Structural Systematics for Lanthanide(III) Systems: Lattice Interactions in Salts [CoL3][Ln(dipic)3]·nH2O (L = N,N′‐Aromatic Bidentate Ligand; dipic = Dipicolinate = pyridine‐2,6‐dicarboxylate) Containing Complex Ions of D3 Symmetry
Identifieur interne : 000A87 ( Istex/Checkpoint ); précédent : 000A86; suivant : 000A88Structural Systematics for Lanthanide(III) Systems: Lattice Interactions in Salts [CoL3][Ln(dipic)3]·nH2O (L = N,N′‐Aromatic Bidentate Ligand; dipic = Dipicolinate = pyridine‐2,6‐dicarboxylate) Containing Complex Ions of D3 Symmetry
Auteurs : Jack M. Harrowfield [Australie, France] ; George A. Koutsantonis [Australie] ; Brian W. Skelton [Australie] ; Adam J. Strong [Australie] ; Allan H. White [Australie]Source :
- ZAAC ‐ Journal of Inorganic and General Chemistry [ 0044-2313 ] ; 2010-04.
Descripteurs français
- Wicri :
- topic : Cobalt, Collecte de données.
English descriptors
- KwdEn :
- Acta chem, Acta crystallogr, Allg, Anion, Anion columns, Anion contacts, Anorg, Aqueous layer, Aromatic rings, Asymmetric unit, Carboxylate, Cation, Cation columns, Cation pairs, Chem, Chirality, Cobalt, Cobalt cations, Complex cations, Complex ions, Coordination sphere interpenetration, Crystal data, Crystallographic symmetry, Dalton trans, Data centre, Data collection, Derivative, Dipic dipicolinate, Dipicolinate, Dipicolinate ligands, Direct contacts, Direct interactions, Double layer, Double layers, Europium, Europium analogue, Formula unit, Gmbh, Harrowfield, Heteroaromatic, Heteroaromatic ligand, Heteroaromatic ligands, Heterochiral, Heterochiral contacts, Heterochiral pair interactions, Heterochiral pairs, Heterogeneous sheets, Hexagonal array, Homochiral, Homochiral columns, Hydrogen atoms, Inorg, Interatomic, Interatomic contacts, Intermolecular forces, Kgaa, Lanthanide, Lanthanide anions, Lanthanide contraction, Lanthanum, Lattice, Lattice components, Lattice interactions, Lattice residues, Lattice structure, Ligand, Ligand atoms, Metal atoms, Molecule, Obvious differences, Opposite chirality, Outer atoms, Pair type, Pair type heterochiral heterochiral homochiral homochiral heterochiral, Phen, Racemic compounds, Racemic mixtures, Ring planes, Same chirality, Site occupancies, Specific interactions, Structural systematics, Structure determinations, Structure refinement, Trial refinement, Unit cell contents, Various contacts, Verlag, Verlag gmbh, Water molecule, Water molecule oxygen atoms, Water molecules, Weinheim.
- Teeft :
- Acta chem, Acta crystallogr, Allg, Anion, Anion columns, Anion contacts, Anorg, Aqueous layer, Aromatic rings, Asymmetric unit, Carboxylate, Cation, Cation columns, Cation pairs, Chem, Chirality, Cobalt, Cobalt cations, Complex cations, Complex ions, Coordination sphere interpenetration, Crystal data, Crystallographic symmetry, Dalton trans, Data centre, Data collection, Derivative, Dipic dipicolinate, Dipicolinate, Dipicolinate ligands, Direct contacts, Direct interactions, Double layer, Double layers, Europium, Europium analogue, Formula unit, Gmbh, Harrowfield, Heteroaromatic, Heteroaromatic ligand, Heteroaromatic ligands, Heterochiral, Heterochiral contacts, Heterochiral pair interactions, Heterochiral pairs, Heterogeneous sheets, Hexagonal array, Homochiral, Homochiral columns, Hydrogen atoms, Inorg, Interatomic, Interatomic contacts, Intermolecular forces, Kgaa, Lanthanide, Lanthanide anions, Lanthanide contraction, Lanthanum, Lattice, Lattice components, Lattice interactions, Lattice residues, Lattice structure, Ligand, Ligand atoms, Metal atoms, Molecule, Obvious differences, Opposite chirality, Outer atoms, Pair type, Pair type heterochiral heterochiral homochiral homochiral heterochiral, Phen, Racemic compounds, Racemic mixtures, Ring planes, Same chirality, Site occupancies, Specific interactions, Structural systematics, Structure determinations, Structure refinement, Trial refinement, Unit cell contents, Various contacts, Verlag, Verlag gmbh, Water molecule, Water molecule oxygen atoms, Water molecules, Weinheim.
