The E 2Σ+ → C 2Π Transition of NO and Term Values for the A, D, E, and C Lowest Rydberg Levels
Identifieur interne : 000296 ( France/Analysis ); précédent : 000295; suivant : 000297The E 2Σ+ → C 2Π Transition of NO and Term Values for the A, D, E, and C Lowest Rydberg Levels
Auteurs : V. D. Braun [Japon] ; K. P. Huber [Canada] ; M. Vervloet [France] ; C. Amiot [France] ; J. Vergès [France] ; K. Tsukiyama [Japon]Source :
- Journal of Molecular Spectroscopy [ 0022-2852 ] ; 2000.
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Abstract
The E2Σ+ → C2Π Rydberg–Rydberg transition of 14N16O near 8492 cm−1 has been studied by Fourier transform spectrometry in the emission from a dc excited supersonic jet expansion and from a dc discharge under equilibrium conditions. The same transition has also been observed in laser-induced stimulated emission. Line wavenumbers of the 0–0, 1–1, and 2–2 bands, together with data for previously published near-infrared transitions, have been reduced to consistent sets of rovibronic term values for v = 0, 1, and 2 of the A2Σ+, D2Σ+, E2Σ+, and C2Π states which frequently serve as intermediates in the multiphoton excitation of higher Rydberg levels of NO.
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DOI: 10.1006/jmsp.2000.8148
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The same transition has also been observed in laser-induced stimulated emission. Line wavenumbers of the 0–0, 1–1, and 2–2 bands, together with data for previously published near-infrared transitions, have been reduced to consistent sets of rovibronic term values for v = 0, 1, and 2 of the A2Σ+, D2Σ+, E2Σ+, and C2Π states which frequently serve as intermediates in the multiphoton excitation of higher Rydberg levels of NO.</div></front></TEI><affiliations><list><country><li>Canada</li><li>France</li><li>Japon</li></country><region><li>Île-de-France</li></region><settlement><li>Orsay</li></settlement></list><tree><country name="Japon"><noRegion><name sortKey="Braun, V D" sort="Braun, V D" uniqKey="Braun V" first="V. D." last="Braun">V. D. Braun</name></noRegion><name sortKey="Tsukiyama, K" sort="Tsukiyama, K" uniqKey="Tsukiyama K" first="K." last="Tsukiyama">K. 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