Synthesis of triblock and multiblock methacrylate polymers and self‐assembly of stimuli responsive triblock polymers
Identifieur interne : 004869 ( Main/Merge ); précédent : 004868; suivant : 004870Synthesis of triblock and multiblock methacrylate polymers and self‐assembly of stimuli responsive triblock polymers
Auteurs : Stacey M. Chin [États-Unis] ; Hongkun He [États-Unis] ; Dominik Konkolewicz [États-Unis] ; Krzysztof Matyjaszewski [États-Unis]Source :
- Journal of Polymer Science Part A: Polymer Chemistry [ 0887-624X ] ; 2014-09-01.
Abstract
Multisegmented poly(methacrylate)s were synthesized using one pot reversible addition fragmentation chain transfer polymerization. Initially, a series of triblock copolymers were synthesized with different ratios of trimethylsilyl methacrylate, di(ethylene oxide) methacrylate, and oligo(ethylene oxide) methacrylate, and different total polymer molecular weights. Additionally, a polymer containing seven distinct blocks of methacrylic monomers was synthesized in one pot. For the triblock copolymers, the trimethylsilyl group was subsequently hydrolyzed, and the self‐assembly of the triblock copolymer was studied in water, under different pH and thermal conditions. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 2548–2555
Url:
DOI: 10.1002/pola.27271
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Chin</name></author><author><name sortKey="He, Hongkun" sort="He, Hongkun" uniqKey="He H" first="Hongkun" last="He">Hongkun He</name></author><author><name sortKey="Konkolewicz, Dominik" sort="Konkolewicz, Dominik" uniqKey="Konkolewicz D" first="Dominik" last="Konkolewicz">Dominik Konkolewicz</name></author><author><name sortKey="Matyjaszewski, Krzysztof" sort="Matyjaszewski, Krzysztof" uniqKey="Matyjaszewski K" first="Krzysztof" last="Matyjaszewski">Krzysztof Matyjaszewski</name></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:9D2C6AED185A9F75CF29F42C2AB99CE655AA76BF</idno><date when="2014" year="2014">2014</date><idno type="doi">10.1002/pola.27271</idno><idno type="url">https://api.istex.fr/document/9D2C6AED185A9F75CF29F42C2AB99CE655AA76BF/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">002500</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">002500</idno><idno type="wicri:Area/Istex/Curation">002500</idno><idno type="wicri:Area/Istex/Checkpoint">000140</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000140</idno><idno type="wicri:doubleKey">0887-624X:2014:Chin S:synthesis:of:triblock</idno><idno type="wicri:Area/Main/Merge">004869</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main">Synthesis of triblock and multiblock methacrylate polymers and self‐assembly of stimuli responsive triblock polymers</title><author><name sortKey="Chin, Stacey M" sort="Chin, Stacey M" uniqKey="Chin S" first="Stacey M." last="Chin">Stacey M. Chin</name><affiliation wicri:level="3"><country>États-Unis</country><placeName><settlement type="city">Pittsburgh</settlement><region type="state">Pennsylvanie</region></placeName><wicri:orgArea>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pennsylvania, 15213</wicri:orgArea></affiliation></author><author><name sortKey="He, Hongkun" sort="He, Hongkun" uniqKey="He H" first="Hongkun" last="He">Hongkun He</name><affiliation wicri:level="3"><country>États-Unis</country><placeName><settlement type="city">Pittsburgh</settlement><region type="state">Pennsylvanie</region></placeName><wicri:orgArea>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pennsylvania, 15213</wicri:orgArea></affiliation></author><author><name sortKey="Konkolewicz, Dominik" sort="Konkolewicz, Dominik" uniqKey="Konkolewicz D" first="Dominik" last="Konkolewicz">Dominik Konkolewicz</name><affiliation wicri:level="3"><country>États-Unis</country><placeName><settlement type="city">Pittsburgh</settlement><region type="state">Pennsylvanie</region></placeName><wicri:orgArea>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pennsylvania, 15213</wicri:orgArea></affiliation><affiliation wicri:level="1"><country wicri:rule="url">États-Unis</country></affiliation></author><author><name sortKey="Matyjaszewski, Krzysztof" sort="Matyjaszewski, Krzysztof" uniqKey="Matyjaszewski K" first="Krzysztof" last="Matyjaszewski">Krzysztof Matyjaszewski</name><affiliation wicri:level="3"><country>États-Unis</country><placeName><settlement type="city">Pittsburgh</settlement><region type="state">Pennsylvanie</region></placeName><wicri:orgArea>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pennsylvania, 15213</wicri:orgArea></affiliation><affiliation wicri:level="1"><country wicri:rule="url">États-Unis</country></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">Journal of Polymer Science Part A: Polymer Chemistry</title><title level="j" type="alt">JOURNAL OF POLYMER SCIENCE PART A: POLYMER CHEMISTRY</title><idno type="ISSN">0887-624X</idno><idno type="eISSN">1099-0518</idno><imprint><biblScope unit="vol">52</biblScope><biblScope unit="issue">17</biblScope><biblScope unit="page" from="2548">2548</biblScope><biblScope unit="page" to="2555">2555</biblScope><biblScope unit="page-count">8</biblScope><date type="published" when="2014-09-01">2014-09-01</date></imprint><idno type="ISSN">0887-624X</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0887-624X</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract">Multisegmented poly(methacrylate)s were synthesized using one pot reversible addition fragmentation chain transfer polymerization. Initially, a series of triblock copolymers were synthesized with different ratios of trimethylsilyl methacrylate, di(ethylene oxide) methacrylate, and oligo(ethylene oxide) methacrylate, and different total polymer molecular weights. Additionally, a polymer containing seven distinct blocks of methacrylic monomers was synthesized in one pot. For the triblock copolymers, the trimethylsilyl group was subsequently hydrolyzed, and the self‐assembly of the triblock copolymer was studied in water, under different pH and thermal conditions. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 2548–2555</div></front></TEI></record>Pour manipuler ce document sous Unix (Dilib)
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