ASI: Toward the optimal integrated production of biodiesel with internal recycling of methanol produced from glycerol
Identifieur interne : 006245 ( Main/Exploration ); précédent : 006244; suivant : 006246ASI: Toward the optimal integrated production of biodiesel with internal recycling of methanol produced from glycerol
Auteurs : Mariano Martín [Espagne] ; Ignacio E. Grossmann [États-Unis]Source :
- Environmental Progress & Sustainable Energy [ 1944-7442 ] ; 2013-12.
Descripteurs français
- Pascal (Inist)
- Wicri :
English descriptors
- KwdEn :
- Aiche journal, Algae, American institute, Autoreforming, Biodiesel, Biodiesel production, Bioethanol, Biomass, Bypass, Byproduct, Carbon dioxide, Carnegie mellon university, Catadded2 cmetoh, Catalyst, Catalyst load, Chemical engineering, Chemical engineering journal, Composition adjustment, Cost analysis, December, Design, Distillation column, Economic evaluation, Energy balances, Energy consumption, Energy fuels, Environmental progress, Equilibrium constants, Equipment cost, Experimental data, Experimental results, Fenske equation, Fossil, Fossil fuel, Fossil fuels, Further details, Galbiofuel energy water investment, Glycerol, Glycerol recycling, Grossmann, Gure, Heat integration, Heat recovery, Heterogeneous catalysis, Heterogeneous catalyst, Heterogeneous catalysts, Hydrogen energy, Hydrogen production, Industrial engineering chemistry research, International journal, Investment cost, Liquid fuels, Mart, Mathematical modelling, Methanol, Methanol production, Methanol reactor, Methanol synthesis, Methanol synthesis reactor, Online, Online issue, Optimal heat exchanger network, Optimal operation, Optimal process, Optimal production, Optimization, Phase separation, Previous paper, Previous papers, Production, Production cost, Production costs, Production process, Reactor, Recycling, Royal society, Shift reactor, Simultaneous optimization, Simultaneous production, Split fraction, Steam reforming, Superstructure, Syngas, Synthesis gas, Thermodynamic analysis, Water consumption, Water gas, Water network.
- Teeft :
- Aiche journal, American institute, Autoreforming, Biodiesel, Biodiesel production, Bioethanol, Biomass, Byproduct, Carnegie mellon university, Catadded2 cmetoh, Catalyst, Catalyst load, Chemical engineering, Chemical engineering journal, Composition adjustment, Cost analysis, December, Distillation column, Economic evaluation, Energy balances, Energy fuels, Environmental progress, Equilibrium constants, Equipment cost, Experimental data, Experimental results, Fenske equation, Fossil, Fossil fuel, Fossil fuels, Further details, Galbiofuel energy water investment, Glycerol, Glycerol recycling, Grossmann, Gure, Heat integration, Heterogeneous catalyst, Heterogeneous catalysts, Hydrogen energy, Hydrogen production, Industrial engineering chemistry research, International journal, Investment cost, Liquid fuels, Mart, Mathematical modelling, Methanol, Methanol production, Methanol reactor, Methanol synthesis, Methanol synthesis reactor, Online, Online issue, Optimal heat exchanger network, Optimal operation, Optimal process, Optimal production, Optimization, Phase separation, Previous paper, Previous papers, Production cost, Production costs, Production process, Reactor, Royal society, Shift reactor, Simultaneous optimization, Simultaneous production, Split fraction, Superstructure, Syngas, Thermodynamic analysis, Water consumption, Water network.
