Crystal structure of bis-(4-nitro-aniline-κN (1))(5,10,15,20-tetra-phenyl-por-phy-rin-ato-κ(4) N)cobalt(III) chloride di-chloro-methane monosolvate.
Identifieur interne : 000016 ( PubMed/Corpus ); précédent : 000015; suivant : 000017Crystal structure of bis-(4-nitro-aniline-κN (1))(5,10,15,20-tetra-phenyl-por-phy-rin-ato-κ(4) N)cobalt(III) chloride di-chloro-methane monosolvate.
Auteurs : Yassine Belghith ; Anissa Mansour ; Habib NasriSource :
- Acta crystallographica. Section E, Structure reports online ; 2014.
Abstract
The reaction of [Co(III)(TPP)Cl] (TPP is the dianion of 5,10,15,20-tetra-phenyl-porphyrin) with an excess of 4-nitro-aniline in di-chloro-methane leads to the title compound, [Co(III)(C44H28N4)(C6H6N2O2)2]Cl·CH2Cl2. The Co(III) ion lies on an inversion centre and is octa-hedrally coordinated by two N atoms of the NH2 groups of the two 4-nitro-aniline trans-axial ligands and four pyrrole N atoms of the porphyrin. The asymmetric unit contains one half of the [Co(III)(TPP)(4-nitro-aniline)2](+) ion complex, one chloride counter-ion (lying on a twofold rotation axis) and one half di-chloro-methane solvent mol-ecule, where the C atom lies on a twofold rotation axis. The average equatorial Co-N(pyrrole) distance (Co-Np) is 1.982 (2) Å and the axial Co-N(4-nitro-aniline) bond length is 2.006 (2) Å. The crystal packing is stabilized by an N-H⋯Cl hydrogen bond between the N atom of the amino group of the 4-nitro-aniline axial ligand and the chloride counter-ion. The supra-molecular architecture is further stabilized by weak C-H⋯π inter-actions.
DOI: 10.1107/S1600536814016274
PubMed: 25309176
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Crystal structure of bis-(4-nitro-aniline-κN (1))(5,10,15,20-tetra-phenyl-por-phy-rin-ato-κ(4) N)cobalt(III) chloride di-chloro-methane monosolvate.</title><author><name sortKey="Belghith, Yassine" sort="Belghith, Yassine" uniqKey="Belghith Y" first="Yassine" last="Belghith">Yassine Belghith</name><affiliation><nlm:affiliation>Laboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, Tunisia.</nlm:affiliation></affiliation></author><author><name sortKey="Mansour, Anissa" sort="Mansour, Anissa" uniqKey="Mansour A" first="Anissa" last="Mansour">Anissa Mansour</name><affiliation><nlm:affiliation>University of Dammam, PO Box 1982, Dammam, Kingdom of Saudi Arabia.</nlm:affiliation></affiliation></author><author><name sortKey="Nasri, Habib" sort="Nasri, Habib" uniqKey="Nasri H" first="Habib" last="Nasri">Habib Nasri</name><affiliation><nlm:affiliation>Laboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, Tunisia.</nlm:affiliation></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2014">2014</date><idno type="RBID">pubmed:25309176</idno><idno type="pmid">25309176</idno><idno type="doi">10.1107/S1600536814016274</idno><idno type="wicri:Area/PubMed/Corpus">000016</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000016</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Crystal structure of bis-(4-nitro-aniline-κN (1))(5,10,15,20-tetra-phenyl-por-phy-rin-ato-κ(4) N)cobalt(III) chloride di-chloro-methane monosolvate.</title><author><name sortKey="Belghith, Yassine" sort="Belghith, Yassine" uniqKey="Belghith Y" first="Yassine" last="Belghith">Yassine Belghith</name><affiliation><nlm:affiliation>Laboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, Tunisia.</nlm:affiliation></affiliation></author><author><name sortKey="Mansour, Anissa" sort="Mansour, Anissa" uniqKey="Mansour A" first="Anissa" last="Mansour">Anissa Mansour</name><affiliation><nlm:affiliation>University of Dammam, PO Box 1982, Dammam, Kingdom of Saudi Arabia.</nlm:affiliation></affiliation></author><author><name sortKey="Nasri, Habib" sort="Nasri, Habib" uniqKey="Nasri H" first="Habib" last="Nasri">Habib Nasri</name><affiliation><nlm:affiliation>Laboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, Tunisia.</nlm:affiliation></affiliation></author></analytic><series><title level="j">Acta crystallographica. Section E, Structure reports online</title><imprint><date when="2014" type="published">2014</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The reaction of [Co(III)(TPP)Cl] (TPP is the dianion of 5,10,15,20-tetra-phenyl-porphyrin) with an excess of 4-nitro-aniline in di-chloro-methane leads to the title compound, [Co(III)(C44H28N4)(C6H6N2O2)2]Cl·CH2Cl2. The Co(III) ion lies on an inversion centre and is octa-hedrally coordinated by two N atoms of the NH2 groups of the two 4-nitro-aniline trans-axial ligands and four pyrrole N atoms of the porphyrin. The asymmetric unit contains one half of the [Co(III)(TPP)(4-nitro-aniline)2](+) ion complex, one chloride counter-ion (lying on a twofold rotation axis) and one half di-chloro-methane solvent mol-ecule, where the C atom lies on a twofold rotation axis. The average equatorial Co-N(pyrrole) distance (Co-Np) is 1.982 (2) Å and the axial Co-N(4-nitro-aniline) bond length is 2.006 (2) Å. The crystal packing is stabilized by an N-H⋯Cl hydrogen bond between the N atom of the amino group of the 4-nitro-aniline axial ligand and the chloride counter-ion. The supra-molecular architecture is further stabilized by weak C-H⋯π inter-actions.