Crystal structures of a copper(II) and the isotypic nickel(II) and palladium(II) complexes of the ligand (E)-1-[(2,4,6-tribromophenyl)diazenyl]naphthalen-2-ol
Identifieur interne : 000161 ( Ncbi/Merge ); précédent : 000160; suivant : 000162Crystal structures of a copper(II) and the isotypic nickel(II) and palladium(II) complexes of the ligand (E)-1-[(2,4,6-tribromophenyl)diazenyl]naphthalen-2-ol
Auteurs : Souheyla Chetioui [Algérie] ; Djamil-Azzeddine Rouag [Algérie] ; Jean-Pierre Djukic [France] ; Christian G. Bochet [Suisse] ; Rachid Touzani [Maroc] ; Corinne Bailly [France] ; Aurélien Crochet [Suisse] ; Katharina M. Fromm [Suisse]Source :
- Acta Crystallographica Section E: Crystallographic Communications [ 2056-9890 ] ; 2016.
Abstract
In the title copper(II) complex, the metal atom is coordinated by two N atoms and two O atoms from two bidentate (
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DOI: 10.1107/S205698901601080X
PubMed: 27536389
PubMed Central: 4971848
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Bochet</name><affiliation wicri:level="1"><nlm:aff id="c">Chemistry Department, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg,<country>Switzerland</country></nlm:aff><country xml:lang="fr">Suisse</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Touzani, Rachid" sort="Touzani, Rachid" uniqKey="Touzani R" first="Rachid" last="Touzani">Rachid Touzani</name><affiliation wicri:level="1"><nlm:aff id="d">Laboratoire de Chimie Appliquée et Environnement, LCAE-URAC18, COSTE, Faculté des Sciences, Université Mohamed Premier, BP524, 60000 Oujda,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation><affiliation wicri:level="1"><nlm:aff id="e">Faculté Pluridisciplinaire Nador BP 300, Selouane 62702, Nador,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Bailly, Corinne" sort="Bailly, Corinne" uniqKey="Bailly C" first="Corinne" last="Bailly">Corinne Bailly</name><affiliation wicri:level="1"><nlm:aff id="f">Service de Radiocristallographie, Institut de Chimie, Université de Strasbourg, UMR 7177, 67008 Strasbourg Cedex,<country>France</country></nlm:aff><country xml:lang="fr">France</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Crochet, Aurelien" sort="Crochet, Aurelien" uniqKey="Crochet A" first="Aurélien" last="Crochet">Aurélien Crochet</name><affiliation wicri:level="1"><nlm:aff id="g">Fribourg Center for Nanomaterials, FriMat, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg,<country>Switzerland</country></nlm:aff><country xml:lang="fr">Suisse</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Fromm, Katharina M" sort="Fromm, Katharina M" uniqKey="Fromm K" first="Katharina M." last="Fromm">Katharina M. Fromm</name><affiliation wicri:level="1"><nlm:aff id="c">Chemistry Department, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg,<country>Switzerland</country></nlm:aff><country xml:lang="fr">Suisse</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></analytic><series><title level="j">Acta Crystallographica Section E: Crystallographic Communications</title><idno type="eISSN">2056-9890</idno><imprint><date when="2016">2016</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p>In the title copper(II) complex, the metal atom is coordinated by two N atoms and two O atoms from two bidentate (<italic>E</italic>)-1-[(2,4,6-tribromophenyl)diazenyl]naphthalen-2-ol ligands, forming a slightly distorted square-planar environment. In the isotypic nickel(II) and palladium(II) complexes, the metal atoms are located on centres of inversion, hence the metal coordination spheres have perfect square-planar geometries.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct></listBibl></div1></back></TEI><double pmid="27536389"><pmc><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Crystal structures of a copper(II) and the isotypic nickel(II) and palladium(II) complexes of the ligand (<italic>E</italic>)-1-[(2,4,6-tribromophenyl)diazenyl]naphthalen-2-ol</title><author><name sortKey="Chetioui, Souheyla" sort="Chetioui, Souheyla" uniqKey="Chetioui S" first="Souheyla" last="Chetioui">Souheyla Chetioui</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université des Frères Mentouri Constantine, Constantine 25000,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Rouag, Djamil Azzeddine" sort="Rouag, Djamil