PittsburghV1, PascalFrancis, Corpus, bibRecord, 000D16

Vinyl-Triazolium Monomers: Versatile and New Class of Radically Polymerizable Ionic Monomers

Identifieur interne : 000D16 ( PascalFrancis/Corpus ); précédent : 000D15; suivant : 000D17

Vinyl-Triazolium Monomers: Versatile and New Class of Radically Polymerizable Ionic Monomers

Auteurs : Brian J. Adzima ; Steve C. Taylor ; HONGKUN HE ; David R. Luebke ; Krzysztof Matyjaszewski ; Hunaid B. Nulwala

Source :

Journal of polymer science. Part A. Polymer chemistry [ 0887-624X ] ; 2014.

RBID : Pascal:14-0094088

Descripteurs français

Pascal (Inist)
- Vinylique dérivé polymère, Triazole dérivé polymère, Imidazolium(vinyl) sel polymère, Préparation, Polymérisation radicalaire, Polymérisation solution, Polymérisation masse, Liquide ionique, Composé de l'iminium, Cinétique chimique, Stabilité thermique, Effet substituant, Etude expérimentale, Liquide ionique polymère, Triazolium(vinyl) sel polymère.

English descriptors

KwdEn :
- Bulk polymerization, Chemical reaction kinetics, Experimental study, Free radical polymerization, Imidazolium(vinyl) salt polymer, Iminium compounds, Ionic liquid, Polyvinyl derivative, Preparation, Solution polymerization, Substituent effect, Thermal stability, Triazole derivative polymer.

Abstract

A set of eight functional 4-vinyl-1,2,3-triazolium monomers were synthesized using copper catalyzed azide-alkyne 2 + 3 Hüisgen cycloaddition. These vinyl-trizolium monomers readily polymerized via free radical polymerization. The physical properties of the vinyl-triazolium based poly(ionic liquid)s (PILs) are strongly dependent on the pendant functional groups. These polymers were characterized for glass transition temperature (T_g), solubility, and the thermal decomposition. The vinyl-triazolium based PILs offer an efficient route to highly functional PILs with the advantage of facile synthesis and the ability to incorporate many desirable functional moieties.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

