PittsburghV1, Istex, Corpus, bibRecord, 003D21

The Parent Borylene: Betwixt and Between

Identifieur interne : 003D21 ( Istex/Corpus ); précédent : 003D20; suivant : 003D22

The Parent Borylene: Betwixt and Between

Auteurs : Dennis P. Curran ; Anne Boussonnière ; Steven J. Geib ; Emmanuel Lacôte

Source :

Angewandte Chemie [ 0044-8249 ] ; 2012-02-13.

RBID : ISTEX:FBFAFFEEC012019CC7CC33600918AE12805BDFF0

English descriptors

KwdEn :
- Aliphatic, Aliphatic products, Alkyl, Alkyl halides, Angew, Angewandte, Anion, Boriranes, Boryl, Boryl dichlorides, Borylene, Braunschweig, Chem, Cleaner crude product, Crystal structures, Curran, Electron transfer, Equiv, Fensterbank, Flash chromatography, Geib, Gmbh, Halide, Insertion, Insertion product, Insertion products, Kgaa, Ldbb, Makhlouf brahmi, Malacria, Naphthalene, Naphthalenide, Sodium naphthalenide, Solovyev, Triplet, Verlag, Verlag gmbh, Weinheim, Weinheim angew.
Teeft :
- Aliphatic, Aliphatic products, Alkyl, Alkyl halides, Angew, Angewandte, Anion, Boriranes, Boryl, Boryl dichlorides, Borylene, Braunschweig, Chem, Cleaner crude product, Crystal structures, Curran, Electron transfer, Equiv, Fensterbank, Flash chromatography, Geib, Gmbh, Halide, Insertion, Insertion product, Insertion products, Kgaa, Ldbb, Makhlouf brahmi, Malacria, Naphthalene, Naphthalenide, Sodium naphthalenide, Solovyev, Triplet, Verlag, Verlag gmbh, Weinheim, Weinheim angew.

Abstract

Schwer greifbar: Es wurde vorgeschlagen, dass die Reduktion von Dimethylimidazol‐2‐yliden‐dichloroboran durch Natriumnaphthalenid ein Borylen liefert, das unter Bildung eines Borirans an Naphthalin cycloaddiert. Nun werden Beweise vorgelegt, dass dieses Boriran stattdessen aus der Kupplung eines Borylradikals mit Natriumnaphthalenid entsteht.

Url:

https://api.istex.fr/document/FBFAFFEEC012019CC7CC33600918AE12805BDFF0/fulltext/pdf

DOI: 10.1002/ange.201107238

Links to Exploration step

ISTEX:FBFAFFEEC012019CC7CC33600918AE12805BDFF0

Le document en format XML

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The Parent Borylene: Betwixt and Between

The Parent Borylene: Betwixt and Between

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