Azzeddine" uniqKey="Rouag D" first="Djamil-Azzeddine" last="Rouag">Djamil-Azzeddine Rouag</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université des Frères Mentouri Constantine, Constantine 25000,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Djukic, Jean Pierre" sort="Djukic, Jean Pierre" uniqKey="Djukic J" first="Jean-Pierre" last="Djukic">Jean-Pierre Djukic</name><affiliation wicri:level="1"><nlm:aff id="b">Laboratoire de Chimie et Systémique Organométallique (LCSOM), Institut de Chimie, Université de Strasbourg, UMR 7177., 4 rue Blaise Pascal, F-67070 Strasbourg Cedex,<country>France</country></nlm:aff><country xml:lang="fr">France</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Bochet, Christian G" sort="Bochet, Christian G" uniqKey="Bochet C" first="Christian G." last="Bochet">Christian G. Bochet</name><affiliation wicri:level="1"><nlm:aff id="c">Chemistry Department, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg,<country>Switzerland</country></nlm:aff><country xml:lang="fr">Suisse</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Touzani, Rachid" sort="Touzani, Rachid" uniqKey="Touzani R" first="Rachid" last="Touzani">Rachid Touzani</name><affiliation wicri:level="1"><nlm:aff id="d">Laboratoire de Chimie Appliquée et Environnement, LCAE-URAC18, COSTE, Faculté des Sciences, Université Mohamed Premier, BP524, 60000 Oujda,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation><affiliation wicri:level="1"><nlm:aff id="e">Faculté Pluridisciplinaire Nador BP 300, Selouane 62702, Nador,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Bailly, Corinne" sort="Bailly, Corinne" uniqKey="Bailly C" first="Corinne" last="Bailly">Corinne Bailly</name><affiliation wicri:level="1"><nlm:aff id="f">Service de Radiocristallographie, Institut de Chimie, Université de Strasbourg, UMR 7177, 67008 Strasbourg Cedex,<country>France</country></nlm:aff><country xml:lang="fr">France</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Crochet, Aurelien" sort="Crochet, Aurelien" uniqKey="Crochet A" first="Aurélien" last="Crochet">Aurélien Crochet</name><affiliation wicri:level="1"><nlm:aff id="g">Fribourg Center for Nanomaterials, FriMat, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg,<country>Switzerland</country></nlm:aff><country xml:lang="fr">Suisse</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Fromm, Katharina M" sort="Fromm, Katharina M" uniqKey="Fromm K" first="Katharina M." last="Fromm">Katharina M. Fromm</name><affiliation wicri:level="1"><nlm:aff id="c">Chemistry Department, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg,<country>Switzerland</country></nlm:aff><country xml:lang="fr">Suisse</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PMC</idno><idno type="pmid">27536389</idno><idno type="pmc">4971848</idno><idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4971848</idno><idno type="RBID">PMC:4971848</idno><idno type="doi">10.1107/S205698901601080X</idno><date when="2016">2016</date><idno type="wicri:Area/Pmc/Corpus">000006</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000006</idno><idno type="wicri:Area/Pmc/Curation">000006</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000006</idno><idno type="wicri:Area/Pmc/Checkpoint">000005</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Checkpoint">000005</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Crystal structures of a copper(II) and the isotypic nickel(II) and palladium(II) complexes of the ligand (<italic>E</italic>)-1-[(2,4,6-tribromophenyl)diazenyl]naphthalen-2-ol</title><author><name sortKey="Chetioui, Souheyla" sort="Chetioui, Souheyla" uniqKey="Chetioui S" first="Souheyla" last="Chetioui">Souheyla Chetioui</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université des Frères Mentouri Constantine, Constantine 25000,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Rouag, Djamil Azzeddine" sort="Rouag, Djamil Azzeddine" uniqKey="Rouag D" first="Djamil-Azzeddine" last="Rouag">Djamil-Azzeddine Rouag</name><affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université des Frères Mentouri Constantine, Constantine 25000,<country>Algeria</country></nlm:aff><country xml:lang="fr">Algérie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Djukic, Jean Pierre" sort="Djukic, Jean