A01	`01`	`1`		`@0 0887-624X`
A02	`01`			`@0 JPLCAT`
A03		`1`		`@0 J. polym. sci., Part A, Polym. chem.`
A05				`@2 52`
A06				`@2 3`
A08	`01`	`1`	`ENG`	`@1 Vinyl-Triazolium Monomers: Versatile and New Class of Radically Polymerizable Ionic Monomers`
A11	`01`	`1`		`@1 ADZIMA (Brian J.)`
A11	`02`	`1`		`@1 TAYLOR (Steve C.)`
A11	`03`	`1`		`@1 HONGKUN HE`
A11	`04`	`1`		`@1 LUEBKE (David R.)`
A11	`05`	`1`		`@1 MATYJASZEWSKI (Krzysztof)`
A11	`06`	`1`		`@1 NULWALA (Hunaid B.)`
A14	`01`			`@1 National Energy Technology Laboratory @2 Pittsburgh, Pennsylvania 15236 @3 USA @Z 1 aut. @Z 2 aut. @Z 4 aut. @Z 6 aut.`
A14	`02`			`@1 Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue @2 Pittsburgh, Pennsylvania 15213 @3 USA @Z 1 aut. @Z 3 aut. @Z 5 aut. @Z 6 aut.`
A20				`@1 417-423`
A21				`@1 2014`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 6199A1 @5 354000505776920150`
A44				`@0 0000 @1 © 2014 INIST-CNRS. All rights reserved.`
A47	`01`	`1`		`@0 14-0094088`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Journal of polymer science. Part A. Polymer chemistry`
A66	`01`			`@0 USA`
A99				`@0 3/4 p. ref. et notes`
C01	`01`		`ENG`	@0 A set of eight functional 4-vinyl-1,2,3-triazolium monomers were synthesized using copper catalyzed azide-alkyne 2 + 3 Hüisgen cycloaddition. These vinyl-trizolium monomers readily polymerized via free radical polymerization. The physical properties of the vinyl-triazolium based poly(ionic liquid)s (PILs) are strongly dependent on the pendant functional groups. These polymers were characterized for glass transition temperature (T_g), solubility, and the thermal decomposition. The vinyl-triazolium based PILs offer an efficient route to highly functional PILs with the advantage of facile synthesis and the ability to incorporate many desirable functional moieties.
C02	`01`	`X`		`@0 001D09D02B`
C03	`01`	`X`	`FRE`	`@0 Vinylique dérivé polymère @2 NK @5 01`
C03	`01`	`X`	`ENG`	`@0 Polyvinyl derivative @2 NK @5 01`
C03	`01`	`X`	`SPA`	`@0 Vinílico derivado polímero @2 NK @5 01`
C03	`02`	`X`	`FRE`	`@0 Triazole dérivé polymère @2 NK @5 02`
C03	`02`	`X`	`ENG`	`@0 Triazole derivative polymer @2 NK @5 02`
C03	`02`	`X`	`SPA`	`@0 Triazol derivado polímero @2 NK @5 02`
C03	`03`	`X`	`FRE`	`@0 Imidazolium(vinyl) sel polymère @2 NK @5 03`
C03	`03`	`X`	`ENG`	`@0 Imidazolium(vinyl) salt polymer @2 NK @5 03`
C03	`03`	`X`	`SPA`	`@0 Imidazolio(vinil) sal polímero @2 NK @5 03`
C03	`04`	`X`	`FRE`	`@0 Préparation @5 04`
C03	`04`	`X`	`ENG`	`@0 Preparation @5 04`
C03	`04`	`X`	`SPA`	`@0 Preparación @5 04`
C03	`05`	`X`	`FRE`	`@0 Polymérisation radicalaire @5 05`
C03	`05`	`X`	`ENG`	`@0 Free radical polymerization @5 05`
C03	`05`	`X`	`SPA`	`@0 Polimerización radicalar @5 05`
C03	`06`	`X`	`FRE`	`@0 Polymérisation solution @5 06`
C03	`06`	`X`	`ENG`	`@0 Solution polymerization @5 06`
C03	`06`	`X`	`SPA`	`@0 Polimerización solución @5 06`
C03	`07`	`X`	`FRE`	`@0 Polymérisation masse @5 07`
C03	`07`	`X`	`ENG`	`@0 Bulk polymerization @5 07`
C03	`07`	`X`	`SPA`	`@0 Polimerización masa @5 07`
C03	`08`	`X`	`FRE`	`@0 Liquide ionique @1 ENT @5 08`
C03	`08`	`X`	`ENG`	`@0 Ionic liquid @1 ENT @5 08`
C03	`08`	`X`	`SPA`	`@0 Líquido iónico @1 ENT @5 08`
C03	`09`	`X`	`FRE`	`@0 Composé de l'iminium @1 ENT @5 09`
C03	`09`	`X`	`ENG`	`@0 Iminium compounds @1 ENT @5 09`
C03	`09`	`X`	`SPA`	`@0 Iminio compuesto @1 ENT @5 09`
C03	`10`	`X`	`FRE`	`@0 Cinétique chimique @5 10`
C03	`10`	`X`	`ENG`	`@0 Chemical reaction kinetics @5 10`
C03	`10`	`X`	`SPA`	`@0 Cinética química @5 10`
C03	`11`	`X`	`FRE`	`@0 Stabilité thermique @5 11`
C03	`11`	`X`	`ENG`	`@0 Thermal stability @5 11`
C03	`11`	`X`	`SPA`	`@0 Estabilidad térmica @5 11`
C03	`12`	`X`	`FRE`	`@0 Effet substituant @5 12`
C03	`12`	`X`	`ENG`	`@0 Substituent effect @5 12`
C03	`12`	`X`	`SPA`	`@0 Efecto sustituyente @5 12`
C03	`13`	`X`	`FRE`	`@0 Etude expérimentale @5 13`
C03	`13`	`X`	`ENG`	`@0 Experimental study @5 13`
C03	`13`	`X`	`SPA`	`@0 Estudio experimental @5 13`
C03	`14`	`X`	`FRE`	`@0 Liquide ionique polymère @2 NK @4 INC @5 41`
C03	`15`	`X`	`FRE`	`@0 Triazolium(vinyl) sel polymère @2 NK @4 INC @5 42`
N21				`@1 125`

Format Inist (serveur)

