Poly[di-μ-aqua-diaqua-di-μ6-malonato-cobalt(II)dipotassium(I)]
Identifieur interne : 000392 ( Pmc/Curation ); précédent : 000391; suivant : 000393Poly[di-μ-aqua-diaqua-di-μ6-malonato-cobalt(II)dipotassium(I)]
Auteurs : Adama Sy [Sénégal] ; Aliou Hamady Barry [Mauritanie] ; Mohamed Gaye [Sénégal] ; Abdou Salam Sall [Sénégal] ; Ahmed Driss [Tunisie]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2011.
Abstract
In the title complex, [CoK2(C3H2O4)2(H2O)4]
Url:
DOI: 10.1107/S1600536811012839
PubMed: 21754320
PubMed Central: 3089327
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Poly[di-μ-aqua-diaqua-di-μ<sub>6</sub>-malonato-cobalt(II)dipotassium(I)]</title><author><name sortKey="Sy, Adama" sort="Sy, Adama" uniqKey="Sy A" first="Adama" last="Sy">Adama Sy</name><affiliation wicri:level="1"><nlm:aff id="a">Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar,<country>Senegal</country></nlm:aff><country xml:lang="fr">Sénégal</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Barry, Aliou Hamady" sort="Barry, Aliou Hamady" uniqKey="Barry A" first="Aliou Hamady" last="Barry">Aliou Hamady Barry</name><affiliation wicri:level="1"><nlm:aff id="b">Département de Chimie, Faculté des Sciences, Université de Nouakchott, Nouakchott,<country>Mauritania</country></nlm:aff><country xml:lang="fr">Mauritanie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Gaye, Mohamed" sort="Gaye, Mohamed" uniqKey="Gaye M" first="Mohamed" last="Gaye">Mohamed Gaye</name><affiliation wicri:level="1"><nlm:aff id="a">Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar,<country>Senegal</country></nlm:aff><country xml:lang="fr">Sénégal</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Sall, Abdou Salam" sort="Sall, Abdou Salam" uniqKey="Sall A" first="Abdou Salam" last="Sall">Abdou Salam Sall</name><affiliation wicri:level="1"><nlm:aff id="a">Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar,<country>Senegal</country></nlm:aff><country xml:lang="fr">Sénégal</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name><affiliation wicri:level="1"><nlm:aff id="c">Campus Universitaire, Département de Chimie, Faculté des Sciences, Université de Tunis, 1060 Tunis,<country>Tunisia</country></nlm:aff><country xml:lang="fr">Tunisie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PMC</idno><idno type="pmid">21754320</idno><idno type="pmc">3089327</idno><idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089327</idno><idno type="RBID">PMC:3089327</idno><idno type="doi">10.1107/S1600536811012839</idno><date when="2011">2011</date><idno type="wicri:Area/Pmc/Corpus">000393</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000393</idno><idno type="wicri:Area/Pmc/Curation">000392</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000392</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Poly[di-μ-aqua-diaqua-di-μ<sub>6</sub>-malonato-cobalt(II)dipotassium(I)]</title><author><name sortKey="Sy, Adama" sort="Sy, Adama" uniqKey="Sy A" first="Adama" last="Sy">Adama Sy</name><affiliation wicri:level="1"><nlm:aff id="a">Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar,<country>Senegal</country></nlm:aff><country xml:lang="fr">Sénégal</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Barry, Aliou Hamady" sort="Barry, Aliou Hamady" uniqKey="Barry A" first="Aliou Hamady" last="Barry">Aliou Hamady Barry</name><affiliation wicri:level="1"><nlm:aff id="b">Département de Chimie, Faculté des Sciences, Université de Nouakchott, Nouakchott,<country>Mauritania</country></nlm:aff><country xml:lang="fr">Mauritanie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Gaye, Mohamed" sort="Gaye, Mohamed" uniqKey="Gaye M" first="Mohamed" last="Gaye">Mohamed Gaye</name><affiliation wicri:level="1"><nlm:aff id="a">Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar,<country>Senegal</country></nlm:aff><country xml:lang="fr">Sénégal</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Sall, Abdou Salam" sort="Sall, Abdou Salam" uniqKey="Sall A" first="Abdou Salam" last="Sall">Abdou Salam Sall</name><affiliation wicri:level="1"><nlm:aff id="a">Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar,<country>Senegal</country></nlm:aff><country xml:lang="fr">Sénégal</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name><affiliation wicri:level="1"><nlm:aff id="c">Campus Universitaire, Département