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Thermodynamics properties of NiCuP4O12

Identifieur interne : 000236 ( PascalFrancis/Corpus ); précédent : 000235; suivant : 000237

Thermodynamics properties of NiCuP4O12

Auteurs : M. Belaiche ; M. Bakhache ; M. Benhammou ; K. El-Mabrouke ; M. Bousmina

Source :

RBID : Pascal:08-0117706

Descripteurs français

English descriptors

Abstract

The variation of magnetic susceptibility and heat capacity with temperature for the bimetallic nickel Ni(II)-copper Cu(II) cyclo-tetrametaphosphates (CuNiP4O12) has been examined. The complex has a structure of quasi-one-dimensional alternate spins chains of Ni(II) and Cu(II) that exhibits a three-dimensional magnetic ordering at approximately 13.5 K. The compound is characterized by a ferromagnetic intrachain constant JF = 4.05K, with a significant effect of single ion anisotropy D = 9.70K. The chains are weakly coupled antiferromagnetically with an interchain exchange constant of 2zAFJAF = -1.125 K.

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Pour connaître la documentation sur le format Inist Standard.

pA  
A01 01  1    @0 1386-9477
A03   1    @0 Physica ( E) low-dimens. syst. nanostrut.
A05       @2 40
A06       @2 3
A08 01  1  ENG  @1 Thermodynamics properties of NiCuP4O12
A11 01  1    @1 BELAICHE (M.)
A11 02  1    @1 BAKHACHE (M.)
A11 03  1    @1 BENHAMMOU (M.)
A11 04  1    @1 EL-MABROUKE (K.)
A11 05  1    @1 BOUSMINA (M.)
A14 01      @1 Laboratory of Magnetism, Magnetic Materials, Micro-waves and Ceramics, Ecole Normale Supérieure de Rabat, BP 9235 @2 Ocean, Rabat @3 MAR @Z 1 aut. @Z 2 aut. @Z 3 aut.
A14 02      @1 Hassan II Academy of Science and Technology @2 Rabat @3 MAR @Z 1 aut. @Z 5 aut.
A14 03      @1 Canada Research Chair on Polymer Physics and Nanomaterials, Department of Chemical Engineering (CREPEC), Laval University @2 Sainte-Foy, Que., GIK 7P4 @3 CAN @Z 4 aut. @Z 5 aut.
A20       @1 574-578
A21       @1 2008
A23 01      @0 ENG
A43 01      @1 INIST @2 145E @5 354000161884020250
A44       @0 0000 @1 © 2008 INIST-CNRS. All rights reserved.
A45       @0 23 ref.
A47 01  1    @0 08-0117706
A60       @1 P
A61       @0 A
A64 01  1    @0 Physica. E, low-dimentional systems and nanostructures
A66 01      @0 NLD
C01 01    ENG  @0 The variation of magnetic susceptibility and heat capacity with temperature for the bimetallic nickel Ni(II)-copper Cu(II) cyclo-tetrametaphosphates (CuNiP4O12) has been examined. The complex has a structure of quasi-one-dimensional alternate spins chains of Ni(II) and Cu(II) that exhibits a three-dimensional magnetic ordering at approximately 13.5 K. The compound is characterized by a ferromagnetic intrachain constant JF = 4.05K, with a significant effect of single ion anisotropy D = 9.70K. The chains are weakly coupled antiferromagnetically with an interchain exchange constant of 2zAFJAF = -1.125 K.
C02 01  3    @0 001B70E40C
C03 01  3  FRE  @0 Propriété thermodynamique @5 02
C03 01  3  ENG  @0 Thermodynamic properties @5 02
C03 02  3  FRE  @0 Susceptibilité magnétique @5 03
C03 02  3  ENG  @0 Magnetic susceptibility @5 03
C03 03  3  FRE  @0 Chaleur massique @5 04
C03 03  3  ENG  @0 Specific heat @5 04
C03 04  3  FRE  @0 Chaîne spin @5 05
C03 04  3  ENG  @0 Spin chain @5 05
C03 05  3  FRE  @0 Ordre magnétique @5 06
C03 05  3  ENG  @0 Magnetic ordering @5 06
C03 06  3  FRE  @0 Anisotropie @5 07
C03 06  3  ENG  @0 Anisotropy @5 07
C03 07  3  FRE  @0 Interaction échange @5 08
C03 07  3  ENG  @0 Exchange interactions @5 08
C03 08  3  FRE  @0 Ferromagnétisme @5 10
C03 08  3  ENG  @0 Ferromagnetism @5 10
C03 09  3  FRE  @0 Antiferromagnétisme @5 11
C03 09  3  ENG  @0 Antiferromagnetism @5 11
C03 10  3  FRE  @0 Modèle chaîne alternée @5 12
C03 10  3  ENG  @0 Alternated chains model @5 12
C03 11  3  FRE  @0 CuNiP4O12 @4 INC @5 63
C03 12  3  FRE  @0 Phosphate de cuivre et de nickel @4 INC @5 64
N21       @1 063