NO :	PASCAL 14-0094088 INIST
ET :	Vinyl-Triazolium Monomers: Versatile and New Class of Radically Polymerizable Ionic Monomers
AU :	ADZIMA (Brian J.); TAYLOR (Steve C.); HONGKUN HE; LUEBKE (David R.); MATYJASZEWSKI (Krzysztof); NULWALA (Hunaid B.)
AF :	National Energy Technology Laboratory/Pittsburgh, Pennsylvania 15236/Etats-Unis (1 aut., 2 aut., 4 aut., 6 aut.); Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue/Pittsburgh, Pennsylvania 15213/Etats-Unis (1 aut., 3 aut., 5 aut., 6 aut.)
DT :	Publication en série; Niveau analytique
SO :	Journal of polymer science. Part A. Polymer chemistry; ISSN 0887-624X; Coden JPLCAT; Etats-Unis; Da. 2014; Vol. 52; No. 3; Pp. 417-423
LA :	Anglais
EA :	A set of eight functional 4-vinyl-1,2,3-triazolium monomers were synthesized using copper catalyzed azide-alkyne 2 + 3 Hüisgen cycloaddition. These vinyl-trizolium monomers readily polymerized via free radical polymerization. The physical properties of the vinyl-triazolium based poly(ionic liquid)s (PILs) are strongly dependent on the pendant functional groups. These polymers were characterized for glass transition temperature (T_g), solubility, and the thermal decomposition. The vinyl-triazolium based PILs offer an efficient route to highly functional PILs with the advantage of facile synthesis and the ability to incorporate many desirable functional moieties.
CC :	001D09D02B
FD :	Vinylique dérivé polymère; Triazole dérivé polymère; Imidazolium(vinyl) sel polymère; Préparation; Polymérisation radicalaire; Polymérisation solution; Polymérisation masse; Liquide ionique; Composé de l'iminium; Cinétique chimique; Stabilité thermique; Effet substituant; Etude expérimentale; Liquide ionique polymère; Triazolium(vinyl) sel polymère
ED :	Polyvinyl derivative; Triazole derivative polymer; Imidazolium(vinyl) salt polymer; Preparation; Free radical polymerization; Solution polymerization; Bulk polymerization; Ionic liquid; Iminium compounds; Chemical reaction kinetics; Thermal stability; Substituent effect; Experimental study
SD :	Vinílico derivado polímero; Triazol derivado polímero; Imidazolio(vinil) sal polímero; Preparación; Polimerización radicalar; Polimerización solución; Polimerización masa; Líquido iónico; Iminio compuesto; Cinética química; Estabilidad térmica; Efecto sustituyente; Estudio experimental
LO :	INIST-6199A1.354000505776920150
ID :	14-0094088