Pierre" uniqKey="Djukic J" first="Jean-Pierre" last="Djukic">Jean-Pierre Djukic</name><affiliation wicri:level="1"><nlm:aff id="b">Laboratoire de Chimie et Systémique Organométallique (LCSOM), Institut de Chimie, Université de Strasbourg, UMR 7177., 4 rue Blaise Pascal, F-67070 Strasbourg Cedex,<country>France</country></nlm:aff><country xml:lang="fr">France</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Bochet, Christian G" sort="Bochet, Christian G" uniqKey="Bochet C" first="Christian G." last="Bochet">Christian G. Bochet</name><affiliation wicri:level="1"><nlm:aff id="c">Chemistry Department, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg,<country>Switzerland</country></nlm:aff><country xml:lang="fr">Suisse</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Touzani, Rachid" sort="Touzani, Rachid" uniqKey="Touzani R" first="Rachid" last="Touzani">Rachid Touzani</name><affiliation wicri:level="1"><nlm:aff id="d">Laboratoire de Chimie Appliquée et Environnement, LCAE-URAC18, COSTE, Faculté des Sciences, Université Mohamed Premier, BP524, 60000 Oujda,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation><affiliation wicri:level="1"><nlm:aff id="e">Faculté Pluridisciplinaire Nador BP 300, Selouane 62702, Nador,<country>Morocco</country></nlm:aff><country xml:lang="fr">Maroc</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Bailly, Corinne" sort="Bailly, Corinne" uniqKey="Bailly C" first="Corinne" last="Bailly">Corinne Bailly</name><affiliation wicri:level="1"><nlm:aff id="f">Service de Radiocristallographie, Institut de Chimie, Université de Strasbourg, UMR 7177, 67008 Strasbourg Cedex,<country>France</country></nlm:aff><country xml:lang="fr">France</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Crochet, Aurelien" sort="Crochet, Aurelien" uniqKey="Crochet A" first="Aurélien" last="Crochet">Aurélien Crochet</name><affiliation wicri:level="1"><nlm:aff id="g">Fribourg Center for Nanomaterials, FriMat, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg,<country>Switzerland</country></nlm:aff><country xml:lang="fr">Suisse</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Fromm, Katharina M" sort="Fromm, Katharina M" uniqKey="Fromm K" first="Katharina M." last="Fromm">Katharina M. Fromm</name><affiliation wicri:level="1"><nlm:aff id="c">Chemistry Department, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg,<country>Switzerland</country></nlm:aff><country xml:lang="fr">Suisse</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></analytic><series><title level="j">Acta Crystallographica Section E: Crystallographic Communications</title><idno type="eISSN">2056-9890</idno><imprint><date when="2016">2016</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p>In the title copper(II) complex, the metal atom is coordinated by two N atoms and two O atoms from two bidentate (<italic>E</italic>)-1-[(2,4,6-tribromophenyl)diazenyl]naphthalen-2-ol ligands, forming a slightly distorted square-planar environment. In the isotypic nickel(II) and palladium(II) complexes, the metal atoms are located on centres of inversion, hence the metal coordination spheres have perfect square-planar geometries.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct></listBibl></div1></back></TEI></pmc><pubmed><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Crystal structures of a copper(II) and the isotypic nickel(II) and palladium(II) complexes of the ligand (E)-1-[(2,4,6-tri-bromo-phen-yl)diazen-yl]naphthalen-2-ol.</title><author><name sortKey="Chetioui, Souheyla" sort="Chetioui, Souheyla" uniqKey="Chetioui S" first="Souheyla" last="Chetioui">Souheyla Chetioui</name><affiliation wicri:level="1"><nlm:affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université des Frères Mentouri Constantine, Constantine 25000, Algeria.</nlm:affiliation><country xml:lang="fr">Algérie</country><wicri:regionArea>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université des Frères Mentouri Constantine, Constantine 25000</wicri:regionArea><wicri:noRegion>Constantine 25000</wicri:noRegion></affiliation></author><author><name sortKey="Rouag, Djamil Azzeddine" sort="Rouag, Djamil Azzeddine" uniqKey="Rouag D" first="Djamil-Azzeddine" last="Rouag">Djamil-Azzeddine Rouag</name><affiliation wicri:level="1"><nlm:affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université des Frères Mentouri Constantine, Constantine 25000, Algeria.