Abstract
In this article, we present the optimization of the production methanol from glycerol and its integration in the production of biodiesel from algae. We propose a limited superstructure where the glycerol from biodiesel is first reformed for which steam reforming and autoreforming are evaluated. The gas obtained is cleaned up and its composition is adjusted in terms of the ratio CO/H2 using three possible alternatives (bypass, PSA and water gas shift). Next, the removal of CO2 is performed by means of PSA and the syngas is fed to the methanol synthesis reactor and the products obtained are separated. This synthesis is coupled with the production of biodiesel from algae using heterogeneous catalyzed reaction based on previous results. The optimization of the system is formulated as a Mixed Integer Nonlinear Programming (MINLP) that is solved for the simultaneous optimization and heat integration of the production of biodiesel with recycle of methanol followed by water integration. The best process involves the use of autoreforming for a production cost of $0.66 gal−1, 3.65 MJ/gal of energy consumption and water consumption of 0.79 gal/gal. The integrated process is $0.2 gal−1 more expensive than the one that directly uses methanol but reduces in more than half the dependency of the process on fossil fuels. © 2013 American Institute of Chemical Engineers Environ Prog, 32: 891–901, 2013
Url:
DOI: 10.1002/ep.11836
Affiliations:
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l'eau</term><term>Optimisation</term><term>Production</term><term>Recyclage</term><term>Reformage vapeur</term><term>Réacteur</term><term>Récupération chaleur</term><term>Surstructure</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Aiche journal</term><term>American institute</term><term>Autoreforming</term><term>Biodiesel</term><term>Biodiesel production</term><term>Bioethanol</term><term>Biomass</term><term>Byproduct</term><term>Carnegie mellon university</term><term>Catadded2 cmetoh</term><term>Catalyst</term><term>Catalyst load</term><term>Chemical engineering</term><term>Chemical engineering journal</term><term>Composition adjustment</term><term>Cost analysis</term><term>December</term><term>Distillation column</term><term>Economic evaluation</term><term>Energy balances</term><term>Energy fuels</term><term>Environmental progress</term><term>Equilibrium constants</term><term>Equipment cost</term><term>Experimental data</term><term>Experimental 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separation</term><term>Previous paper</term><term>Previous papers</term><term>Production cost</term><term>Production costs</term><term>Production process</term><term>Reactor</term><term>Royal society</term><term>Shift reactor</term><term>Simultaneous optimization</term><term>Simultaneous production</term><term>Split fraction</term><term>Superstructure</term><term>Syngas</term><term>Thermodynamic analysis</term><term>Water consumption</term><term>Water network</term></keywords><keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Biomasse</term><term>Analyse des coûts</term><term>Combustible fossile</term><term>Coût d'équipement</term><term>Combustible fossile</term><term>Production</term><term>Production d'hydrogène</term><term>Coût d'investissement</term><term>Méthanol</term><term>Coût de production</term><term>Consommation d'eau</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract">In this article, we present the optimization of the production methanol from glycerol and its integration in the production of biodiesel from algae. We propose a limited superstructure where the glycerol from biodiesel is first reformed for which steam reforming and autoreforming are evaluated. The gas obtained is cleaned up and its composition is adjusted in terms of the ratio CO/H2 using three possible alternatives (bypass, PSA and water gas shift). Next, the removal of CO2 is performed by means of PSA and the syngas is fed to the methanol synthesis reactor and the products obtained are separated. This synthesis is coupled with the production of biodiesel from algae using heterogeneous catalyzed reaction based on previous results. The optimization of the system is formulated as a Mixed Integer Nonlinear Programming (MINLP) that is solved for the simultaneous optimization and heat integration of the production of biodiesel with recycle of methanol followed by water integration. The best process involves the use of autoreforming for a production cost of $0.66 gal−1, 3.65 MJ/gal of energy consumption and water consumption of 0.79 gal/gal. The integrated process is $0.2 gal−1 more expensive than the one that directly uses methanol but reduces in more than half the dependency of the process on fossil fuels. © 2013 American Institute of Chemical Engineers Environ Prog, 32: 891–901, 2013</div></front></TEI><affiliations><list><country><li>Espagne</li><li>États-Unis</li></country><region><li>Pennsylvanie</li></region></list><tree><country name="Espagne"><noRegion><name sortKey="Martin, Mariano" sort="Martin, Mariano" uniqKey="Martin M" first="Mariano" last="Martín">Mariano Martín</name></noRegion><name sortKey="Martin, Mariano" sort="Martin, Mariano" uniqKey="Martin M" first="Mariano" last="Martín">Mariano Martín</name></country><country name="États-Unis"><region name="Pennsylvanie"><name sortKey="Grossmann, Ignacio E" sort="Grossmann, Ignacio E" uniqKey="Grossmann I" first="Ignacio E." last="Grossmann">Ignacio E. Grossmann</name></region></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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