Bis[tris(phenanthroline-κ2N,N′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrate
Identifieur interne : 000168 ( Main/Curation ); précédent : 000167; suivant : 000169Bis[tris(phenanthroline-κ2N,N′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrate
Auteurs : Assia Hajsalem [Tunisie] ; Sameh Aoun [France] ; Aurelien Planchat [France] ; Mohamed Rzaigui [Tunisie] ; Samah Akriche Toumi [Tunisie]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2014.
Abstract
In the title hydrated salt, [Co(C12H8N2)3]2[PVW11O40]·2H2O, the complete Kegggin ion is generated by crystallographic inversion symmetry, which imposes statistical disorder on the O atoms of its central PO4 group. The V atom is statistically disordered over all the metal sites of the anion. In the cation, the Co2+ ion is coordinated by three bidentate 1,10-phenanthroline (phen) ligands, generating a distorted CoN6 octahedron. Possible very weak intramolecular C—H⋯π interactions occur in the cation. In the crystal, the components are linked by O—H⋯O and C—H⋯O interactions, building a three-dimensional network featuring one-dimensional voids along the
Url:
DOI: 10.1107/S160053681400484X
PubMed: 24826091
PubMed Central: 3998553
Links toward previous steps (curation, corpus...)
- to stream Pmc, to step Corpus: Pour aller vers cette notice dans l'étape Curation :000380
- to stream Pmc, to step Curation: Pour aller vers cette notice dans l'étape Curation :000379
- to stream Pmc, to step Checkpoint: Pour aller vers cette notice dans l'étape Curation :000156
- to stream PubMed, to step Corpus: Pour aller vers cette notice dans l'étape Curation :000022
- to stream PubMed, to step Curation: Pour aller vers cette notice dans l'étape Curation :000022
- to stream PubMed, to step Checkpoint: Pour aller vers cette notice dans l'étape Curation :000022
- to stream Ncbi, to step Merge: Pour aller vers cette notice dans l'étape Curation :000319
- to stream Ncbi, to step Curation: Pour aller vers cette notice dans l'étape Curation :000319
- to stream Ncbi, to step Checkpoint: Pour aller vers cette notice dans l'étape Curation :000319
- to stream Main, to step Merge: Pour aller vers cette notice dans l'étape Curation :000168
Links to Exploration step
PMC:3998553Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Bis[tris(phenanthroline-κ<sup>2</sup>
<italic>N</italic>
,<italic>N</italic>
′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrate</title>
<author><name sortKey="Hajsalem, Assia" sort="Hajsalem, Assia" uniqKey="Hajsalem A" first="Assia" last="Hajsalem">Assia Hajsalem</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Aoun, Sameh" sort="Aoun, Sameh" uniqKey="Aoun S" first="Sameh" last="Aoun">Sameh Aoun</name>
<affiliation wicri:level="1"><nlm:aff id="b">Laboratoire CEISAM, UMR CNRS 6230, UFR des Sciences et des Techniques, 2 rue de la Houssinière, BP 92208, 44322 Nantes Cedex 03,<country>France</country>
</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Planchat, Aurelien" sort="Planchat, Aurelien" uniqKey="Planchat A" first="Aurelien" last="Planchat">Aurelien Planchat</name>
<affiliation wicri:level="1"><nlm:aff id="b">Laboratoire CEISAM, UMR CNRS 6230, UFR des Sciences et des Techniques, 2 rue de la Houssinière, BP 92208, 44322 Nantes Cedex 03,<country>France</country>
</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Rzaigui, Mohamed" sort="Rzaigui, Mohamed" uniqKey="Rzaigui M" first="Mohamed" last="Rzaigui">Mohamed Rzaigui</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Toumi, Samah Akriche" sort="Toumi, Samah Akriche" uniqKey="Toumi S" first="Samah Akriche" last="Toumi">Samah Akriche Toumi</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PMC</idno>
<idno type="pmid">24826091</idno>
<idno type="pmc">3998553</idno>
<idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998553</idno>
<idno type="RBID">PMC:3998553</idno>
<idno type="doi">10.1107/S160053681400484X</idno>
<date when="2014">2014</date>
<idno type="wicri:Area/Pmc/Corpus">000380</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000380</idno>
<idno type="wicri:Area/Pmc/Curation">000379</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000379</idno>
