A one-dimensional polymeric cobalt(III)-potassium complex with 18-crown-6, cyanide and porphyrinate ligands.
Identifieur interne : 000023 ( PubMed/Checkpoint ); précédent : 000022; suivant : 000024A one-dimensional polymeric cobalt(III)-potassium complex with 18-crown-6, cyanide and porphyrinate ligands.
Auteurs : Yassine Belghith [Tunisie] ; Hamza Toumi [Tunisie] ; Jean-Claude Daran [France] ; Habib Nasri [Tunisie]Source :
- Acta crystallographica. Section E, Structure reports online ; 2014.
Abstract
The reaction of Co(II)(TpivPP) {TpivPP is the dianion of 5,10,15,20-tetra-kis-[2-(2,2-di-methyl-propanamido)-phen-yl]por-ph-yrin} with an excess of KCN salts and an excess of the 18-crown-6 in chloro-benzene leads to the polymeric title compound catena-poly[[dicyanido-2κ(2) C-(1,4,7,10,13,16-hexa-oxa-cyclo-octa-decane-1κ(6) O){μ3-(2α,2β)-5,10,15,20-tetra-kis-[2-(2,2-di-methyl-propanamido)-phen-yl]porphyrinato-1κO (5):2κ(4) N,N',N'',N''':1'κO (15)}cobalt(III)potassium] dihydrate], {[CoK(CN)2(C12H24O6)(C64H64N8O4]·2H2O} n . The Co(III) ion lies on an inversion center, and the asymmetric unit contains one half of a [Co(III)(2α,2β-TpivPP)(CN)2](-) ion complex and one half of a [K(18-C-6](+) counter-ion (18-C-6 is 1,4,7,10,13,16-hexa-oxa-cyclo-octa-deca-ne), where the K(I) ion lies on an inversion center. The Co(III) ion is hexa-coordinated by two C-bonded axial cyanide ligands and the four pyrrole N atoms of the porphyrin ligand. The K(I) ion is chelated by the six O atoms of the 18-crown-6 mol-ecule and is further coordinated by two O atoms of pivalamido groups of the porphyrin ligands, leading to the formation of polymeric chains running along [011]. In the crystal, the polymeric chains and the lattice water mol-ecules are linked by N-H⋯O and O-H⋯N hydrogen bonds, as well as weak C-H⋯O, O-H⋯π and C-H⋯π inter-actions into a three-dimensional supra-molecular architecture.
DOI: 10.1107/S1600536814003596
PubMed: 24764938
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de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, Tunisia.</nlm:affiliation><country xml:lang="fr">Tunisie</country><wicri:regionArea>Laboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir</wicri:regionArea><wicri:noRegion>University of Monastir</wicri:noRegion></affiliation></author><author><name sortKey="Toumi, Hamza" sort="Toumi, Hamza" uniqKey="Toumi H" first="Hamza" last="Toumi">Hamza Toumi</name><affiliation wicri:level="1"><nlm:affiliation>Laboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, Tunisia.</nlm:affiliation><country xml:lang="fr">Tunisie</country><wicri:regionArea>Laboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir</wicri:regionArea><wicri:noRegion>University of Monastir</wicri:noRegion></affiliation></author><author><name sortKey="Daran, Jean Claude" sort="Daran, Jean Claude" uniqKey="Daran J" first="Jean-Claude" last="Daran">Jean-Claude Daran</name><affiliation wicri:level="3"><nlm:affiliation>Laboratoire de Chimie de Coordination CNRS UPR 8241, 205 Route de Narbonne, 31077 Toulouse Cedex 04, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire de Chimie de Coordination CNRS UPR 8241, 205 Route de Narbonne, 31077 Toulouse Cedex 04</wicri:regionArea><placeName><region type="region" nuts="2">Occitanie (région administrative)</region><region type="old region" nuts="2">Midi-Pyrénées</region><settlement type="city">Toulouse</settlement></placeName></affiliation></author><author><name sortKey="Nasri, Habib" sort="Nasri, Habib" uniqKey="Nasri H" first="Habib" last="Nasri">Habib Nasri</name><affiliation wicri:level="1"><nlm:affiliation>Laboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, Tunisia.