Format Inist (serveur)

NO : PASCAL 08-0117706 INIST
ET : Thermodynamics properties of NiCuP4O12
AU : BELAICHE (M.); BAKHACHE (M.); BENHAMMOU (M.); EL-MABROUKE (K.); BOUSMINA (M.)
AF : Laboratory of Magnetism, Magnetic Materials, Micro-waves and Ceramics, Ecole Normale Supérieure de Rabat, BP 9235/Ocean, Rabat/Maroc (1 aut., 2 aut., 3 aut.); Hassan II Academy of Science and Technology/Rabat/Maroc (1 aut., 5 aut.); Canada Research Chair on Polymer Physics and Nanomaterials, Department of Chemical Engineering (CREPEC), Laval University/Sainte-Foy, Que., GIK 7P4/Canada (4 aut., 5 aut.)
DT : Publication en série; Niveau analytique
SO : Physica. E, low-dimentional systems and nanostructures; ISSN 1386-9477; Pays-Bas; Da. 2008; Vol. 40; No. 3; Pp. 574-578; Bibl. 23 ref.
LA : Anglais
EA : The variation of magnetic susceptibility and heat capacity with temperature for the bimetallic nickel Ni(II)-copper Cu(II) cyclo-tetrametaphosphates (CuNiP4O12) has been examined. The complex has a structure of quasi-one-dimensional alternate spins chains of Ni(II) and Cu(II) that exhibits a three-dimensional magnetic ordering at approximately 13.5 K. The compound is characterized by a ferromagnetic intrachain constant JF = 4.05K, with a significant effect of single ion anisotropy D = 9.70K. The chains are weakly coupled antiferromagnetically with an interchain exchange constant of 2zAFJAF = -1.125 K.
CC : 001B70E40C
FD : Propriété thermodynamique; Susceptibilité magnétique; Chaleur massique; Chaîne spin; Ordre magnétique; Anisotropie; Interaction échange; Ferromagnétisme; Antiferromagnétisme; Modèle chaîne alternée; CuNiP4O12; Phosphate de cuivre et de nickel
ED : Thermodynamic properties; Magnetic susceptibility; Specific heat; Spin chain; Magnetic ordering; Anisotropy; Exchange interactions; Ferromagnetism; Antiferromagnetism; Alternated chains model
LO : INIST-145E.354000161884020250
ID : 08-0117706