de Chimie, Faculté des Sciences, Université de Tunis, 1060 Tunis,<country>Tunisia</country></nlm:aff><country xml:lang="fr">Tunisie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></analytic><series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title><idno type="eISSN">1600-5368</idno><imprint><date when="2011">2011</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p>In the title complex, [CoK<sub>2</sub>(C<sub>3</sub>H<sub>2</sub>O<sub>4</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>]<sub><italic>n</italic></sub>, the Co atom is located on a position with site symmetry 2/<italic>m</italic>, the K atom and one water molecule are located on a mirror plane, and the malonate and one water molecule are located on a twofold rotation axis. The K<sup>I</sup> atom is seven-coordinated by four carboxylate O atoms from four malonate ligands and by three water O atoms, forming a distorted polyhedron. The Co<sup>II</sup> atom is in an almost octahedral environment formed by four carboxylate O atoms from two malonate ligands and two water O atoms. The structure consists of layers parallel to (20<inline-formula><inline-graphic xlink:href="e-67-0m601-efi1.jpg" mimetype="image" mime-subtype="gif"></inline-graphic></inline-formula>) built up from edge-sharing KO<sub>7</sub> and CoO<sub>6</sub> polyhedra, which are connected by O—H⋯O hydrogen bonding including water molecules into a three-dimensional network.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct></listBibl></div1></back></TEI><pmc article-type="research-article"><pmc-dir>properties open_access</pmc-dir>
<front><journal-meta><journal-id journal-id-type="nlm-ta">Acta Crystallogr Sect E Struct Rep Online</journal-id><journal-id journal-id-type="publisher-id">Acta Cryst. E</journal-id><journal-title-group><journal-title>Acta Crystallographica Section E: Structure Reports Online</journal-title></journal-title-group><issn pub-type="epub">1600-5368</issn><publisher><publisher-name>International Union of Crystallography</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="pmid">21754320</article-id><article-id pub-id-type="pmc">3089327</article-id><article-id pub-id-type="publisher-id">bt5510</article-id><article-id pub-id-type="doi">10.1107/S1600536811012839</article-id><article-id pub-id-type="coden">ACSEBH</article-id><article-id pub-id-type="pii">S1600536811012839</article-id><article-categories><subj-group subj-group-type="heading"><subject>Metal-Organic Papers</subject></subj-group></article-categories><title-group><article-title>Poly[di-μ-aqua-diaqua-di-μ<sub>6</sub>-malonato-cobalt(II)dipotassium(I)]</article-title><alt-title><italic>[CoK<sub>2</sub>(C<sub>3</sub>H<sub>2</sub>O<sub>4</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>]</italic></alt-title></title-group><contrib-group><contrib contrib-type="author"><name><surname>Sy</surname><given-names>Adama</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><contrib contrib-type="author"><name><surname>Barry</surname><given-names>Aliou Hamady</given-names></name><xref ref-type="aff" rid="b">b</xref></contrib><contrib contrib-type="author"><name><surname>Gaye</surname><given-names>Mohamed</given-names></name><xref ref-type="aff" rid="a">a</xref><xref ref-type="corresp" rid="cor">*</xref></contrib><contrib contrib-type="author"><name><surname>Sall</surname><given-names>Abdou Salam</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><contrib contrib-type="author"><name><surname>Driss</surname><given-names>Ahmed</given-names></name><xref ref-type="aff" rid="c">c</xref></contrib><aff id="a"><label>a</label>Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar,<country>Senegal</country></aff><aff id="b"><label>b</label>Département de Chimie, Faculté des Sciences, Université de Nouakchott, Nouakchott,<country>Mauritania</country></aff><aff id="c"><label>c</label>Campus Universitaire, Département de Chimie, Faculté des Sciences, Université de Tunis, 1060 Tunis,<country>Tunisia</country></aff></contrib-group><author-notes><corresp id="cor">Correspondence e-mail: <email>mlgayeastou@yahoo.fr</email></corresp></author-notes><pub-date pub-type="collection"><day>01</day><month>5</month><year>2011</year></pub-date><pub-date pub-type="epub"><day>16</day><month>4</month><year>2011</year></pub-date><pub-date pub-type="pmc-release"><day>16</day><month>4</month><year>2011</year></pub-date><pmc-comment> PMC Release delay is 0 months and 0 days and was based on the
