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ChemInform Abstract: Silica Gel Promotes Reductions of Aldehydes and Ketones by N‐Heterocyclic Carbene Boranes.

Identifieur interne : 002315 ( Istex/Corpus ); précédent : 002314; suivant : 002316

ChemInform Abstract: Silica Gel Promotes Reductions of Aldehydes and Ketones by N‐Heterocyclic Carbene Boranes.

Auteurs : Tsuyoshi Taniguchi ; Dennis P. Curran

Source :

RBID : ISTEX:958D9C4B9DE372B0DB9282206930ACDD0E3F0F42

English descriptors

Abstract

One, two, or all three of the boron hydrides of carbene borane NHC and its dimethyl analogue can be transferred to the aldehydes and ketones to give primary and secondary alcohols under ambient conditions and in the presence of SiO2, which is crucial for the rapid reduction.

Url:
DOI: 10.1002/chin.201252072

Links to Exploration step

ISTEX:958D9C4B9DE372B0DB9282206930ACDD0E3F0F42

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