</nlm:affiliation><country xml:lang="fr">Tunisie</country><wicri:regionArea>Laboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir</wicri:regionArea><wicri:noRegion>University of Monastir</wicri:noRegion></affiliation></author></analytic><series><title level="j">Acta crystallographica. Section E, Structure reports online</title><imprint><date when="2014" type="published">2014</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The reaction of Co(II)(TpivPP) {TpivPP is the dianion of 5,10,15,20-tetra-kis-[2-(2,2-di-methyl-propanamido)-phen-yl]por-ph-yrin} with an excess of KCN salts and an excess of the 18-crown-6 in chloro-benzene leads to the polymeric title compound catena-poly[[dicyanido-2κ(2) C-(1,4,7,10,13,16-hexa-oxa-cyclo-octa-decane-1κ(6) O){μ3-(2α,2β)-5,10,15,20-tetra-kis-[2-(2,2-di-methyl-propanamido)-phen-yl]porphyrinato-1κO (5):2κ(4) N,N',N'',N''':1'κO (15)}cobalt(III)potassium] dihydrate], {[CoK(CN)2(C12H24O6)(C64H64N8O4]·2H2O} n . The Co(III) ion lies on an inversion center, and the asymmetric unit contains one half of a [Co(III)(2α,2β-TpivPP)(CN)2](-) ion complex and one half of a [K(18-C-6](+) counter-ion (18-C-6 is 1,4,7,10,13,16-hexa-oxa-cyclo-octa-deca-ne), where the K(I) ion lies on an inversion center. The Co(III) ion is hexa-coordinated by two C-bonded axial cyanide ligands and the four pyrrole N atoms of the porphyrin ligand. The K(I) ion is chelated by the six O atoms of the 18-crown-6 mol-ecule and is further coordinated by two O atoms of pivalamido groups of the porphyrin ligands, leading to the formation of polymeric chains running along [011]. In the crystal, the polymeric chains and the lattice water mol-ecules are linked by N-H⋯O and O-H⋯N hydrogen bonds, as well as weak C-H⋯O, O-H⋯π and C-H⋯π inter-actions into a three-dimensional supra-molecular architecture.</div></front></TEI><pubmed><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">24764938</PMID><DateCreated><Year>2014</Year><Month>4</Month><Day>25</Day></DateCreated><DateCompleted><Year>2014</Year><Month>04</Month><Day>25</Day></DateCompleted><DateRevised><Year>2014</Year><Month>4</Month><Day>28</Day></DateRevised><Article PubModel="Electronic-eCollection"><Journal><JournalIssue CitedMedium="Print"><Volume>70</Volume><Issue>Pt 3</Issue><PubDate><Year>2014</Year><Month>Mar</Month><Day>1</Day></PubDate></JournalIssue><Title>Acta crystallographica. Section E, Structure reports online</Title><ISOAbbreviation>Acta Crystallogr Sect E Struct Rep Online</ISOAbbreviation></Journal><ArticleTitle>A one-dimensional polymeric cobalt(III)-potassium complex with 18-crown-6, cyanide and porphyrinate ligands.</ArticleTitle><Pagination><MedlinePgn>m104-5</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1107/S1600536814003596</ELocationID><Abstract><AbstractText>The reaction of Co(II)(TpivPP) {TpivPP is the dianion of 5,10,15,20-tetra-kis-[2-(2,2-di-methyl-propanamido)-phen-yl]por-ph-yrin} with an excess of KCN salts and an excess of the 18-crown-6 in chloro-benzene leads to the polymeric title compound catena-poly[[dicyanido-2κ(2) C-(1,4,7,10,13,16-hexa-oxa-cyclo-octa-decane-1κ(6) O){μ3-(2α,2β)-5,10,15,20-tetra-kis-[2-(2,2-di-methyl-propanamido)-phen-yl]porphyrinato-1κO (5):2κ(4) N,N',N'',N''':1'κO (15)}cobalt(III)potassium] dihydrate], {[CoK(CN)2(C12H24O6)(C64H64N8O4]·2H2O} n . The Co(III) ion lies on an inversion center, and the asymmetric unit contains one half of a [Co(III)(2α,2β-TpivPP)(CN)2](-) ion complex and one half of a [K(18-C-6](+) counter-ion (18-C-6 is 1,4,7,10,13,16-hexa-oxa-cyclo-octa-deca-ne), where the K(I) ion lies on an