Thermodynamics properties of NiCuP4O12
Identifieur interne : 000236 ( PascalFrancis/Corpus ); précédent : 000235; suivant : 000237Thermodynamics properties of NiCuP4O12
Auteurs : M. Belaiche ; M. Bakhache ; M. Benhammou ; K. El-Mabrouke ; M. BousminaSource :
- Physica. E, low-dimentional systems and nanostructures [ 1386-9477 ] ; 2008.
Descripteurs français
- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
The variation of magnetic susceptibility and heat capacity with temperature for the bimetallic nickel Ni(II)-copper Cu(II) cyclo-tetrametaphosphates (CuNiP4O12) has been examined. The complex has a structure of quasi-one-dimensional alternate spins chains of Ni(II) and Cu(II) that exhibits a three-dimensional magnetic ordering at approximately 13.5 K. The compound is characterized by a ferromagnetic intrachain constant JF = 4.05K, with a significant effect of single ion anisotropy D = 9.70K. The chains are weakly coupled antiferromagnetically with an interchain exchange constant of 2zAFJAF = -1.125 K.
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Format Inist (serveur)
NO : | PASCAL 08-0117706 INIST |
---|---|
ET : | Thermodynamics properties of NiCuP4O12 |
AU : | BELAICHE (M.); BAKHACHE (M.); BENHAMMOU (M.); EL-MABROUKE (K.); BOUSMINA (M.) |
AF : | Laboratory of Magnetism, Magnetic Materials, Micro-waves and Ceramics, Ecole Normale Supérieure de Rabat, BP 9235/Ocean, Rabat/Maroc (1 aut., 2 aut., 3 aut.); Hassan II Academy of Science and Technology/Rabat/Maroc (1 aut., 5 aut.); Canada Research Chair on Polymer Physics and Nanomaterials, Department of Chemical Engineering (CREPEC), Laval University/Sainte-Foy, Que., GIK 7P4/Canada (4 aut., 5 aut.) |
DT : | Publication en série; Niveau analytique |
SO : | Physica. E, low-dimentional systems and nanostructures; ISSN 1386-9477; Pays-Bas; Da. 2008; Vol. 40; No. 3; Pp. 574-578; Bibl. 23 ref. |
LA : | Anglais |
EA : | The variation of magnetic susceptibility and heat capacity with temperature for the bimetallic nickel Ni(II)-copper Cu(II) cyclo-tetrametaphosphates (CuNiP4O12) has been examined. The complex has a structure of quasi-one-dimensional alternate spins chains of Ni(II) and Cu(II) that exhibits a three-dimensional magnetic ordering at approximately 13.5 K. The compound is characterized by a ferromagnetic intrachain constant JF = 4.05K, with a significant effect of single ion anisotropy D = 9.70K. The chains are weakly coupled antiferromagnetically with an interchain exchange constant of 2zAFJAF = -1.125 K. |
CC : | 001B70E40C |
FD : | Propriété thermodynamique; Susceptibilité magnétique; Chaleur massique; Chaîne spin; Ordre magnétique; Anisotropie; Interaction échange; Ferromagnétisme; Antiferromagnétisme; Modèle chaîne alternée; CuNiP4O12; Phosphate de cuivre et de nickel |
ED : | Thermodynamic properties; Magnetic susceptibility; Specific heat; Spin chain; Magnetic ordering; Anisotropy; Exchange interactions; Ferromagnetism; Antiferromagnetism; Alternated chains model |
LO : | INIST-145E.354000161884020250 |
ID : | 08-0117706 |
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Pascal:08-0117706Le document en format XML
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<author><name sortKey="Belaiche, M" sort="Belaiche, M" uniqKey="Belaiche M" first="M." last="Belaiche">M. Belaiche</name>
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<sZ>1 aut.</sZ>
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<sZ>5 aut.</sZ>
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<author><name sortKey="Bakhache, M" sort="Bakhache, M" uniqKey="Bakhache M" first="M." last="Bakhache">M. Bakhache</name>
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<s3>MAR</s3>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Alternated chains model</term>
<term>Anisotropy</term>
<term>Antiferromagnetism</term>
<term>Exchange interactions</term>
<term>Ferromagnetism</term>
<term>Magnetic ordering</term>
<term>Magnetic susceptibility</term>
<term>Specific heat</term>
<term>Spin chain</term>
<term>Thermodynamic properties</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Propriété thermodynamique</term>
<term>Susceptibilité magnétique</term>
<term>Chaleur massique</term>
<term>Chaîne spin</term>
<term>Ordre magnétique</term>
<term>Anisotropie</term>
<term>Interaction échange</term>
<term>Ferromagnétisme</term>
<term>Antiferromagnétisme</term>
<term>Modèle chaîne alternée</term>
<term>CuNiP4O12</term>
<term>Phosphate de cuivre et de nickel</term>
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<front><div type="abstract" xml:lang="en">The variation of magnetic susceptibility and heat capacity with temperature for the bimetallic nickel Ni(II)-copper Cu(II) cyclo-tetrametaphosphates (CuNiP<sub>4</sub>
O<sub>12</sub>
) has been examined. The complex has a structure of quasi-one-dimensional alternate spins chains of Ni(II) and Cu(II) that exhibits a three-dimensional magnetic ordering at approximately 13.5 K. The compound is characterized by a ferromagnetic intrachain constant J<sub>F</sub>
= 4.05K, with a significant effect of single ion anisotropy D = 9.70K. The chains are weakly coupled antiferromagnetically with an interchain exchange constant of 2z<sub>AF</sub>
J<sub>AF</sub>
= -1.125 K.</div>
</front>
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<fA11 i1="01" i2="1"><s1>BELAICHE (M.)</s1>
