculaires et Matériaux Nanostructurés, Ecole Nationale Supérieure de Chimie de Montpellier, 8, rue de l'école normale, 34296 Montpellier cedex 5 (France)</unparsedAffiliation></affiliation><affiliation xml:id="a3" countryCode="AU" type="organization"><unparsedAffiliation>School of Natural Sciences, University of Western Sydney, Locked Bag 1797, Penrith South DC, NSW 1797 (Australia)</unparsedAffiliation></affiliation></affiliationGroup><keywordGroup xml:lang="en" type="author"><keyword xml:id="kwd1">Hybrid materials</keyword><keyword xml:id="kwd2">Nanostructures</keyword><keyword xml:id="kwd3">Self‐assembly</keyword><keyword xml:id="kwd4">Thin films</keyword></keywordGroup><fundingInfo><fundingAgency>Ministère de la recherche de France</fundingAgency></fundingInfo><fundingInfo><fundingAgency>CNRS</fundingAgency></fundingInfo><supportingInformation><p>Supporting information for this article is available on the WWW under <url href="http://www.wiley-vch.de/contents/jc_2126/2007/fp0299_s.pdf">http://www.wiley‐vch.de/contents/jc_2126/2007/fp0299_s.pdf</url> or from the author.</p></supportingInformation><abstractGroup><abstract type="main" xml:lang="en"><title type="main">Abstract</title><p>Hybrid organic‐inorganic thin films exhibiting patterned structuring on the nanometer scale have been prepared through the controlled hydrolysis‐condensation of enantiomerically pure chiral urea‐based silyl compounds. The thin films are obtained by spin‐coating of sols obtained via acid‐ or base‐catalyzed hydrolytic condensation of these molecular precursors. A self‐templating process is demonstrated via atomic force and transmission electron microscopy, showing the formation of nanometer size aggregates consisting of interconnected spherulates under acidic condition and of assembled fibers under basic conditions.</p></abstract><abstract type="graphical" xml:lang="en"><p><b>Hybrid organic‐inorganic thin films</b> exhibiting patterned structuring on the nanometer scale have been prepared via the sol‐gel process assisted by spin coating. A self‐templating process is demonstrated via atomic force and transmission electron microscopy showing the formation of nanometer size aggregates consisting of interconnected spherulates under acidic conditions and of assembled fibers under basic conditions. <blockFixed type="graphic"><mediaResourceGroup><mediaResource alt="image" eRights="yes" copyright="WILEY-VCH" href="urn:x-wiley:1616301X:media:ADFM200700299:content"></mediaResource><mediaResource alt="thumbnail image" rendition="webLoRes" mimeType="image/gif" href=""></mediaResource><mediaResource alt="original image" rendition="webOriginal" mimeType="image/gif" href=""></mediaResource><mediaResource alt="magnified image" rendition="webHiRes" mimeType="image/gif" href=""></mediaResource></mediaResourceGroup></blockFixed></p></abstract></abstractGroup></contentMeta><noteGroup><note xml:id="fn1"><p>Financial supports from the “Ministère de la recherche de France” through the “ACI Nanosciences‐Nanotechnologies programs” and CNRS are acknowledged. Supporting Information is available online through Wiley InterScience or from the authors.</p></note></noteGroup></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Structural Evolution of Self‐Assembling Nanohybrid Thin Films from Functionalized Urea Precursors</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Structural Evolution of Self‐Assembling Nanohybrid Thin Films from Functionalized Urea Precursors</title></titleInfo><name type="personal"><namePart type="given">I.</namePart><namePart type="family">Karatchevtseva</namePart><affiliation>E-mail: ikm@ansto.gov.au</affiliation><affiliation>ANSTO Institute of Materials and Engineering Science, PMB 1, Menai NSW 2234 (Australia)</affiliation><affiliation>E-mail: ikm@ansto.gov.au</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">D. 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V.</namePart><namePart type="family">Hanna</namePart><affiliation>ANSTO Institute of Materials and Engineering Science, PMB 1, Menai NSW 2234 (Australia)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">C.</namePart><namePart type="family">Carcel</namePart><affiliation>ICG Montpellier (UMR 5253), ENSCM CNRS UM I UM II, Laboratoire Architectures Moléculaires et Matériaux Nanostructurés, Ecole Nationale Supérieure de Chimie de Montpellier, 8, rue de l'école normale, 34296 Montpellier cedex 5 (France)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">C.