</nlm:affiliation><country xml:lang="fr">Algérie</country><wicri:regionArea>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université des Frères Mentouri Constantine, Constantine 25000</wicri:regionArea><wicri:noRegion>Constantine 25000</wicri:noRegion></affiliation></author><author><name sortKey="Djukic, Jean Pierre" sort="Djukic, Jean Pierre" uniqKey="Djukic J" first="Jean-Pierre" last="Djukic">Jean-Pierre Djukic</name><affiliation wicri:level="4"><nlm:affiliation>Laboratoire de Chimie et Systémique Organométallique (LCSOM), Institut de Chimie, Université de Strasbourg, UMR 7177., 4 rue Blaise Pascal, F-67070 Strasbourg Cedex, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire de Chimie et Systémique Organométallique (LCSOM), Institut de Chimie, Université de Strasbourg, UMR 7177., 4 rue Blaise Pascal, F-67070 Strasbourg Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Alsace (région administrative)</region><settlement type="city">Strasbourg</settlement></placeName><orgName type="university">Université de Strasbourg</orgName></affiliation></author><author><name sortKey="Bochet, Christian G" sort="Bochet, Christian G" uniqKey="Bochet C" first="Christian G" last="Bochet">Christian G. Bochet</name><affiliation wicri:level="4"><nlm:affiliation>Chemistry Department, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg, Switzerland.</nlm:affiliation><country xml:lang="fr">Suisse</country><wicri:regionArea>Chemistry Department, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg</wicri:regionArea><orgName type="university">Université de Fribourg</orgName><placeName><settlement type="city">Fribourg</settlement><region nuts="3" type="region">Canton de Fribourg</region></placeName></affiliation></author><author><name sortKey="Touzani, Rachid" sort="Touzani, Rachid" uniqKey="Touzani R" first="Rachid" last="Touzani">Rachid Touzani</name><affiliation wicri:level="1"><nlm:affiliation>Laboratoire de Chimie Appliquée et Environnement, LCAE-URAC18, COSTE, Faculté des Sciences, Université Mohamed Premier, BP524, 60000 Oujda, Morocco; Faculté Pluridisciplinaire Nador BP 300, Selouane 62702, Nador, Morocco.</nlm:affiliation><country xml:lang="fr">Maroc</country><wicri:regionArea>Laboratoire de Chimie Appliquée et Environnement, LCAE-URAC18, COSTE, Faculté des Sciences, Université Mohamed Premier, BP524, 60000 Oujda, Morocco; Faculté Pluridisciplinaire Nador BP 300, Selouane 62702, Nador</wicri:regionArea><wicri:noRegion>Nador</wicri:noRegion></affiliation></author><author><name sortKey="Bailly, Corinne" sort="Bailly, Corinne" uniqKey="Bailly C" first="Corinne" last="Bailly">Corinne Bailly</name><affiliation wicri:level="4"><nlm:affiliation>Service de Radiocristallographie, Institut de Chimie, Université de Strasbourg, UMR 7177, 67008 Strasbourg Cedex, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Service de Radiocristallographie, Institut de Chimie, Université de Strasbourg, UMR 7177, 67008 Strasbourg Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Alsace (région administrative)</region><settlement type="city">Strasbourg</settlement></placeName><orgName type="university">Université de Strasbourg</orgName></affiliation></author><author><name sortKey="Crochet, Aurelien" sort="Crochet, Aurelien" uniqKey="Crochet A" first="Aurélien" last="Crochet">Aurélien Crochet</name><affiliation wicri:level="4"><nlm:affiliation>Fribourg Center for Nanomaterials, FriMat, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg, Switzerland.</nlm:affiliation><country xml:lang="fr">Suisse</country><wicri:regionArea>Fribourg Center for Nanomaterials, FriMat, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg</wicri:regionArea><orgName type="university">Université de Fribourg</orgName><placeName><settlement type="city">Fribourg</settlement><region nuts="3" type="region">Canton de Fribourg</region></placeName></affiliation></author><author><name sortKey="Fromm, Katharina M" sort="Fromm, Katharina M" uniqKey="Fromm K" first="Katharina M" last="Fromm">Katharina M. Fromm</name><affiliation wicri:level="4"><nlm:affiliation>Chemistry Department, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg, Switzerland.