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Pascal:08-0117706

Le document en format XML

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<term>Ferromagnetism</term>
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<front>
<div type="abstract" xml:lang="en">The variation of magnetic susceptibility and heat capacity with temperature for the bimetallic nickel Ni(II)-copper Cu(II) cyclo-tetrametaphosphates (CuNiP
<sub>4</sub>
O
<sub>12</sub>
) has been examined. The complex has a structure of quasi-one-dimensional alternate spins chains of Ni(II) and Cu(II) that exhibits a three-dimensional magnetic ordering at approximately 13.5 K. The compound is characterized by a ferromagnetic intrachain constant J
<sub>F</sub>
= 4.05K, with a significant effect of single ion anisotropy D = 9.70K. The chains are weakly coupled antiferromagnetically with an interchain exchange constant of 2z
<sub>AF</sub>
J
<sub>AF</sub>
= -1.125 K.</div>
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O
<sub>12</sub>
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<s0>The variation of magnetic susceptibility and heat capacity with temperature for the bimetallic nickel Ni(II)-copper Cu(II) cyclo-tetrametaphosphates (CuNiP
<sub>4</sub>
O
<sub>12</sub>
) has been examined. The complex has a structure of quasi-one-dimensional alternate spins chains of Ni(II) and Cu(II) that exhibits a three-dimensional magnetic ordering at approximately 13.5 K. The compound is characterized by a ferromagnetic intrachain constant J
<sub>F</sub>
= 4.05K, with a significant effect of single ion anisotropy D = 9.70K. The chains are weakly coupled antiferromagnetically with an interchain exchange constant of 2z
<sub>AF</sub>
J
<sub>AF</sub>
= -1.125 K.</s0>
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<s0>Thermodynamic properties</s0>
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<s0>Susceptibilité magnétique</s0>
<s5>03</s5>
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<s5>05</s5>
</fC03>
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<s0>Spin chain</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE">
<s0>Ordre magnétique</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG">
<s0>Magnetic ordering</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE">
<s0>Anisotropie</s0>
<s5>07</s5>
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<s0>Anisotropy</s0>
<s5>07</s5>
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<s0>Interaction échange</s0>
<s5>08</s5>
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<s0>Exchange interactions</s0>
<s5>08</s5>
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<s0>Ferromagnétisme</s0>
<s5>10</s5>
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<s0>Ferromagnetism</s0>
<s5>10</s5>
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<s0>Antiferromagnétisme</s0>
<s5>11</s5>
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<s0>Antiferromagnetism</s0>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE">
<s0>Modèle chaîne alternée</s0>
<s5>12</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG">
<s0>Alternated chains model</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE">
<s0>CuNiP4O12</s0>
<s4>INC</s4>
<s5>63</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE">
<s0>Phosphate de cuivre et de nickel</s0>
<s4>INC</s4>
<s5>64</s5>
</fC03>
<fN21>
<s1>063</s1>
</fN21>
</pA>
</standard>
<server>
<NO>PASCAL 08-0117706 INIST</NO>
<ET>Thermodynamics properties of NiCuP
<sub>4</sub>
O
<sub>12</sub>
</ET>
<AU>BELAICHE (M.); BAKHACHE (M.); BENHAMMOU (M.); EL-MABROUKE (K.); BOUSMINA (M.)</AU>
<AF>Laboratory of Magnetism, Magnetic Materials, Micro-waves and Ceramics, Ecole Normale Supérieure de Rabat, BP 9235/Ocean, Rabat/Maroc (1 aut., 2 aut., 3 aut.); Hassan II Academy of Science and Technology/Rabat/Maroc (1 aut., 5 aut.); Canada Research Chair on Polymer Physics and Nanomaterials, Department of Chemical Engineering (CREPEC), Laval University/Sainte-Foy, Que., GIK 7P4/Canada (4 aut., 5 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Physica. E, low-dimentional systems and nanostructures; ISSN 1386-9477; Pays-Bas; Da. 2008; Vol. 40; No. 3; Pp. 574-578; Bibl. 23 ref.</SO>
<LA>Anglais</LA>
<EA>The variation of magnetic susceptibility and heat capacity with temperature for the bimetallic nickel Ni(II)-copper Cu(II) cyclo-tetrametaphosphates (CuNiP
<sub>4</sub>
O
<sub>12</sub>
) has been examined. The complex has a structure of quasi-one-dimensional alternate spins chains of Ni(II) and Cu(II) that exhibits a three-dimensional magnetic ordering at approximately 13.5 K. The compound is characterized by a ferromagnetic intrachain constant J
<sub>F</sub>
= 4.05K, with a significant effect of single ion anisotropy D = 9.70K. The chains are weakly coupled antiferromagnetically with an interchain exchange constant of 2z
<sub>AF</sub>
J
<sub>AF</sub>
= -1.125 K.</EA>
<CC>001B70E40C</CC>
<FD>Propriété thermodynamique; Susceptibilité magnétique; Chaleur massique; Chaîne spin; Ordre magnétique; Anisotropie; Interaction échange; Ferromagnétisme; Antiferromagnétisme; Modèle chaîne alternée; CuNiP4O12; Phosphate de cuivre et de nickel</FD>
<ED>Thermodynamic properties; Magnetic susceptibility; Specific heat; Spin chain; Magnetic ordering; Anisotropy; Exchange interactions; Ferromagnetism; Antiferromagnetism; Alternated chains model</ED>
<LO>INIST-145E.354000161884020250</LO>
<ID>08-0117706</ID>
</server>
</inist>
</record>

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