Application of zirconium dioxide nanoparticle sorbent for the clean-up step in post-harvest pesticide residue analysis.
Identifieur interne : 000120 ( PubMed/Corpus ); précédent : 000119; suivant : 000121Application of zirconium dioxide nanoparticle sorbent for the clean-up step in post-harvest pesticide residue analysis.
Auteurs : Ana Uclés ; Sonia Herrera L Pez ; Maria Dolores Hernando ; Roberto Rosal ; Carmen Ferrer ; Amadeo R. Fernández-AlbaSource :
- Talanta [ 1873-3573 ] ; 2015.
English descriptors
- KwdEn :
- Adsorption, Chromatography, Liquid, Citrus sinensis (chemistry), Limit of Detection, Linear Models, Nanoparticles (chemistry), Nanotubes, Carbon (chemistry), Pesticide Residues (analysis), Pesticide Residues (chemistry), Pesticide Residues (isolation & purification), Pyrus (chemistry), Safety, Solid Phase Extraction (economics), Solid Phase Extraction (methods), Soot (chemistry), Tandem Mass Spectrometry, Time Factors, Yttrium (chemistry), Zirconium (chemistry).
- MESH :
- chemical , analysis : Pesticide Residues.
- chemical , chemistry : Nanotubes, Carbon, Pesticide Residues, Soot, Yttrium, Zirconium.
- chemistry : Citrus sinensis, Nanoparticles, Pyrus.
- economics : Solid Phase Extraction.
- chemical , isolation & purification : Pesticide Residues.
- methods : Solid Phase Extraction.
- Adsorption, Chromatography, Liquid, Limit of Detection, Linear Models, Safety, Tandem Mass Spectrometry, Time Factors.
Abstract
The use of yttria-stabilized zirconium dioxide nanoparticles as d-SPE clean-up sorbent for a rapid and sensitive liquid chromatography-electrospray ionization-tandem mass spectrometry (LC-ESI-MS/MS) method for the determination of post-harvest fungicides (carbaryl, carbendazim, chlorpropham, diphenylamine, ethoxyquin, flutriafol, imazalil, iprodione, methomyl, myclobutanil, pirimiphos-methyl, prochloraz, pyrimethanil, thiabendazole, thiophanate-methyl and tolclofos-methyl) in orange and pear samples has been evaluated and validated. The sample preparation was a modification of the QuEChERS extraction method using yttria-stabilized zirconium dioxide and multi-walled carbon nanotubes (MWCNTs) nanoparticles as the solid phase extraction (d-SPE) clean-up sorbents prior to injecting the ten-fold diluted extracts into the LC system. By using the yttria-stabilized zirconium dioxide extraction method, more recoveries in the 70-120% range were obtained - thus this method was used for the validation. Quantification was carried out using a matrix-matched calibration curve which was linear in the 1-500 µg kg(-1) range for almost all the pesticides studied. The validated limit of quantification was 10 µg kg(-1) for most of the studied compounds, except chlorpropham, ethoxyquin and thiophanate-methyl. Pesticide recoveries at the 10 and 100 µg kg(-1) concentration levels were satisfactory, with values between 77% and 120% and relative standard deviations (RSD) lower than 10% (n=5). The developed method was applied for the determination of selected fungicides in 20 real orange and pear samples. Four different pesticide residues were detected in 10 of these commodities; 20% of the samples contained pesticide residues at a quantifiable level (equal to or above the LOQs) for at least one pesticide residue. The most frequently-detected pesticide residues were: carbendazim, thiabendazole and imazalil-all were below the MRL. The highest concentration found was imazalil at 1175 µg kg(-1) in a pear sample.