Abstract
Structural characterisation of a number of hydrated solids containing chiral, kinetically inert [Co(A–A)3]3+ cations (A–A = 2,2′‐bipyridine, 1,10‐phenanthroline, 4,4′‐dimethyl‐2,2′‐bipyridine) and chiral, kinetically labile [Ln(dipic)3]3– anions (Ln = La, Eu, Tb, Ho, Er, Lu, Y, though not for all cobalt cations; dipic = dipicolinate = pyridine‐2,6‐dicarboxylate) show a remarkable range of associations between the lattice components, though all are racemic arrays. Analysis of the structures in terms of short interatomic contacts between the components shows that, whereas numerous contacts of the heteroaromatic ligands do occur, very few define an arrangement which could be truly termed “π‐stacking” where the rings are closely parallel and atom overlaps in projection are substantial. Water is important in the highly hydrated lattice structures, not only because of hydrogen‐bonding interactions with itself and carboxylate‐O atoms but also because of its interactions with the aromatic units. The family [Co(bipy)3][Ln(dipic)3]·~13H2O are essentially isomorphous for the full range of Ln plus Y (triclinic, P\bar{1}, a = 12.3, b = 14.3, c = 16.5 Å, α = 94, β = 94, γ = 108 ˚, Z = 2). Among the heavier lanthanides, the potential symmetry of the anion/cation combination is realised in the trigonal space group P\bar{3}, both species lying together as an ion‐pair, disposed on the trigonal axis for [Co(phen)3][Ln(dipic)3]·22H2O (Ln = Eu, Er; a = 15.2, c = 16.8 Å, Z = 2).
Url:
DOI: 10.1002/zaac.200900409
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<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Structural Systematics for Lanthanide(III) Systems: Lattice Interactions in Salts [CoL3][Ln(dipic)3]·nH2O (L = N,N′‐Aromatic Bidentate Ligand; dipic = Dipicolinate = pyridine‐2,6‐dicarboxylate) Containing Complex Ions of D3 Symmetry</title><author><name sortKey="Harrowfield, Jack M" sort="Harrowfield, Jack M" uniqKey="Harrowfield J" first="Jack M." last="Harrowfield">Jack M. Harrowfield</name></author><author><name sortKey="Koutsantonis, George A" sort="Koutsantonis, George A" uniqKey="Koutsantonis G" first="George A." last="Koutsantonis">George A. Koutsantonis</name></author><author><name sortKey="Skelton, Brian W" sort="Skelton, Brian W" uniqKey="Skelton B" first="Brian W." last="Skelton">Brian W. Skelton</name></author><author><name sortKey="Strong, Adam J" sort="Strong, Adam J" uniqKey="Strong A" first="Adam J." last="Strong">Adam J. Strong</name></author><author><name sortKey="White, Allan H" sort="White, Allan H" uniqKey="White A" first="Allan H." last="White">Allan H. White</name></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:DB897DFD18DE20B1627006DA01798EDFF024A71A</idno><date when="2010" year="2010">2010</date><idno type="doi">10.1002/zaac.200900409</idno><idno type="url">https://api.istex.fr/document/DB897DFD18DE20B1627006DA01798EDFF024A71A/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">002892</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">002892</idno><idno type="wicri:Area/Istex/Curation">002892</idno><idno type="wicri:Area/Istex/Checkpoint">000A87</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000A87</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Structural Systematics for Lanthanide(III) Systems: Lattice Interactions in Salts [CoL<hi rend="subscript">3</hi>][Ln(dipic)<hi rend="subscript">3</hi>]·<hi rend="italic">n</hi>H<hi rend="subscript">2</hi>O (L = <hi rend="italic">N</hi>,<hi rend="italic">N</hi>′‐Aromatic Bidentate Ligand; dipic = Dipicolinate = pyridine‐2,6‐dicarboxylate) Containing Complex Ions of <hi rend="italic">D</hi><hi rend="subscript">3</hi> Symmetry</title><author><name sortKey="Harrowfield, Jack M" sort="Harrowfield, Jack M" uniqKey="Harrowfield J" first="Jack M." last="Harrowfield">Jack M. Harrowfield</name><affiliation