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<fA14 i1="01"><s1>Laboratory of Magnetism, Magnetic Materials, Micro-waves and Ceramics, Ecole Normale Supérieure de Rabat, BP 9235</s1>
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<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</fA14>
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<s2>Rabat</s2>
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<sZ>5 aut.</sZ>
</fA14>
<fA14 i1="03"><s1>Canada Research Chair on Polymer Physics and Nanomaterials, Department of Chemical Engineering (CREPEC), Laval University</s1>
<s2>Sainte-Foy, Que., GIK 7P4</s2>
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</fA66>
<fC01 i1="01" l="ENG"><s0>The variation of magnetic susceptibility and heat capacity with temperature for the bimetallic nickel Ni(II)-copper Cu(II) cyclo-tetrametaphosphates (CuNiP<sub>4</sub>
O<sub>12</sub>
) has been examined. The complex has a structure of quasi-one-dimensional alternate spins chains of Ni(II) and Cu(II) that exhibits a three-dimensional magnetic ordering at approximately 13.5 K. The compound is characterized by a ferromagnetic intrachain constant J<sub>F</sub>
= 4.05K, with a significant effect of single ion anisotropy D = 9.70K. The chains are weakly coupled antiferromagnetically with an interchain exchange constant of 2z<sub>AF</sub>
J<sub>AF</sub>
= -1.125 K.</s0>
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<fC02 i1="01" i2="3"><s0>001B70E40C</s0>
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<fC03 i1="01" i2="3" l="FRE"><s0>Propriété thermodynamique</s0>
<s5>02</s5>
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<fC03 i1="01" i2="3" l="ENG"><s0>Thermodynamic properties</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Susceptibilité magnétique</s0>
<s5>03</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>Magnetic susceptibility</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Chaleur massique</s0>
<s5>04</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>Specific heat</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Chaîne spin</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Spin chain</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Ordre magnétique</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Magnetic ordering</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Anisotropie</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Anisotropy</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Interaction échange</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Exchange interactions</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>Ferromagnétisme</s0>
<s5>10</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG"><s0>Ferromagnetism</s0>
<s5>10</s5>
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<s5>11</s5>
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<fC03 i1="09" i2="3" l="ENG"><s0>Antiferromagnetism</s0>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Modèle chaîne alternée</s0>
<s5>12</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Alternated chains model</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>CuNiP4O12</s0>
<s4>INC</s4>
<s5>63</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>Phosphate de cuivre et de nickel</s0>
<s4>INC</s4>
<s5>64</s5>
</fC03>
<fN21><s1>063</s1>
</fN21>
</pA>
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<server><NO>PASCAL 08-0117706 INIST</NO>
<ET>Thermodynamics properties of NiCuP<sub>4</sub>
O<sub>12</sub>
</ET>
<AU>BELAICHE (M.); BAKHACHE (M.); BENHAMMOU (M.); EL-MABROUKE (K.); BOUSMINA (M.)</AU>
<AF>Laboratory of Magnetism, Magnetic Materials, Micro-waves and Ceramics, Ecole Normale Supérieure de Rabat, BP 9235/Ocean, Rabat/Maroc (1 aut., 2 aut., 3 aut.); Hassan II Academy of Science and Technology/Rabat/Maroc (1 aut., 5 aut.); Canada Research Chair on Polymer Physics and Nanomaterials, Department of Chemical Engineering (CREPEC), Laval University/Sainte-Foy, Que., GIK 7P4/Canada (4 aut., 5 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Physica. E, low-dimentional systems and nanostructures; ISSN 1386-9477; Pays-Bas; Da. 2008; Vol. 40; No. 3; Pp. 574-578; Bibl. 23 ref.</SO>
<LA>Anglais</LA>
<EA>The variation of magnetic susceptibility and heat capacity with temperature for the bimetallic nickel Ni(II)-copper Cu(II) cyclo-tetrametaphosphates (CuNiP<sub>4</sub>
O<sub>12</sub>
) has been examined. The complex has a structure of quasi-one-dimensional alternate spins chains of Ni(II) and Cu(II) that exhibits a three-dimensional magnetic ordering at approximately 13.5 K. The compound is characterized by a ferromagnetic intrachain constant J<sub>F</sub>
= 4.05K, with a significant effect of single ion anisotropy D = 9.70K. The chains are weakly coupled antiferromagnetically with an interchain exchange constant of 2z<sub>AF</sub>
J<sub>AF</sub>
= -1.125 K.</EA>
<CC>001B70E40C</CC>
<FD>Propriété thermodynamique; Susceptibilité magnétique; Chaleur massique; Chaîne spin; Ordre magnétique; Anisotropie; Interaction échange; Ferromagnétisme; Antiferromagnétisme; Modèle chaîne alternée; CuNiP4O12; Phosphate de cuivre et de nickel</FD>
<ED>Thermodynamic properties; Magnetic susceptibility; Specific heat; Spin chain; Magnetic ordering; Anisotropy; Exchange interactions; Ferromagnetism; Antiferromagnetism; Alternated chains model</ED>
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