DOI: 10.1016/j.talanta.2015.05.055
PubMed: 26452791
Links to Exploration step
pubmed:26452791Le document en format XML
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Fernández-Alba</name><affiliation><nlm:affiliation>Agrifood Campus of International Excellence (ceiA3), European Union Reference Laboratory for Pesticide Residues in Fruit & Vegetables, University of Almeria, Spain. 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Fernández-Alba</name><affiliation><nlm:affiliation>Agrifood Campus of International Excellence (ceiA3), European Union Reference Laboratory for Pesticide Residues in Fruit & Vegetables, University of Almeria, Spain. Electronic address: amadeo@ual.es.</nlm:affiliation></affiliation></author></analytic><series><title level="j">Talanta</title><idno type="eISSN">1873-3573</idno><imprint><date when="2015" type="published">2015</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Adsorption</term><term>Chromatography, Liquid</term><term>Citrus sinensis (chemistry)</term><term>Limit of Detection</term><term>Linear Models</term><term>Nanoparticles (chemistry)</term><term>Nanotubes, Carbon (chemistry)</term><term>Pesticide Residues (analysis)</term><term>Pesticide Residues (chemistry)</term><term>Pesticide Residues (isolation & purification)</term><term>Pyrus (chemistry)</term><term>Safety</term><term>Solid Phase Extraction (economics)</term><term>Solid Phase Extraction (methods)</term><term>Soot (chemistry)</term><term>Tandem Mass Spectrometry</term><term>Time Factors</term><term>Yttrium (chemistry)</term><term>Zirconium (chemistry)</term></keywords><keywords scheme="MESH" type="chemical" qualifier="analysis" xml:lang="en"><term>Pesticide Residues</term></keywords><keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Nanotubes, Carbon</term><term>Pesticide Residues</term><term>Soot</term><term>Yttrium</term><term>Zirconium</term></keywords><keywords scheme="MESH" qualifier="chemistry" xml:lang="en"><term>Citrus sinensis</term><term>Nanoparticles</term><term>Pyrus</term></keywords><keywords scheme="MESH" qualifier="economics" xml:lang="en"><term>Solid Phase Extraction</term></keywords><keywords scheme="MESH" type="chemical" qualifier="isolation & purification" xml:lang="en"><term>Pesticide Residues</term></keywords><keywords scheme="MESH" qualifier="methods" xml:lang="en"><term>Solid Phase Extraction</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Adsorption</term><term>Chromatography, Liquid</term><term>Limit of Detection</term><term>Linear Models</term><term>Safety</term><term>Tandem Mass Spectrometry</term><term>Time Factors</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The use of yttria-stabilized zirconium dioxide nanoparticles as d-SPE clean-up sorbent for a rapid and sensitive liquid chromatography-electrospray ionization-tandem mass spectrometry (LC-ESI-MS/MS) method for the determination of post-harvest fungicides (carbaryl, carbendazim, chlorpropham, diphenylamine, ethoxyquin, flutriafol, imazalil, iprodione, methomyl, myclobutanil, pirimiphos-methyl, prochloraz, pyrimethanil, thiabendazole, thiophanate-methyl and tolclofos-methyl) in orange and pear samples has been evaluated and validated. The sample preparation was a modification of the QuEChERS extraction method using yttria-stabilized zirconium dioxide and multi-walled carbon nanotubes (MWCNTs) nanoparticles as the solid phase extraction (d-SPE) clean-up sorbents prior to injecting the ten-fold diluted extracts into the LC system. By using the yttria-stabilized zirconium dioxide extraction method, more recoveries in the 70-120% range were obtained - thus this method was used for the validation. Quantification was carried out using a matrix-matched calibration curve which was linear in the 1-500 µg kg(-1) range for almost all the pesticides studied. The validated limit of quantification was 10 µg kg(-1) for most of the studied compounds, except chlorpropham, ethoxyquin and thiophanate-methyl. Pesticide recoveries at the 10 and 100 µg kg(-1) concentration levels were satisfactory, with values between 77% and 120% and relative standard deviations (RSD) lower than 10% (n=5). The developed method was applied for the determination of selected fungicides in 20 real orange and pear samples. Four different pesticide residues were detected in 10 of these commodities; 20% of the samples contained pesticide residues at a quantifiable level (equal to or above the LOQs) for at least one pesticide residue. The most frequently-detected pesticide residues were: carbendazim, thiabendazole and imazalil-all were below the MRL. The highest concentration found was imazalil at 1175 µg kg(-1) in a pear sample.