Links to Exploration step

Pascal:14-0094088

Le document en format XML

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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Vinyl-Triazolium Monomers: Versatile and New Class of Radically Polymerizable Ionic Monomers</title>
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<series><title level="j" type="main">Journal of polymer science. Part A. Polymer chemistry</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Bulk polymerization</term>
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<term>Free radical polymerization</term>
<term>Imidazolium(vinyl) salt polymer</term>
<term>Iminium compounds</term>
<term>Ionic liquid</term>
<term>Polyvinyl derivative</term>
<term>Preparation</term>
<term>Solution polymerization</term>
<term>Substituent effect</term>
<term>Thermal stability</term>
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<keywords scheme="Pascal" xml:lang="fr"><term>Vinylique dérivé polymère</term>
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<term>Polymérisation radicalaire</term>
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<term>Liquide ionique</term>
<term>Composé de l'iminium</term>
<term>Cinétique chimique</term>
<term>Stabilité thermique</term>
<term>Effet substituant</term>
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<front><div type="abstract" xml:lang="en">A set of eight functional 4-vinyl-1,2,3-triazolium monomers were synthesized using copper catalyzed azide-alkyne 2 + 3 Hüisgen cycloaddition. These vinyl-trizolium monomers readily polymerized via free radical polymerization. The physical properties of the vinyl-triazolium based poly(ionic liquid)s (PILs) are strongly dependent on the pendant functional groups. These polymers were characterized for glass transition temperature (T<sub>g</sub>
), solubility, and the thermal decomposition. The vinyl-triazolium based PILs offer an efficient route to highly functional PILs with the advantage of facile synthesis and the ability to incorporate many desirable functional moieties.</div>
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<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Journal of polymer science. Part A. Polymer chemistry</s0>
</fA64>
<fA66 i1="01"><s0>USA</s0>
</fA66>
<fA99><s0>3/4 p. ref. et notes</s0>
</fA99>
<fC01 i1="01" l="ENG"><s0>A set of eight functional 4-vinyl-1,2,3-triazolium monomers were synthesized using copper catalyzed azide-alkyne 2 + 3 Hüisgen cycloaddition. These vinyl-trizolium monomers readily polymerized via free radical polymerization. The physical properties of the vinyl-triazolium based poly(ionic liquid)s (PILs) are strongly dependent on the pendant functional groups. These polymers were characterized for glass transition temperature (T<sub>g</sub>
), solubility, and the thermal decomposition. The vinyl-triazolium based PILs offer an efficient route to highly functional PILs with the advantage of facile synthesis and the ability to incorporate many desirable functional moieties.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001D09D02B</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Vinylique dérivé polymère</s0>
<s2>NK</s2>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Polyvinyl derivative</s0>
<s2>NK</s2>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Vinílico derivado polímero</s0>
<s2>NK</s2>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Triazole dérivé polymère</s0>
<s2>NK</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Triazole derivative polymer</s0>
<s2>NK</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Triazol derivado polímero</s0>
<s2>NK</s2>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Imidazolium(vinyl) sel polymère</s0>
<s2>NK</s2>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Imidazolium(vinyl) salt polymer</s0>
<s2>NK</s2>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Imidazolio(vinil) sal polímero</s0>
<s2>NK</s2>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Préparation</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Preparation</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Preparación</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Polymérisation radicalaire</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Free radical polymerization</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Polimerización radicalar</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Polymérisation solution</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Solution polymerization</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Polimerización solución</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Polymérisation masse</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Bulk polymerization</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Polimerización masa</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Liquide ionique</s0>
<s1>ENT</s1>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Ionic liquid</s0>
<s1>ENT</s1>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Líquido iónico</s0>
<s1>ENT</s1>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Composé de l'iminium</s0>
<s1>ENT</s1>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Iminium compounds</s0>
<s1>ENT</s1>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Iminio compuesto</s0>
<s1>ENT</s1>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Cinétique chimique</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Chemical reaction kinetics</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Cinética química</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Stabilité thermique</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Thermal stability</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Estabilidad térmica</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Effet substituant</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Substituent effect</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Efecto sustituyente</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Etude expérimentale</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG"><s0>Experimental study</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA"><s0>Estudio experimental</s0>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE"><s0>Liquide ionique polymère</s0>
<s2>NK</s2>
<s4>INC</s4>
<s5>41</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Triazolium(vinyl) sel polymère</s0>
<s2>NK</s2>
<s4>INC</s4>
<s5>42</s5>
</fC03>
<fN21><s1>125</s1>
</fN21>
</pA>
</standard>
<server><NO>PASCAL 14-0094088 INIST</NO>
<ET>Vinyl-Triazolium Monomers: Versatile and New Class of Radically Polymerizable Ionic Monomers</ET>
<AU>ADZIMA (Brian J.); TAYLOR (Steve C.); HONGKUN HE; LUEBKE (David R.); MATYJASZEWSKI (Krzysztof); NULWALA (Hunaid B.)</AU>
<AF>National Energy Technology Laboratory/Pittsburgh, Pennsylvania 15236/Etats-Unis (1 aut., 2 aut., 4 aut., 6 aut.); Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue/Pittsburgh, Pennsylvania 15213/Etats-Unis (1 aut., 3 aut., 5 aut., 6 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Journal of polymer science. Part A. Polymer chemistry; ISSN 0887-624X; Coden JPLCAT; Etats-Unis; Da. 2014; Vol. 52; No. 3; Pp. 417-423</SO>
<LA>Anglais</LA>
<EA>A set of eight functional 4-vinyl-1,2,3-triazolium monomers were synthesized using copper catalyzed azide-alkyne 2 + 3 Hüisgen cycloaddition. These vinyl-trizolium monomers readily polymerized via free radical polymerization. The physical properties of the vinyl-triazolium based poly(ionic liquid)s (PILs) are strongly dependent on the pendant functional groups. These polymers were characterized for glass transition temperature (T<sub>g</sub>
), solubility, and the thermal decomposition. The vinyl-triazolium based PILs offer an efficient route to highly functional PILs with the advantage of facile synthesis and the ability to incorporate many desirable functional moieties.</EA>
<CC>001D09D02B</CC>
<FD>Vinylique dérivé polymère; Triazole dérivé polymère; Imidazolium(vinyl) sel polymère; Préparation; Polymérisation radicalaire; Polymérisation solution; Polymérisation masse; Liquide ionique; Composé de l'iminium; Cinétique chimique; Stabilité thermique; Effet substituant; Etude expérimentale; Liquide ionique polymère; Triazolium(vinyl) sel polymère</FD>
<ED>Polyvinyl derivative; Triazole derivative polymer; Imidazolium(vinyl) salt polymer; Preparation; Free radical polymerization; Solution polymerization; Bulk polymerization; Ionic liquid; Iminium compounds; Chemical reaction kinetics; Thermal stability; Substituent effect; Experimental study</ED>
<SD>Vinílico derivado polímero; Triazol derivado polímero; Imidazolio(vinil) sal polímero; Preparación; Polimerización radicalar; Polimerización solución; Polimerización masa; Líquido iónico; Iminio compuesto; Cinética química; Estabilidad térmica; Efecto sustituyente; Estudio experimental</SD>
<LO>INIST-6199A1.354000505776920150</LO>
<ID>14-0094088</ID>
</server>
</inist>
</record>

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Vinyl-Triazolium Monomers: Versatile and New Class of Radically Polymerizable Ionic Monomers

Vinyl-Triazolium Monomers: Versatile and New Class of Radically Polymerizable Ionic Monomers

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