</nlm:affiliation><country xml:lang="fr">Suisse</country><wicri:regionArea>Chemistry Department, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg</wicri:regionArea><orgName type="university">Université de Fribourg</orgName><placeName><settlement type="city">Fribourg</settlement><region nuts="3" type="region">Canton de Fribourg</region></placeName></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2016">2016</date><idno type="RBID">pubmed:27536389</idno><idno type="pmid">27536389</idno><idno type="doi">10.1107/S205698901601080X</idno><idno type="wicri:Area/PubMed/Corpus">000012</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000012</idno><idno type="wicri:Area/PubMed/Curation">000012</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">000012</idno><idno type="wicri:Area/PubMed/Checkpoint">000012</idno><idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">000012</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Crystal structures of a copper(II) and the isotypic nickel(II) and palladium(II) complexes of the ligand (E)-1-[(2,4,6-tri-bromo-phen-yl)diazen-yl]naphthalen-2-ol.</title><author><name sortKey="Chetioui, Souheyla" sort="Chetioui, Souheyla" uniqKey="Chetioui S" first="Souheyla" last="Chetioui">Souheyla Chetioui</name><affiliation wicri:level="1"><nlm:affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université des Frères Mentouri Constantine, Constantine 25000, Algeria.</nlm:affiliation><country xml:lang="fr">Algérie</country><wicri:regionArea>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université des Frères Mentouri Constantine, Constantine 25000</wicri:regionArea><wicri:noRegion>Constantine 25000</wicri:noRegion></affiliation></author><author><name sortKey="Rouag, Djamil Azzeddine" sort="Rouag, Djamil Azzeddine" uniqKey="Rouag D" first="Djamil-Azzeddine" last="Rouag">Djamil-Azzeddine Rouag</name><affiliation wicri:level="1"><nlm:affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université des Frères Mentouri Constantine, Constantine 25000, Algeria.</nlm:affiliation><country xml:lang="fr">Algérie</country><wicri:regionArea>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université des Frères Mentouri Constantine, Constantine 25000</wicri:regionArea><wicri:noRegion>Constantine 25000</wicri:noRegion></affiliation></author><author><name sortKey="Djukic, Jean Pierre" sort="Djukic, Jean Pierre" uniqKey="Djukic J" first="Jean-Pierre" last="Djukic">Jean-Pierre Djukic</name><affiliation wicri:level="4"><nlm:affiliation>Laboratoire de Chimie et Systémique Organométallique (LCSOM), Institut de Chimie, Université de Strasbourg, UMR 7177., 4 rue Blaise Pascal, F-67070 Strasbourg Cedex, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire de Chimie et Systémique Organométallique (LCSOM), Institut de Chimie, Université de Strasbourg, UMR 7177., 4 rue Blaise Pascal, F-67070 Strasbourg Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Alsace (région administrative)</region><settlement type="city">Strasbourg</settlement></placeName><orgName type="university">Université de Strasbourg</orgName></affiliation></author><author><name sortKey="Bochet, Christian G" sort="Bochet, Christian G" uniqKey="Bochet C" first="Christian G" last="Bochet">Christian G. Bochet</name><affiliation wicri:level="4"><nlm:affiliation>Chemistry Department, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg, Switzerland.</nlm:affiliation><country xml:lang="fr">Suisse</country><wicri:regionArea>Chemistry Department, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg</wicri:regionArea><orgName type="university">Université de Fribourg</orgName><placeName><settlement type="city">Fribourg</settlement><region nuts="3" type="region">Canton de Fribourg</region></placeName></affiliation></author><author><name sortKey="Touzani, Rachid" sort="Touzani, Rachid" uniqKey="Touzani R" first="Rachid" last="Touzani">Rachid Touzani</name><affiliation wicri:level="1"><nlm:affiliation>Laboratoire de Chimie Appliquée et Environnement, LCAE-URAC18, COSTE, Faculté des Sciences, Université Mohamed Premier, BP524, 60000 Oujda, Morocco; Faculté Pluridisciplinaire Nador BP 300, Selouane 62702, Nador, Morocco.