NickelMaghrebV1, PascalFrancis, Curation, bibRecord, 000563

Thermal effects of a laser beam on the electrodeposition of Ni-P alloys

Identifieur interne : 000563 ( PascalFrancis/Curation ); précédent : 000562; suivant : 000564

Thermal effects of a laser beam on the electrodeposition of Ni-P alloys

Auteurs : I. Zouari [France, Tunisie] ; A. Bellagi [Tunisie] ; F. Lapicque [France]

Source :

Journal of applied electrochemistry [ 0021-891X ] ; 1998.

RBID : Pascal:98-0109448

Descripteurs français

Pascal (Inist)
- Dépôt électrolytique, Revêtement métallique, Densité courant, Effet température, Microstructure, Laser pulsé, Laser continu, Hypophosphite, Composition chimique, Alliage base nickel, Traitement surface, Acétate, Phosphore alliage, Alliage NiP, Ni P.

English descriptors

KwdEn :
- Acetate, CW laser, Chemical composition, Current density, Electrodeposition, Hypophosphites, Metal coating, Microstructure, Nickel base alloys, Phosphorus alloys, Pulsed laser, Surface treatment, Temperature effect.

Abstract

The paper deals with the effects of an incident laser beam on electrodeposition of Ni-P alloys from dilute acetate solutions. The kinetics of separate reductions of Ni²⁺ and H₂PO^-₂ species were first investigated by linear sweep voltammetry, varying the hypophosphite concentration and the solution temperature: comparison of the kinetically limited current densities of the two reductions suggested that increasing temperature might reduce the significance of P codeposition. This tendency was confirmed by deposition runs carried out at controlled current. Deposition performance was discussed in terms of faradaic yield and deposit properties, namely P content together with the aspect and the structure of the alloys. Use of a continuous or pulsed laser beam was shown to reduce the P content in the deposit at high current densities; in some cases, amorphous structures were replaced by more crystalline forms with assistance of a laser beam.