wicri:level="1"><country xml:lang="fr">Australie</country><wicri:regionArea>School of Biomedical, Biomolecular and Chemical Sciences, Chemistry M313, The University of Western Australia, Crawley/Western Australia 6009</wicri:regionArea><wicri:noRegion>Crawley/Western Australia 6009</wicri:noRegion></affiliation><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire de Chimie Supramoléculaire, Institut de Science et d′Ingénierie Supramoléculaires, 67083 Strasbourg</wicri:regionArea><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Alsace (région administrative)</region><settlement type="city">Strasbourg</settlement></placeName></affiliation><affiliation wicri:level="1"><country wicri:rule="url">France</country></affiliation><affiliation></affiliation></author><author><name sortKey="Koutsantonis, George A" sort="Koutsantonis, George A" uniqKey="Koutsantonis G" first="George A." last="Koutsantonis">George A. Koutsantonis</name><affiliation wicri:level="1"><country xml:lang="fr">Australie</country><wicri:regionArea>School of Biomedical, Biomolecular and Chemical Sciences, Chemistry M313, The University of Western Australia, Crawley/Western Australia 6009</wicri:regionArea><wicri:noRegion>Crawley/Western Australia 6009</wicri:noRegion></affiliation></author><author><name sortKey="Skelton, Brian W" sort="Skelton, Brian W" uniqKey="Skelton B" first="Brian W." last="Skelton">Brian W. Skelton</name><affiliation wicri:level="1"><country xml:lang="fr">Australie</country><wicri:regionArea>School of Biomedical, Biomolecular and Chemical Sciences, Chemistry M313, The University of Western Australia, Crawley/Western Australia 6009</wicri:regionArea><wicri:noRegion>Crawley/Western Australia 6009</wicri:noRegion></affiliation></author><author><name sortKey="Strong, Adam J" sort="Strong, Adam J" uniqKey="Strong A" first="Adam J." last="Strong">Adam J. Strong</name><affiliation wicri:level="1"><country xml:lang="fr">Australie</country><wicri:regionArea>School of Biomedical, Biomolecular and Chemical Sciences, Chemistry M313, The University of Western Australia, Crawley/Western Australia 6009</wicri:regionArea><wicri:noRegion>Crawley/Western Australia 6009</wicri:noRegion></affiliation></author><author><name sortKey="White, Allan H" sort="White, Allan H" uniqKey="White A" first="Allan H." last="White">Allan H. White</name><affiliation wicri:level="1"><country xml:lang="fr">Australie</country><wicri:regionArea>School of Biomedical, Biomolecular and Chemical Sciences, Chemistry M313, The University of Western Australia, Crawley/Western Australia 6009</wicri:regionArea><wicri:noRegion>Crawley/Western Australia 6009</wicri:noRegion></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">ZAAC ‐ Journal of Inorganic and General Chemistry</title><idno type="ISSN">0044-2313</idno><idno type="eISSN">1521-3749</idno><imprint><biblScope unit="vol">636</biblScope><biblScope unit="issue">5</biblScope><biblScope unit="page" from="808">808</biblScope><biblScope unit="page" to="817">817</biblScope><biblScope unit="page-count">10</biblScope><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2010-04">2010-04</date></imprint><idno type="ISSN">0044-2313</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0044-2313</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Acta chem</term><term>Acta crystallogr</term><term>Allg</term><term>Anion</term><term>Anion columns</term><term>Anion contacts</term><term>Anorg</term><term>Aqueous layer</term><term>Aromatic rings</term><term>Asymmetric unit</term><term>Carboxylate</term><term>Cation</term><term>Cation columns</term><term>Cation pairs</term><term>Chem</term><term>Chirality</term><term>Cobalt</term><term>Cobalt cations</term><term>Complex cations</term><term>Complex ions</term><term>Coordination sphere interpenetration</term><term>Crystal