Homopiperazine-1,4-diium bis[hexaaquacobalt(II)] trisulfate
Identifieur interne : 000484 ( Main/Exploration ); précédent : 000483; suivant : 000485Homopiperazine-1,4-diium bis[hexaaquacobalt(II)] trisulfate
Auteurs : Thameur Sahbani [Tunisie] ; Wajda Smirani Sta [Tunisie] ; Salem S. Al-Deyab [Arabie saoudite] ; Mohamed Rzaigui [Tunisie]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2011.
Abstract
In the title compound, (C5H14N2)[Co(H2O)6]2(SO4)3, the cationic framework is built up of mixed organic–inorganic fragments, namely [Co(H2O)6]2+ and [C5H14N2]2+. The [Co(H2O)6]2+ cations form unconnected octahedra. Sulfate anions intercalated between cationic species connect them
Url:
DOI: 10.1107/S1600536811027012
PubMed: 22090857
PubMed Central: 3212155
Affiliations:
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Le document en format XML
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Homopiperazine-1,4-diium bis[hexaaquacobalt(II)] trisulfate</title>
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<front><div type="abstract" xml:lang="en"><p>In the title compound, (C<sub>5</sub>
H<sub>14</sub>
N<sub>2</sub>
)[Co(H<sub>2</sub>
O)<sub>6</sub>
]<sub>2</sub>
(SO<sub>4</sub>
)<sub>3</sub>
, the cationic framework is built up of mixed organic–inorganic fragments, namely [Co(H<sub>2</sub>
O)<sub>6</sub>
]<sup>2+</sup>
and [C<sub>5</sub>
H<sub>14</sub>
N<sub>2</sub>
]<sup>2+</sup>
. The [Co(H<sub>2</sub>
O)<sub>6</sub>
]<sup>2+</sup>
cations form unconnected octahedra. Sulfate anions intercalated between cationic species connect them <italic>via</italic>
N—H⋯O and O—H⋯O hydrogen bonds and electrostatic interactions.</p>
</div>
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