</nlm:affiliation><country xml:lang="fr">Maroc</country><wicri:regionArea>Laboratoire de Chimie Appliquée et Environnement, LCAE-URAC18, COSTE, Faculté des Sciences, Université Mohamed Premier, BP524, 60000 Oujda, Morocco; Faculté Pluridisciplinaire Nador BP 300, Selouane 62702, Nador</wicri:regionArea><wicri:noRegion>Nador</wicri:noRegion></affiliation></author><author><name sortKey="Bailly, Corinne" sort="Bailly, Corinne" uniqKey="Bailly C" first="Corinne" last="Bailly">Corinne Bailly</name><affiliation wicri:level="4"><nlm:affiliation>Service de Radiocristallographie, Institut de Chimie, Université de Strasbourg, UMR 7177, 67008 Strasbourg Cedex, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Service de Radiocristallographie, Institut de Chimie, Université de Strasbourg, UMR 7177, 67008 Strasbourg Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Alsace (région administrative)</region><settlement type="city">Strasbourg</settlement></placeName><orgName type="university">Université de Strasbourg</orgName></affiliation></author><author><name sortKey="Crochet, Aurelien" sort="Crochet, Aurelien" uniqKey="Crochet A" first="Aurélien" last="Crochet">Aurélien Crochet</name><affiliation wicri:level="4"><nlm:affiliation>Fribourg Center for Nanomaterials, FriMat, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg, Switzerland.</nlm:affiliation><country xml:lang="fr">Suisse</country><wicri:regionArea>Fribourg Center for Nanomaterials, FriMat, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg</wicri:regionArea><orgName type="university">Université de Fribourg</orgName><placeName><settlement type="city">Fribourg</settlement><region nuts="3" type="region">Canton de Fribourg</region></placeName></affiliation></author><author><name sortKey="Fromm, Katharina M" sort="Fromm, Katharina M" uniqKey="Fromm K" first="Katharina M" last="Fromm">Katharina M. Fromm</name><affiliation wicri:level="4"><nlm:affiliation>Chemistry Department, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg, Switzerland.</nlm:affiliation><country xml:lang="fr">Suisse</country><wicri:regionArea>Chemistry Department, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg</wicri:regionArea><orgName type="university">Université de Fribourg</orgName><placeName><settlement type="city">Fribourg</settlement><region nuts="3" type="region">Canton de Fribourg</region></placeName></affiliation></author></analytic><series><title level="j">Acta crystallographica. Section E, Crystallographic communications</title><imprint><date when="2016" type="published">2016</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">In the copper(II) complex, bis-{(E)-1-[(2,4,6-tri-bromo-phen-yl)diazen-yl]naph-thalen-2-olato}copper(II), [Cu(C16H8Br3N2O)2], (I), the metal cation is coord-inated by two N atoms and two O atoms from two bidentate (E)-1-[(2,4,6-tri-bromo-phen-yl)diazen-yl]naphthalen-2-olate ligands, forming a slightly distorted square-planar environment. In one of the ligands, the tri-bromo-benzene ring is inclined to the naphthalene ring system by 37.4 (5)°, creating a weak intra-molecular Cu⋯Br inter-action [3.134 (2) Å], while in the other ligand, the tri-bromo-benzene ring is inclined to the naphthalene ring system by 72.1 (6)°. In the isotypic nickel(II) and palladium(II) complexes, namely bis-{(E)-1-[(2,4,6-tri-bromo-phen-yl)diazen-yl]naphthalen-2-olato}nickel(II), [Ni(C16H8Br3N2O)2], (II), and bis-{(E)-1-[(2,4,6-tri-bromo-phen-yl)diazen-yl]naphthalen-2-olato}palladium(II), [Pd(C16H8Br3N2O)2], (III), respectively, the metal atoms are located on centres of inversion, hence the metal coordination spheres have perfect square-planar geometries. The tri-bromo-benzene rings are inclined to the naphthalene ring systems by 80.79 (18)° in (II) and by 80.8 (3)° in (III). In the crystal of (I), mol-ecules are linked by C-H⋯Br hydrogen bonds, forming chains along [010]. The chains are linked by C-H⋯π inter-actions, forming sheets parallel to (011). In the crystals of (II) and (III), mol-ecules are linked by C-H⋯π inter-actions, forming slabs parallel to (10-1). For the copper(II) complex (I), a region of disordered electron density was corrected for using the SQUEEZE routine in PLATON [Spek (2015 ▸). Acta Cryst. C71, 9-18]. The formula mass and unit-cell characteristics of the disordered solvent mol-ecules were not taken into account during refinement.</div></front></TEI></pubmed></double></record>Pour manipuler ce document sous Unix (Dilib)
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