</div></front></TEI><pubmed><MedlineCitation Status="MEDLINE" Owner="NLM"><PMID Version="1">26452791</PMID><DateCreated><Year>2015</Year><Month>10</Month><Day>10</Day></DateCreated><DateCompleted><Year>2016</Year><Month>07</Month><Day>20</Day></DateCompleted><DateRevised><Year>2015</Year><Month>10</Month><Day>10</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1873-3573</ISSN><JournalIssue CitedMedium="Internet"><Volume>144</Volume><PubDate><Year>2015</Year><Month>Nov</Month><Day>1</Day></PubDate></JournalIssue><Title>Talanta</Title><ISOAbbreviation>Talanta</ISOAbbreviation></Journal><ArticleTitle>Application of zirconium dioxide nanoparticle sorbent for the clean-up step in post-harvest pesticide residue analysis.</ArticleTitle><Pagination><MedlinePgn>51-61</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1016/j.talanta.2015.05.055</ELocationID><ELocationID EIdType="pii" ValidYN="Y">S0039-9140(15)30012-6</ELocationID><Abstract><AbstractText>The use of yttria-stabilized zirconium dioxide nanoparticles as d-SPE clean-up sorbent for a rapid and sensitive liquid chromatography-electrospray ionization-tandem mass spectrometry (LC-ESI-MS/MS) method for the determination of post-harvest fungicides (carbaryl, carbendazim, chlorpropham, diphenylamine, ethoxyquin, flutriafol, imazalil, iprodione, methomyl, myclobutanil, pirimiphos-methyl, prochloraz, pyrimethanil, thiabendazole, thiophanate-methyl and tolclofos-methyl) in orange and pear samples has been evaluated and validated. The sample preparation was a modification of the QuEChERS extraction method using yttria-stabilized zirconium dioxide and multi-walled carbon nanotubes (MWCNTs) nanoparticles as the solid phase extraction (d-SPE) clean-up sorbents prior to injecting the ten-fold diluted extracts into the LC system. By using the yttria-stabilized zirconium dioxide extraction method, more recoveries in the 70-120% range were obtained - thus this method was used for the validation. Quantification was carried out using a matrix-matched calibration curve which was linear in the 1-500 µg kg(-1) range for almost all the pesticides studied. The validated limit of quantification was 10 µg kg(-1) for most of the studied compounds, except chlorpropham, ethoxyquin and thiophanate-methyl. Pesticide recoveries at the 10 and 100 µg kg(-1) concentration levels were satisfactory, with values between 77% and 120% and relative standard deviations (RSD) lower than 10% (n=5). The developed method was applied for the determination of selected fungicides in 20 real orange and pear samples. Four different pesticide residues were detected in 10 of these commodities; 20% of the samples contained pesticide residues at a quantifiable level (equal to or above the LOQs) for at least one pesticide residue. The most frequently-detected pesticide residues were: carbendazim, thiabendazole and imazalil-all were below the MRL. The highest concentration found was imazalil at 1175 µg kg(-1) in a pear sample.</AbstractText><CopyrightInformation>Copyright © 2015 Elsevier B.V. All rights reserved.</CopyrightInformation></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Uclés</LastName><ForeName>Ana</ForeName><Initials>A</Initials><AffiliationInfo><Affiliation>Agrifood Campus of International Excellence (ceiA3), European Union Reference Laboratory for Pesticide Residues in Fruit & Vegetables, University of Almeria, Spain.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Herrera López</LastName><ForeName>Sonia</ForeName><Initials>S</Initials><AffiliationInfo><Affiliation>Agrifood Campus of International Excellence (ceiA3), European Union Reference Laboratory for Pesticide Residues in Fruit & Vegetables, University of Almeria, Spain.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Dolores Hernando</LastName><ForeName>Maria</ForeName><Initials>M</Initials><AffiliationInfo><Affiliation>National Institute for Agriculture and Food Research and Technology, INIA, 28040 Madrid, Spain.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Rosal</LastName><ForeName>Roberto</ForeName><Initials>R</Initials><AffiliationInfo><Affiliation>Department of Chemical Engineering, University of Alcalá, 28771 Alcalá de Henares, Spain.