Trichlorido(1-ethylpiperazin-1-ium)cobalt(II)
Identifieur interne : 000322 ( Ncbi/Merge ); précédent : 000321; suivant : 000323Trichlorido(1-ethylpiperazin-1-ium)cobalt(II)
Auteurs : Abdelhamid Chiheb Dhieb [Tunisie] ; Daron E. Janzen [États-Unis] ; Mohamed Rzaigui [Tunisie] ; Wajda Smirani Sta [Tunisie]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2014.
Abstract
In the title complex, [Co(C6H15N2)Cl3], the Co2+ ion is coordinated in a distorted tetrahedral fashion by three chloride ions and one N atom of the piperazine ring; the ring adopts a chair conformation with the N—Co and N—CEt bonds in equatorial orientations. In the crystal, molecules are connected by N—H⋯Cl hydrogen bonds, generating (10-1) sheets.
Url:
DOI: 10.1107/S1600536814006989
PubMed: 24860302
PubMed Central: 4011199
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PMC:4011199Le document en format XML
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<front><div type="abstract" xml:lang="en"><p>In the title complex, [Co(C<sub>6</sub>
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N<sub>2</sub>
)Cl<sub>3</sub>
], the Co<sup>2+</sup>
ion is coordinated in a distorted tetrahedral fashion by three chloride ions and one N atom of the piperazine ring; the ring adopts a chair conformation with the N—Co and N—C<sub>Et</sub>
bonds in equatorial orientations. In the crystal, molecules are connected by N—H⋯Cl hydrogen bonds, generating (10-1) sheets.</p>
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<front><div type="abstract" xml:lang="en"><p>In the title complex, [Co(C<sub>6</sub>
H<sub>15</sub>
N<sub>2</sub>
)Cl<sub>3</sub>
], the Co<sup>2+</sup>
ion is coordinated in a distorted tetrahedral fashion by three chloride ions and one N atom of the piperazine ring; the ring adopts a chair conformation with the N—Co and N—C<sub>Et</sub>
bonds in equatorial orientations. In the crystal, molecules are connected by N—H⋯Cl hydrogen bonds, generating (10-1) sheets.</p>
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<front><div type="abstract" xml:lang="en">In the title complex, [Co(C6H15N2)Cl3], the Co(2+) ion is coordinated in a distorted tetra-hedral fashion by three chloride ions and one N atom of the piperazine ring; the ring adopts a chair conformation with the N-Co and N-CEt bonds in equatorial orientations. In the crystal, mol-ecules are connected by N-H⋯Cl hydrogen bonds, generating (10-1) sheets.</div>
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