CobaltMaghrebV1, PubMed, Corpus, bibRecord, 000057

Bis(2-methyl-anilinium) diaqua-bis[dihydrogendiphosphato(2-)]cobaltate(II).

Identifieur interne : 000057 ( PubMed/Corpus ); précédent : 000056; suivant : 000058

Bis(2-methyl-anilinium) diaqua-bis[dihydrogendiphosphato(2-)]cobaltate(II).

Auteurs : Ahmed Selmi ; Samah Akriche ; Mohamed Rzaigui

Source :

Acta crystallographica. Section E, Structure reports online ; 2009.

RBID : pubmed:21578209

Abstract

In the title cobalt(II) complex with 2-methyl-anilinium and diphosphate, (C(7)H(10)N)(2)[Co(H(2)P(2)O(7))(2)(H(2)O)(2)], a three-dimensional network is built up from anionic layers of [Co(H(2)P(2)O(7))(2)(H(2)O)(2)](2-) units and 2-methyl-anilinium cations located between these layers. The dihydrogendiphosphate groups present a bent eclipsed conformation, while the Co(2+) ions lie on inversion centers. An intricate network of O-H⋯O and N-H⋯O hydrogen bonds is established between the different components, assuring the cohesion of the network with other inter-actions, being of electrostatic and van der Waals nature.

DOI: 10.1107/S1600536809044079
PubMed: 21578209

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pubmed:21578209

Le document en format XML

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<front><div type="abstract" xml:lang="en">In the title cobalt(II) complex with 2-methyl-anilinium and diphosphate, (C(7)H(10)N)(2)[Co(H(2)P(2)O(7))(2)(H(2)O)(2)], a three-dimensional network is built up from anionic layers of [Co(H(2)P(2)O(7))(2)(H(2)O)(2)](2-) units and 2-methyl-anilinium cations located between these layers. The dihydrogendiphosphate groups present a bent eclipsed conformation, while the Co(2+) ions lie on inversion centers. An intricate network of O-H⋯O and N-H⋯O hydrogen bonds is established between the different components, assuring the cohesion of the network with other inter-actions, being of electrostatic and van der Waals nature.</div>
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<Abstract><AbstractText>In the title cobalt(II) complex with 2-methyl-anilinium and diphosphate, (C(7)H(10)N)(2)[Co(H(2)P(2)O(7))(2)(H(2)O)(2)], a three-dimensional network is built up from anionic layers of [Co(H(2)P(2)O(7))(2)(H(2)O)(2)](2-) units and 2-methyl-anilinium cations located between these layers. The dihydrogendiphosphate groups present a bent eclipsed conformation, while the Co(2+) ions lie on inversion centers. An intricate network of O-H⋯O and N-H⋯O hydrogen bonds is established between the different components, assuring the cohesion of the network with other inter-actions, being of electrostatic and van der Waals nature.</AbstractText>
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	Serveur d'exploration sur le cobalt au Maghreb
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Serveur d'exploration sur le cobalt au Maghreb

Bis(2-methyl-anilinium) diaqua-bis[dihydrogendiphosphato(2-)]cobaltate(II).

Bis(2-methyl-anilinium) diaqua-bis[dihydrogendiphosphato(2-)]cobaltate(II).

Source :

Abstract

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki