NickelMaghrebV1, PubMed, Corpus, bibRecord, 000053

Bis[tris(propane-1,3-diamine-κ(2) N,N')-nickel(II)] di-aqua-bis(propane-1,3-di-amine-κ(2) N,N')nickel(II) hexa-bromide dihydrate.

Identifieur interne : 000053 ( PubMed/Corpus ); précédent : 000052; suivant : 000054

Bis[tris(propane-1,3-diamine-κ(2) N,N')-nickel(II)] di-aqua-bis(propane-1,3-di-amine-κ(2) N,N')nickel(II) hexa-bromide dihydrate.

Auteurs : Aymen Yangui ; Walid Rekik ; Slim Elleuch ; Younes Abid

Source :

Acta crystallographica. Section E, Structure reports online ; 2014.

RBID : pubmed:24940210

Abstract

In the title compound, [Ni(C3H10N2)3]2[Ni(C3H10N2)2(H2O)2]Br6·2H2O, one Ni(2+) cation, located on an inversion centre, is coordinated by four N atoms from two ligands and by two water O atoms. The other Ni(2+) cation, located in a general position, is coordinated by six N atoms from three ligands. In both cases, the Ni(2+) cation has an octa-hedral coordination environment. The overall structural cohesion is ensured by three types of hydrogen bonds, N-H⋯Br, O-H⋯Br and O-H⋯O, which connect the two types of complex cations, the bromide counter-anions and the lattice water molecules into a three-dimensional network.

DOI: 10.1107/S1600536814011052
PubMed: 24940210

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pubmed:24940210

Le document en format XML

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<author><name sortKey="Yangui, Aymen" sort="Yangui, Aymen" uniqKey="Yangui A" first="Aymen" last="Yangui">Aymen Yangui</name>
<affiliation><nlm:affiliation>Laboratoire de Physique Appliquée, Faculté des Sciences de Sfax, Université de Sfax, BP 1171, 3018 Sfax, Tunisia.</nlm:affiliation>
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<author><name sortKey="Rekik, Walid" sort="Rekik, Walid" uniqKey="Rekik W" first="Walid" last="Rekik">Walid Rekik</name>
<affiliation><nlm:affiliation>Laboratoire Physico-Chimie de l'Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, BP 1171, 3018 Sfax, Tunisia.</nlm:affiliation>
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<author><name sortKey="Elleuch, Slim" sort="Elleuch, Slim" uniqKey="Elleuch S" first="Slim" last="Elleuch">Slim Elleuch</name>
<affiliation><nlm:affiliation>Laboratoire de Physique Appliquée, Faculté des Sciences de Sfax, Université de Sfax, BP 1171, 3018 Sfax, Tunisia.</nlm:affiliation>
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<author><name sortKey="Abid, Younes" sort="Abid, Younes" uniqKey="Abid Y" first="Younes" last="Abid">Younes Abid</name>
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<front><div type="abstract" xml:lang="en">In the title compound, [Ni(C3H10N2)3]2[Ni(C3H10N2)2(H2O)2]Br6·2H2O, one Ni(2+) cation, located on an inversion centre, is coordinated by four N atoms from two ligands and by two water O atoms. The other Ni(2+) cation, located in a general position, is coordinated by six N atoms from three ligands. In both cases, the Ni(2+) cation has an octa-hedral coordination environment. The overall structural cohesion is ensured by three types of hydrogen bonds, N-H⋯Br, O-H⋯Br and O-H⋯O, which connect the two types of complex cations, the bromide counter-anions and the lattice water molecules into a three-dimensional network.</div>
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Bis[tris(propane-1,3-diamine-κ(2) N,N')-nickel(II)] di-aqua-bis(propane-1,3-di-amine-κ(2) N,N')nickel(II) hexa-bromide dihydrate.

Bis[tris(propane-1,3-diamine-κ(2) N,N')-nickel(II)] di-aqua-bis(propane-1,3-di-amine-κ(2) N,N')nickel(II) hexa-bromide dihydrate.

Source :

Abstract

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