<volume>67</volume><issue>Pt 5</issue><issue-id pub-id-type="publisher-id">e110500</issue-id><fpage>m601</fpage><lpage>m601</lpage><history><date date-type="received"><day>05</day><month>4</month><year>2011</year></date><date date-type="accepted"><day>06</day><month>4</month><year>2011</year></date></history><permissions><copyright-statement>© Sy et al. 2011</copyright-statement><copyright-year>2011</copyright-year><license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/2.0/uk/"><license-p>This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.</license-p></license></permissions><self-uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1107/S1600536811012839">A full version of this article is available from Crystallography Journals Online.</self-uri><abstract><p>In the title complex, [CoK<sub>2</sub>(C<sub>3</sub>H<sub>2</sub>O<sub>4</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>]<sub><italic>n</italic></sub>, the Co atom is located on a position with site symmetry 2/<italic>m</italic>, the K atom and one water molecule are located on a mirror plane, and the malonate and one water molecule are located on a twofold rotation axis. The K<sup>I</sup> atom is seven-coordinated by four carboxylate O atoms from four malonate ligands and by three water O atoms, forming a distorted polyhedron. The Co<sup>II</sup> atom is in an almost octahedral environment formed by four carboxylate O atoms from two malonate ligands and two water O atoms. The structure consists of layers parallel to (20<inline-formula><inline-graphic xlink:href="e-67-0m601-efi1.jpg" mimetype="image" mime-subtype="gif"></inline-graphic></inline-formula>) built up from edge-sharing KO<sub>7</sub> and CoO<sub>6</sub> polyhedra, which are connected by O—H⋯O hydrogen bonding including water molecules into a three-dimensional network.</p></abstract></article-meta></front><floats-group><table-wrap id="table1" position="float"><label>Table 1</label><caption><title>Selected bond lengths (Å)</title></caption><table frame="hsides" rules="groups"><tbody valign="top"><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">Co1—O2</td><td style="" rowspan="1" colspan="1" align="char" valign="top">2.0584 (11)</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">Co1—O1</td><td style="" rowspan="1" colspan="1" align="char" valign="top">2.1347 (18)</td></tr></tbody></table></table-wrap><table-wrap id="table2" position="float"><label>Table 2</label><caption><title>Hydrogen-bond geometry (Å, °)</title></caption><table frame="hsides" rules="groups"><thead valign="bottom"><tr><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>—H⋯<italic>A</italic></th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>—H</th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom">H⋯<italic>A</italic></th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>⋯<italic>A</italic></th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>—H⋯<italic>A</italic></th></tr></thead><tbody valign="top"><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O1—H<italic>W</italic>1⋯O3<sup>iv</sup></td><td style="" rowspan="1" colspan="1" align="left" valign="top">0.81 (2)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">1.91 (2)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.7077 (17)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">167 (2)</td></tr><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O4—H<italic>W</italic>2⋯O3<sup>i</sup></td><td style="" rowspan="1" colspan="1" align="left" valign="top">0.80 (3)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.03 (3)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.8372 (18)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">176 (3)</td></tr></tbody></table><table-wrap-foot><p>Symmetry codes: (i) <inline-formula><inline-graphic xlink:href="e-67-0m601-efi3.jpg" mimetype="image" mime-subtype="gif"></inline-graphic></inline-formula>; (iv) <inline-formula><inline-graphic xlink:href="e-67-0m601-efi4.jpg" mimetype="image" mime-subtype="gif"></inline-graphic></inline-formula>.</p></table-wrap-foot></table-wrap></floats-group></pmc></record>Pour manipuler ce document sous Unix (Dilib)
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