<idno type="wicri:Area/Pmc/Checkpoint">000156</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Checkpoint">000156</idno>
<idno type="wicri:source">PubMed</idno>
<idno type="wicri:Area/PubMed/Corpus">000022</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000022</idno>
<idno type="wicri:Area/PubMed/Curation">000022</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">000022</idno>
<idno type="wicri:Area/PubMed/Checkpoint">000022</idno>
<idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">000022</idno>
<idno type="wicri:Area/Ncbi/Merge">000319</idno>
<idno type="wicri:Area/Ncbi/Curation">000319</idno>
<idno type="wicri:Area/Ncbi/Checkpoint">000319</idno>
<idno type="wicri:Area/Main/Merge">000168</idno>
<idno type="wicri:Area/Main/Curation">000168</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Bis[tris(phenanthroline-κ<sup>2</sup>
<italic>N</italic>
,<italic>N</italic>
′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrate</title>
<author><name sortKey="Hajsalem, Assia" sort="Hajsalem, Assia" uniqKey="Hajsalem A" first="Assia" last="Hajsalem">Assia Hajsalem</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Aoun, Sameh" sort="Aoun, Sameh" uniqKey="Aoun S" first="Sameh" last="Aoun">Sameh Aoun</name>
<affiliation wicri:level="1"><nlm:aff id="b">Laboratoire CEISAM, UMR CNRS 6230, UFR des Sciences et des Techniques, 2 rue de la Houssinière, BP 92208, 44322 Nantes Cedex 03,<country>France</country>
</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Planchat, Aurelien" sort="Planchat, Aurelien" uniqKey="Planchat A" first="Aurelien" last="Planchat">Aurelien Planchat</name>
<affiliation wicri:level="1"><nlm:aff id="b">Laboratoire CEISAM, UMR CNRS 6230, UFR des Sciences et des Techniques, 2 rue de la Houssinière, BP 92208, 44322 Nantes Cedex 03,<country>France</country>
</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Rzaigui, Mohamed" sort="Rzaigui, Mohamed" uniqKey="Rzaigui M" first="Mohamed" last="Rzaigui">Mohamed Rzaigui</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Toumi, Samah Akriche" sort="Toumi, Samah Akriche" uniqKey="Toumi S" first="Samah Akriche" last="Toumi">Samah Akriche Toumi</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</analytic>
<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
<idno type="eISSN">1600-5368</idno>
<imprint><date when="2014">2014</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en"><p>In the title hydrated salt, [Co(C<sub>12</sub>
H<sub>8</sub>
N<sub>2</sub>
)<sub>3</sub>
]<sub>2</sub>
[PVW<sub>11</sub>
O<sub>40</sub>
]·2H<sub>2</sub>
O, the complete Kegggin ion is generated by crystallographic inversion symmetry, which imposes statistical disorder on the O atoms of its central PO<sub>4</sub>
group. The V atom is statistically disordered over all the metal sites of the anion. In the cation, the Co<sup>2+</sup>
ion is coordinated by three bidentate 1,10-phenanthroline (phen) ligands, generating a distorted CoN<sub>6</sub>
octahedron. Possible very weak intramolecular C—H⋯π interactions occur in the cation. In the crystal, the components are linked by O—H⋯O and C—H⋯O interactions, building a three-dimensional network featuring one-dimensional voids along the <italic>c</italic>
-axis direction.</p>
</div>
</front>
<back><div1 type="bibliography"><listBibl><biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
</listBibl>
</div1>
</back>
</TEI>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/CobaltMaghrebV1/Data/Main/Curation
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000168 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Curation/biblio.hfd -nk 000168 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Wicri/Terre |area= CobaltMaghrebV1 |flux= Main |étape= Curation |type= RBID |clé= PMC:3998553 |texte= Bis[tris(phenanthroline-κ2N,N′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrate }}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Curation/RBID.i -Sk "pubmed:24826091" \ | HfdSelect -Kh $EXPLOR_AREA/Data/Main/Curation/biblio.hfd \ | NlmPubMed2Wicri -a CobaltMaghrebV1
![]() | This area was generated with Dilib version V0.6.32. | ![]() |