data</term><term>Crystallographic symmetry</term><term>Dalton trans</term><term>Data centre</term><term>Data collection</term><term>Derivative</term><term>Dipic dipicolinate</term><term>Dipicolinate</term><term>Dipicolinate ligands</term><term>Direct contacts</term><term>Direct interactions</term><term>Double layer</term><term>Double layers</term><term>Europium</term><term>Europium analogue</term><term>Formula unit</term><term>Gmbh</term><term>Harrowfield</term><term>Heteroaromatic</term><term>Heteroaromatic ligand</term><term>Heteroaromatic ligands</term><term>Heterochiral</term><term>Heterochiral contacts</term><term>Heterochiral pair interactions</term><term>Heterochiral pairs</term><term>Heterogeneous sheets</term><term>Hexagonal array</term><term>Homochiral</term><term>Homochiral columns</term><term>Hydrogen atoms</term><term>Inorg</term><term>Interatomic</term><term>Interatomic contacts</term><term>Intermolecular forces</term><term>Kgaa</term><term>Lanthanide</term><term>Lanthanide anions</term><term>Lanthanide contraction</term><term>Lanthanum</term><term>Lattice</term><term>Lattice components</term><term>Lattice interactions</term><term>Lattice residues</term><term>Lattice structure</term><term>Ligand</term><term>Ligand atoms</term><term>Metal atoms</term><term>Molecule</term><term>Obvious differences</term><term>Opposite chirality</term><term>Outer atoms</term><term>Pair type</term><term>Pair type heterochiral heterochiral homochiral homochiral heterochiral</term><term>Phen</term><term>Racemic compounds</term><term>Racemic mixtures</term><term>Ring planes</term><term>Same chirality</term><term>Site occupancies</term><term>Specific interactions</term><term>Structural systematics</term><term>Structure determinations</term><term>Structure refinement</term><term>Trial refinement</term><term>Unit cell contents</term><term>Various contacts</term><term>Verlag</term><term>Verlag gmbh</term><term>Water molecule</term><term>Water molecule oxygen atoms</term><term>Water molecules</term><term>Weinheim</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Acta chem</term><term>Acta crystallogr</term><term>Allg</term><term>Anion</term><term>Anion columns</term><term>Anion contacts</term><term>Anorg</term><term>Aqueous layer</term><term>Aromatic rings</term><term>Asymmetric unit</term><term>Carboxylate</term><term>Cation</term><term>Cation columns</term><term>Cation pairs</term><term>Chem</term><term>Chirality</term><term>Cobalt</term><term>Cobalt cations</term><term>Complex cations</term><term>Complex ions</term><term>Coordination sphere interpenetration</term><term>Crystal data</term><term>Crystallographic symmetry</term><term>Dalton trans</term><term>Data centre</term><term>Data collection</term><term>Derivative</term><term>Dipic dipicolinate</term><term>Dipicolinate</term><term>Dipicolinate ligands</term><term>Direct contacts</term><term>Direct interactions</term><term>Double layer</term><term>Double layers</term><term>Europium</term><term>Europium analogue</term><term>Formula unit</term><term>Gmbh</term><term>Harrowfield</term><term>Heteroaromatic</term><term>Heteroaromatic ligand</term><term>Heteroaromatic ligands</term><term>Heterochiral</term><term>Heterochiral contacts</term><term>Heterochiral pair interactions</term><term>Heterochiral pairs</term><term>Heterogeneous sheets</term><term>Hexagonal array</term><term>Homochiral</term><term>Homochiral columns</term><term>Hydrogen atoms</term><term>Inorg</term><term>Interatomic</term><term>Interatomic contacts</term><term>Intermolecular forces</term><term>Kgaa</term><term>Lanthanide</term><term>Lanthanide anions</term><term>Lanthanide contraction</term><term>Lanthanum</term><term>Lattice</term><term>Lattice components</term><term>Lattice interactions</term><term>Lattice residues</term><term>Lattice structure</term><term>Ligand</term><term>Ligand