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Ferrer</LastName><ForeName>Carmen</ForeName><Initials>C</Initials><AffiliationInfo><Affiliation>Agrifood Campus of International Excellence (ceiA3), European Union Reference Laboratory for Pesticide Residues in Fruit & Vegetables, University of Almeria, Spain.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Fernández-Alba</LastName><ForeName>Amadeo R</ForeName><Initials>AR</Initials><AffiliationInfo><Affiliation>Agrifood Campus of International Excellence (ceiA3), European Union Reference Laboratory for Pesticide Residues in Fruit & Vegetables, University of Almeria, Spain. Electronic address: amadeo@ual.es.</Affiliation></AffiliationInfo></Author></AuthorList><Language>ENG</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType><PublicationType UI="D013485">Research Support, Non-U.S. Gov't</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2015</Year><Month>May</Month><Day>30</Day></ArticleDate></Article><MedlineJournalInfo><Country>Netherlands</Country><MedlineTA>Talanta</MedlineTA><NlmUniqueID>2984816R</NlmUniqueID><ISSNLinking>0039-9140</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D037742">Nanotubes, Carbon</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D010573">Pesticide Residues</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D053260">Soot</NameOfSubstance></Chemical><Chemical><RegistryNumber>1314-36-9</RegistryNumber><NameOfSubstance UI="C091417">yttria</NameOfSubstance></Chemical><Chemical><RegistryNumber>58784XQC3Y</RegistryNumber><NameOfSubstance UI="D015019">Yttrium</NameOfSubstance></Chemical><Chemical><RegistryNumber>C6V6S92N3C</RegistryNumber><NameOfSubstance UI="D015040">Zirconium</NameOfSubstance></Chemical><Chemical><RegistryNumber>S38N85C5G0</RegistryNumber><NameOfSubstance UI="C028541">zirconium oxide</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName UI="D000327" MajorTopicYN="N">Adsorption</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D002853" MajorTopicYN="N">Chromatography, Liquid</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D032084" MajorTopicYN="N">Citrus sinensis</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D057230" MajorTopicYN="N">Limit of Detection</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D016014" MajorTopicYN="N">Linear Models</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D053758" MajorTopicYN="N">Nanoparticles</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D037742" MajorTopicYN="N">Nanotubes, Carbon</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D010573" MajorTopicYN="N">Pesticide Residues</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="N">analysis</QualifierName><QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName><QualifierName UI="Q000302" MajorTopicYN="Y">isolation & purification</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D031989" MajorTopicYN="N">Pyrus</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D012449" MajorTopicYN="N">Safety</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D052616" MajorTopicYN="N">Solid Phase Extraction</DescriptorName><QualifierName UI="Q000191" MajorTopicYN="N">economics</QualifierName><QualifierName UI="Q000379" MajorTopicYN="Y">methods</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D053260" MajorTopicYN="N">Soot</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D053719" MajorTopicYN="N">Tandem Mass Spectrometry</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D013997" MajorTopicYN="N">Time Factors</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D015019" MajorTopicYN="N">Yttrium</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D015040" MajorTopicYN="N">Zirconium</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName></MeshHeading></MeshHeadingList><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">Clean-up</Keyword><Keyword MajorTopicYN="N">LC–MS/MS</Keyword><Keyword MajorTopicYN="N">Pesticide residues</Keyword><Keyword MajorTopicYN="N">Post-harvest pesticides</Keyword><Keyword MajorTopicYN="N">Recoveries</Keyword><Keyword MajorTopicYN="N">Yttria-stabilized zirconium dioxide</Keyword></KeywordList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2015</Year><Month>3</Month><Day>5</Day></PubMedPubDate><PubMedPubDate PubStatus="revised"><Year>2015</Year><Month>5</Month><Day>20</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2015</Year><Month>5</Month><Day>23</Day></PubMedPubDate><PubMedPubDate 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