inversion center. The Co(III) ion is hexa-coordinated by two C-bonded axial cyanide ligands and the four pyrrole N atoms of the porphyrin ligand. The K(I) ion is chelated by the six O atoms of the 18-crown-6 mol-ecule and is further coordinated by two O atoms of pivalamido groups of the porphyrin ligands, leading to the formation of polymeric chains running along [011]. In the crystal, the polymeric chains and the lattice water mol-ecules are linked by N-H⋯O and O-H⋯N hydrogen bonds, as well as weak C-H⋯O, O-H⋯π and C-H⋯π inter-actions into a three-dimensional supra-molecular architecture.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Belghith</LastName><ForeName>Yassine</ForeName><Initials>Y</Initials><AffiliationInfo><Affiliation>Laboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, Tunisia.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Toumi</LastName><ForeName>Hamza</ForeName><Initials>H</Initials><AffiliationInfo><Affiliation>Laboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, Tunisia.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Daran</LastName><ForeName>Jean-Claude</ForeName><Initials>JC</Initials><AffiliationInfo><Affiliation>Laboratoire de Chimie de Coordination CNRS UPR 8241, 205 Route de Narbonne, 31077 Toulouse Cedex 04, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Nasri</LastName><ForeName>Habib</ForeName><Initials>H</Initials><AffiliationInfo><Affiliation>Laboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, Tunisia.</Affiliation></AffiliationInfo></Author></AuthorList><Language>ENG</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2014</Year><Month>Feb</Month><Day>26</Day></ArticleDate></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>Acta Crystallogr Sect E Struct Rep Online</MedlineTA><NlmUniqueID>101089178</NlmUniqueID><ISSNLinking>1600-5368</ISSNLinking></MedlineJournalInfo><OtherID Source="NLM">PMC3998383</OtherID></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2014</Year><Month>2</Month><Day>06</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2014</Year><Month>2</Month><Day>17</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2014</Year><Month>4</Month><Day>26</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2014</Year><Month>4</Month><Day>26</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2014</Year><Month>4</Month><Day>26</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>epublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">24764938</ArticleId><ArticleId IdType="doi">10.1107/S1600536814003596</ArticleId><ArticleId IdType="pii">xu5770</ArticleId><ArticleId IdType="pmc">PMC3998383</ArticleId></ArticleIdList></PubmedData></pubmed><affiliations><list><country><li>France</li><li>Tunisie</li></country><region><li>Midi-Pyrénées</li><li>Occitanie (région administrative)</li></region><settlement><li>Toulouse</li></settlement></list><tree><country name="Tunisie"><noRegion><name sortKey="Belghith, Yassine" sort="Belghith, Yassine" uniqKey="Belghith Y" first="Yassine" last="Belghith">Yassine Belghith</name></noRegion><name sortKey="Nasri, Habib" sort="Nasri, Habib" uniqKey="Nasri H" first="Habib" last="Nasri">Habib Nasri</name><name sortKey="Toumi, Hamza" sort="Toumi, Hamza" uniqKey="Toumi H" first="Hamza" last="Toumi">Hamza Toumi</name></country><country name="France"><region name="Occitanie (région administrative)"><name sortKey="Daran, Jean Claude" sort="Daran, Jean Claude" uniqKey="Daran J" first="Jean-Claude" last="Daran">Jean-Claude Daran</name></region></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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