</namePart><namePart type="family">Bied</namePart><affiliation>ICG Montpellier (UMR 5253), ENSCM CNRS UM I UM II, Laboratoire Architectures Moléculaires et Matériaux Nanostructurés, Ecole Nationale Supérieure de Chimie de Montpellier, 8, rue de l'école normale, 34296 Montpellier cedex 5 (France)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">J. J. E.</namePart><namePart type="family">Moreau</namePart><affiliation>ICG Montpellier (UMR 5253), ENSCM CNRS UM I UM II, Laboratoire Architectures Moléculaires et Matériaux Nanostructurés, Ecole Nationale Supérieure de Chimie de Montpellier, 8, rue de l'école normale, 34296 Montpellier cedex 5 (France)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">J. R.</namePart><namePart type="family">Bartlett</namePart><affiliation>School of Natural Sciences, University of Western Sydney, Locked Bag 1797, Penrith South DC, NSW 1797 (Australia)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="article" displayLabel="article" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-6N5SZHKN-D">article</genre><originInfo><publisher>WILEY‐VCH Verlag</publisher><place><placeTerm type="text">Weinheim</placeTerm></place><dateIssued encoding="w3cdtf">2007-12-17</dateIssued><dateCaptured encoding="w3cdtf">2007-03-13</dateCaptured><copyrightDate encoding="w3cdtf">2007</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><extent unit="figures">8</extent><extent unit="tables">0</extent><extent unit="references">31</extent></physicalDescription><abstract lang="en">Hybrid organic‐inorganic thin films exhibiting patterned structuring on the nanometer scale have been prepared through the controlled hydrolysis‐condensation of enantiomerically pure chiral urea‐based silyl compounds. The thin films are obtained by spin‐coating of sols obtained via acid‐ or base‐catalyzed hydrolytic condensation of these molecular precursors. A self‐templating process is demonstrated via atomic force and transmission electron microscopy, showing the formation of nanometer size aggregates consisting of interconnected spherulates under acidic condition and of assembled fibers under basic conditions.</abstract><abstract>Hybrid organic‐inorganic thin films exhibiting patterned structuring on the nanometer scale have been prepared via the sol‐gel process assisted by spin coating. A self‐templating process is demonstrated via atomic force and transmission electron microscopy showing the formation of nanometer size aggregates consisting of interconnected spherulates under acidic conditions and of assembled fibers under basic conditions.</abstract><note type="content">*Financial supports from the “Ministère de la recherche de France” through the “ACI Nanosciences‐Nanotechnologies programs” and CNRS are acknowledged. Supporting Information is available online through Wiley InterScience or from the authors.</note><note type="funding">Ministère de la recherche de France</note><note type="funding">CNRS</note><subject lang="en"><genre>keywords</genre><topic>Hybrid materials</topic><topic>Nanostructures</topic><topic>Self‐assembly</topic><topic>Thin films</topic></subject><relatedItem type="host"><titleInfo><title>Advanced Functional Materials</title></titleInfo><titleInfo type="abbreviated"><title>Adv. Funct. Mater.</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><note type="content"> Supporting information for this article is available on the WWW under http://www.wiley‐vch.de/contents/jc_2126/2007/fp0299_s.pdf or from the author.</note><subject><genre>article-category</genre><topic>Full Paper</topic></subject><identifier type="ISSN">1616-301X</identifier><identifier type="eISSN">1616-3028</identifier><identifier type="DOI">10.1002/(ISSN)1616-3028</identifier><identifier type="PublisherID">ADFM</identifier><part><date>2007</date><detail type="volume"><caption>vol.</caption><number>17</number></detail><detail type="issue"><caption>no.</caption><number>18</number></detail><extent unit="pages"><start>3926</start><end>3932</end><total>7</total></extent></part></relatedItem><relatedItem type="preceding"><titleInfo><title>Advanced Materials for Optics and Electronics</title></titleInfo><identifier type="ISSN">1057-9257</identifier><part><date point="end">2000</date><detail type="volume"><caption>last vol.</caption><number>10</number></detail><detail type="issue"><caption>last no.</caption><number>6</number></detail></part></relatedItem><identifier type="istex">6BB5302775E3DDD1396E2D91770134F7EEE8B508</identifier><identifier type="ark">ark:/67375/WNG-26230NQX-B</identifier><identifier type="DOI">10.1002/adfm.200700299</identifier><identifier type="ArticleID">ADFM200700299</identifier><accessCondition type="use and reproduction" contentType="copyright">Copyright © 2007 WILEY‐VCH Verlag GmbH & Co. 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