atoms</term><term>Metal atoms</term><term>Molecule</term><term>Obvious differences</term><term>Opposite chirality</term><term>Outer atoms</term><term>Pair type</term><term>Pair type heterochiral heterochiral homochiral homochiral heterochiral</term><term>Phen</term><term>Racemic compounds</term><term>Racemic mixtures</term><term>Ring planes</term><term>Same chirality</term><term>Site occupancies</term><term>Specific interactions</term><term>Structural systematics</term><term>Structure determinations</term><term>Structure refinement</term><term>Trial refinement</term><term>Unit cell contents</term><term>Various contacts</term><term>Verlag</term><term>Verlag gmbh</term><term>Water molecule</term><term>Water molecule oxygen atoms</term><term>Water molecules</term><term>Weinheim</term></keywords><keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Cobalt</term><term>Collecte de données</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Structural characterisation of a number of hydrated solids containing chiral, kinetically inert [Co(A–A)3]3+ cations (A–A = 2,2′‐bipyridine, 1,10‐phenanthroline, 4,4′‐dimethyl‐2,2′‐bipyridine) and chiral, kinetically labile [Ln(dipic)3]3– anions (Ln = La, Eu, Tb, Ho, Er, Lu, Y, though not for all cobalt cations; dipic = dipicolinate = pyridine‐2,6‐dicarboxylate) show a remarkable range of associations between the lattice components, though all are racemic arrays. Analysis of the structures in terms of short interatomic contacts between the components shows that, whereas numerous contacts of the heteroaromatic ligands do occur, very few define an arrangement which could be truly termed “π‐stacking” where the rings are closely parallel and atom overlaps in projection are substantial. Water is important in the highly hydrated lattice structures, not only because of hydrogen‐bonding interactions with itself and carboxylate‐O atoms but also because of its interactions with the aromatic units. The family [Co(bipy)3][Ln(dipic)3]·~13H2O are essentially isomorphous for the full range of Ln plus Y (triclinic, P\bar{1}, a = 12.3, b = 14.3, c = 16.5 Å, α = 94, β = 94, γ = 108 ˚, Z = 2). Among the heavier lanthanides, the potential symmetry of the anion/cation combination is realised in the trigonal space group P\bar{3}, both species lying together as an ion‐pair, disposed on the trigonal axis for [Co(phen)3][Ln(dipic)3]·22H2O (Ln = Eu, Er; a = 15.2, c = 16.8 Å, Z = 2).</div></front></TEI><affiliations><list><country><li>Australie</li><li>France</li></country><region><li>Alsace (région administrative)</li><li>Grand Est</li></region><settlement><li>Strasbourg</li></settlement></list><tree><country name="Australie"><noRegion><name sortKey="Harrowfield, Jack M" sort="Harrowfield, Jack M" uniqKey="Harrowfield J" first="Jack M." last="Harrowfield">Jack M. Harrowfield</name></noRegion><name sortKey="Koutsantonis, George A" sort="Koutsantonis, George A" uniqKey="Koutsantonis G" first="George A." last="Koutsantonis">George A. Koutsantonis</name><name sortKey="Skelton, Brian W" sort="Skelton, Brian W" uniqKey="Skelton B" first="Brian W." last="Skelton">Brian W. Skelton</name><name sortKey="Strong, Adam J" sort="Strong, Adam J" uniqKey="Strong A" first="Adam J." last="Strong">Adam J. Strong</name><name sortKey="White, Allan H" sort="White, Allan H" uniqKey="White A" first="Allan H." last="White">Allan H. White</name></country><country name="France"><region name="Grand Est"><name sortKey="Harrowfield, Jack M" sort="Harrowfield, Jack M" uniqKey="Harrowfield J" first="Jack M." last="Harrowfield">Jack M. Harrowfield</name></region><name sortKey="Harrowfield, Jack M" sort="Harrowfield, Jack M" uniqKey="Harrowfield J" first="Jack M." last="Harrowfield">Jack M. Harrowfield</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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