</div></front></TEI><pubmed><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">25309176</PMID><DateCreated><Year>2014</Year><Month>10</Month><Day>13</Day></DateCreated><DateCompleted><Year>2014</Year><Month>10</Month><Day>13</Day></DateCompleted><DateRevised><Year>2014</Year><Month>10</Month><Day>15</Day></DateRevised><Article PubModel="Electronic-eCollection"><Journal><JournalIssue CitedMedium="Print"><Volume>70</Volume><Issue>Pt 9</Issue><PubDate><Year>2014</Year><Month>Sep</Month><Day>1</Day></PubDate></JournalIssue><Title>Acta crystallographica. Section E, Structure reports online</Title><ISOAbbreviation>Acta Crystallogr Sect E Struct Rep Online</ISOAbbreviation></Journal><ArticleTitle>Crystal structure of bis-(4-nitro-aniline-κN (1))(5,10,15,20-tetra-phenyl-por-phy-rin-ato-κ(4) N)cobalt(III) chloride di-chloro-methane monosolvate.</ArticleTitle><Pagination><MedlinePgn>m312-3</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1107/S1600536814016274</ELocationID><Abstract><AbstractText>The reaction of [Co(III)(TPP)Cl] (TPP is the dianion of 5,10,15,20-tetra-phenyl-porphyrin) with an excess of 4-nitro-aniline in di-chloro-methane leads to the title compound, [Co(III)(C44H28N4)(C6H6N2O2)2]Cl·CH2Cl2. The Co(III) ion lies on an inversion centre and is octa-hedrally coordinated by two N atoms of the NH2 groups of the two 4-nitro-aniline trans-axial ligands and four pyrrole N atoms of the porphyrin. The asymmetric unit contains one half of the [Co(III)(TPP)(4-nitro-aniline)2](+) ion complex, one chloride counter-ion (lying on a twofold rotation axis) and one half di-chloro-methane solvent mol-ecule, where the C atom lies on a twofold rotation axis. The average equatorial Co-N(pyrrole) distance (Co-Np) is 1.982 (2) Å and the axial Co-N(4-nitro-aniline) bond length is 2.006 (2) Å. The crystal packing is stabilized by an N-H⋯Cl hydrogen bond between the N atom of the amino group of the 4-nitro-aniline axial ligand and the chloride counter-ion. The supra-molecular architecture is further stabilized by weak C-H⋯π inter-actions.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Belghith</LastName><ForeName>Yassine</ForeName><Initials>Y</Initials><AffiliationInfo><Affiliation>Laboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, Tunisia.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Mansour</LastName><ForeName>Anissa</ForeName><Initials>A</Initials><AffiliationInfo><Affiliation>University of Dammam, PO Box 1982, Dammam, Kingdom of Saudi Arabia.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Nasri</LastName><ForeName>Habib</ForeName><Initials>H</Initials><AffiliationInfo><Affiliation>Laboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, Tunisia.</Affiliation></AffiliationInfo></Author></AuthorList><Language>ENG</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2014</Year><Month>Aug</Month><Day>01</Day></ArticleDate></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>Acta Crystallogr Sect E Struct Rep Online</MedlineTA><NlmUniqueID>101089178</NlmUniqueID><ISSNLinking>1600-5368</ISSNLinking></MedlineJournalInfo><OtherID Source="NLM">PMC4186082</OtherID><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">5,10,15,20-tetraphenylporphyrin ligand</Keyword><Keyword MajorTopicYN="N">cobalt(III) complex</Keyword><Keyword MajorTopicYN="N">crystal structure</Keyword></KeywordList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2014</Year><Month>7</Month><Day>10</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2014</Year><Month>7</Month><Day>13</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2014</Year><Month>10</Month><Day>14</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2014</Year><Month>10</Month><Day>14</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2014</Year><Month>10</Month><Day>14</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>epublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">25309176</ArticleId><ArticleId IdType="doi">10.1107/S1600536814016274</ArticleId><ArticleId IdType="pii">xu5802</ArticleId><ArticleId IdType="pmc">PMC4186082</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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