A01	`01`	`1`		`@0 0021-891X`
A02	`01`			`@0 JAELBJ`
A03		`1`		`@0 J. appl. electrochem.`
A05				`@2 28`
A06				`@2 1`
A08	`01`	`1`	`ENG`	`@1 Thermal effects of a laser beam on the electrodeposition of Ni-P alloys`
A11	`01`	`1`		`@1 ZOUARI (I.)`
A11	`02`	`1`		`@1 BELLAGI (A.)`
A11	`03`	`1`		`@1 LAPICQUE (F.)`
A14	`01`			`@1 Laboratoire des Sciences du Génie Chimique, CNRS-ENSIC-INPL, PO Box 451 @2 54001 Nancy @3 FRA @Z 1 aut. @Z 3 aut.`
A14	`02`			`@1 Ecole Nationale d'Ingénieurs de Gabès, Route de Medenine @2 6029 Gabès @3 TUN @Z 1 aut.`
A14	`03`			`@1 Ecole Nationale d'Ingénieurs de Monastir, Route de Kairouan @2 5000 Monastir @3 TUN @Z 2 aut.`
A20				`@1 80-88`
A21				`@1 1998`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 15602 @5 354000077818270110`
A44				`@0 0000 @1 © 1998 INIST-CNRS. All rights reserved.`
A45				`@0 24 ref.`
A47	`01`	`1`		`@0 98-0109448`
A60				`@1 P`
A61				`@0 A`
A64		`1`		`@0 Journal of applied electrochemistry`
A66	`01`			`@0 GBR`
C01	`01`		`ENG`	@0 The paper deals with the effects of an incident laser beam on electrodeposition of Ni-P alloys from dilute acetate solutions. The kinetics of separate reductions of Ni²⁺ and H₂PO^-₂ species were first investigated by linear sweep voltammetry, varying the hypophosphite concentration and the solution temperature: comparison of the kinetically limited current densities of the two reductions suggested that increasing temperature might reduce the significance of P codeposition. This tendency was confirmed by deposition runs carried out at controlled current. Deposition performance was discussed in terms of faradaic yield and deposit properties, namely P content together with the aspect and the structure of the alloys. Use of a continuous or pulsed laser beam was shown to reduce the P content in the deposit at high current densities; in some cases, amorphous structures were replaced by more crystalline forms with assistance of a laser beam.
C02	`01`	`X`		`@0 001D11C06D`
C02	`02`	`X`		`@0 240`
C03	`01`	`X`	`FRE`	`@0 Dépôt électrolytique @5 55`
C03	`01`	`X`	`ENG`	`@0 Electrodeposition @5 55`
C03	`01`	`X`	`GER`	`@0 Elektroplattieren @5 55`
C03	`01`	`X`	`SPA`	`@0 Depósito electrolítico @5 55`
C03	`02`	`X`	`FRE`	`@0 Revêtement métallique @5 56`
C03	`02`	`X`	`ENG`	`@0 Metal coating @5 56`
C03	`02`	`X`	`GER`	`@0 Metallischer Ueberzug @5 56`
C03	`02`	`X`	`SPA`	`@0 Revestimiento metálico @5 56`
C03	`03`	`X`	`FRE`	`@0 Densité courant @5 57`
C03	`03`	`X`	`ENG`	`@0 Current density @5 57`
C03	`03`	`X`	`GER`	`@0 Stromdichte @5 57`
C03	`03`	`X`	`SPA`	`@0 Densidad corriente @5 57`
C03	`04`	`X`	`FRE`	`@0 Effet température @5 58`
C03	`04`	`X`	`ENG`	`@0 Temperature effect @5 58`
C03	`04`	`X`	`GER`	`@0 Temperatureinfluss @5 58`
C03	`04`	`X`	`SPA`	`@0 Efecto temperatura @5 58`
C03	`05`	`X`	`FRE`	`@0 Microstructure @5 59`
C03	`05`	`X`	`ENG`	`@0 Microstructure @5 59`
C03	`05`	`X`	`GER`	`@0 Mikrogefuege @5 59`
C03	`05`	`X`	`SPA`	`@0 Microestructura @5 59`
C03	`06`	`X`	`FRE`	`@0 Laser pulsé @5 60`
C03	`06`	`X`	`ENG`	`@0 Pulsed laser @5 60`
C03	`06`	`X`	`GER`	`@0 Impulslaser @5 60`
C03	`06`	`X`	`SPA`	`@0 Láser pulsado @5 60`
C03	`07`	`X`	`FRE`	`@0 Laser continu @5 61`
C03	`07`	`X`	`ENG`	`@0 CW laser @5 61`
C03	`07`	`X`	`SPA`	`@0 Laser continuo @5 61`
C03	`08`	`X`	`FRE`	`@0 Hypophosphite @2 NA @5 62`
C03	`08`	`X`	`ENG`	`@0 Hypophosphites @2 NA @5 62`
C03	`08`	`X`	`SPA`	`@0 Hipofosfito @2 NA @5 62`
C03	`09`	`X`	`FRE`	`@0 Composition chimique @5 63`
C03	`09`	`X`	`ENG`	`@0 Chemical composition @5 63`
C03	`09`	`X`	`GER`	`@0 Chemische Zusammensetzung @5 63`
C03	`09`	`X`	`SPA`	`@0 Composición química @5 63`
C03	`10`	`3`	`FRE`	`@0 Alliage base nickel @1 SEC @2 NK @5 65`
C03	`10`	`3`	`ENG`	`@0 Nickel base alloys @1 SEC @2 NK @5 65`
C03	`11`	`X`	`FRE`	`@0 Traitement surface @5 74`
C03	`11`	`X`	`ENG`	`@0 Surface treatment @5 74`
C03	`11`	`X`	`GER`	`@0 Oberflaechenbehandlung @5 74`
C03	`11`	`X`	`SPA`	`@0 Tratamiento superficie @5 74`
C03	`12`	`X`	`FRE`	`@0 Acétate @2 NK @5 75`
C03	`12`	`X`	`ENG`	`@0 Acetate @2 NK @5 75`
C03	`12`	`X`	`SPA`	`@0 Acetato @2 NK @5 75`
C03	`13`	`3`	`FRE`	`@0 Phosphore alliage @5 76`
C03	`13`	`3`	`ENG`	`@0 Phosphorus alloys @5 76`
C03	`14`	`X`	`FRE`	`@0 Alliage NiP @2 NK @4 INC @5 81`
C03	`15`	`X`	`FRE`	`@0 Ni P @4 INC @5 85`
N21				`@1 068`

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Le document en format XML

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<series><title level="j" type="main">Journal of applied electrochemistry</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Acetate</term>
<term>CW laser</term>
<term>Chemical composition</term>
<term>Current density</term>
<term>Electrodeposition</term>
<term>Hypophosphites</term>
<term>Metal coating</term>
<term>Microstructure</term>
<term>Nickel base alloys</term>
<term>Phosphorus alloys</term>
<term>Pulsed laser</term>
<term>Surface treatment</term>
<term>Temperature effect</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Dépôt électrolytique</term>
<term>Revêtement métallique</term>
<term>Densité courant</term>
<term>Effet température</term>
<term>Microstructure</term>
<term>Laser pulsé</term>
<term>Laser continu</term>
<term>Hypophosphite</term>
<term>Composition chimique</term>
<term>Alliage base nickel</term>
<term>Traitement surface</term>
<term>Acétate</term>
<term>Phosphore alliage</term>
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<front><div type="abstract" xml:lang="en">The paper deals with the effects of an incident laser beam on electrodeposition of Ni-P alloys from dilute acetate solutions. The kinetics of separate reductions of Ni<sup>2+</sup>
 and H<sub>2</sub>
PO<sup>-</sup>
<sub>2</sub>
 species were first investigated by linear sweep voltammetry, varying the hypophosphite concentration and the solution temperature: comparison of the kinetically limited current densities of the two reductions suggested that increasing temperature might reduce the significance of P codeposition. This tendency was confirmed by deposition runs carried out at controlled current. Deposition performance was discussed in terms of faradaic yield and deposit properties, namely P content together with the aspect and the structure of the alloys. Use of a continuous or pulsed laser beam was shown to reduce the P content in the deposit at high current densities; in some cases, amorphous structures were replaced by more crystalline forms with assistance of a laser beam.</div>
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<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Ecole Nationale d'Ingénieurs de Gabès, Route de Medenine</s1>
<s2>6029 Gabès</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
</fA14>
<fA14 i1="03"><s1>Ecole Nationale d'Ingénieurs de Monastir, Route de Kairouan</s1>
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<s3>TUN</s3>
<sZ>2 aut.</sZ>
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<fC01 i1="01" l="ENG"><s0>The paper deals with the effects of an incident laser beam on electrodeposition of Ni-P alloys from dilute acetate solutions. The kinetics of separate reductions of Ni<sup>2+</sup>
 and H<sub>2</sub>
PO<sup>-</sup>
<sub>2</sub>
 species were first investigated by linear sweep voltammetry, varying the hypophosphite concentration and the solution temperature: comparison of the kinetically limited current densities of the two reductions suggested that increasing temperature might reduce the significance of P codeposition. This tendency was confirmed by deposition runs carried out at controlled current. Deposition performance was discussed in terms of faradaic yield and deposit properties, namely P content together with the aspect and the structure of the alloys. Use of a continuous or pulsed laser beam was shown to reduce the P content in the deposit at high current densities; in some cases, amorphous structures were replaced by more crystalline forms with assistance of a laser beam.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001D11C06D</s0>
</fC02>
<fC02 i1="02" i2="X"><s0>240</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Dépôt électrolytique</s0>
<s5>55</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Electrodeposition</s0>
<s5>55</s5>
</fC03>
<fC03 i1="01" i2="X" l="GER"><s0>Elektroplattieren</s0>
<s5>55</s5>
</fC03>
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<s5>55</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Revêtement métallique</s0>
<s5>56</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Metal coating</s0>
<s5>56</s5>
</fC03>
<fC03 i1="02" i2="X" l="GER"><s0>Metallischer Ueberzug</s0>
<s5>56</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Revestimiento metálico</s0>
<s5>56</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Densité courant</s0>
<s5>57</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Current density</s0>
<s5>57</s5>
</fC03>
<fC03 i1="03" i2="X" l="GER"><s0>Stromdichte</s0>
<s5>57</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Densidad corriente</s0>
<s5>57</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Effet température</s0>
<s5>58</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Temperature effect</s0>
<s5>58</s5>
</fC03>
<fC03 i1="04" i2="X" l="GER"><s0>Temperatureinfluss</s0>
<s5>58</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Efecto temperatura</s0>
<s5>58</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Microstructure</s0>
<s5>59</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Microstructure</s0>
<s5>59</s5>
</fC03>
<fC03 i1="05" i2="X" l="GER"><s0>Mikrogefuege</s0>
<s5>59</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Microestructura</s0>
<s5>59</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Laser pulsé</s0>
<s5>60</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Pulsed laser</s0>
<s5>60</s5>
</fC03>
<fC03 i1="06" i2="X" l="GER"><s0>Impulslaser</s0>
<s5>60</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Láser pulsado</s0>
<s5>60</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Laser continu</s0>
<s5>61</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>CW laser</s0>
<s5>61</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Laser continuo</s0>
<s5>61</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Hypophosphite</s0>
<s2>NA</s2>
<s5>62</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Hypophosphites</s0>
<s2>NA</s2>
<s5>62</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Hipofosfito</s0>
<s2>NA</s2>
<s5>62</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Composition chimique</s0>
<s5>63</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Chemical composition</s0>
<s5>63</s5>
</fC03>
<fC03 i1="09" i2="X" l="GER"><s0>Chemische Zusammensetzung</s0>
<s5>63</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Composición química</s0>
<s5>63</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Alliage base nickel</s0>
<s1>SEC</s1>
<s2>NK</s2>
<s5>65</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Nickel base alloys</s0>
<s1>SEC</s1>
<s2>NK</s2>
<s5>65</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Traitement surface</s0>
<s5>74</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Surface treatment</s0>
<s5>74</s5>
</fC03>
<fC03 i1="11" i2="X" l="GER"><s0>Oberflaechenbehandlung</s0>
<s5>74</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Tratamiento superficie</s0>
<s5>74</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Acétate</s0>
<s2>NK</s2>
<s5>75</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Acetate</s0>
<s2>NK</s2>
<s5>75</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Acetato</s0>
<s2>NK</s2>
<s5>75</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>Phosphore alliage</s0>
<s5>76</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG"><s0>Phosphorus alloys</s0>
<s5>76</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE"><s0>Alliage NiP</s0>
<s2>NK</s2>
<s4>INC</s4>
<s5>81</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Ni P</s0>
<s4>INC</s4>
<s5>85</s5>
</fC03>
<fN21><s1>068</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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	Serveur d'exploration sur le nickel au Maghreb
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Thermal effects of a laser beam on the electrodeposition of Ni-P alloys

Thermal effects of a laser beam on the electrodeposition of Ni-P alloys

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